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哈斯勒合金Ni-Mn-Ga的马氏体相变和磁增强双向形状记忆效应

柳祝红 胡凤霞 王文洪 陈京兰 吴光恒 高书侠 敖玲

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哈斯勒合金Ni-Mn-Ga的马氏体相变和磁增强双向形状记忆效应

柳祝红, 胡凤霞, 王文洪, 陈京兰, 吴光恒, 高书侠, 敖玲

INVESTIGATION ON MARTENSITIC TRANSFORMATION AND FIELD-INDUCED TWO-WAY SHAPE MEMORY EFFECT OF Ni-Mn-Ga ALLOY

LIU ZHU-HONG, HU FENG-XIA, WANG WEN-HONG, CHEN JING-LAN, WU GUANG-HENG, GAO SHU-XIA, AO LING
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  • 通过研究铁磁性金属间化合物Ni2+xMn1-xGa(x=-0.1,0,0.08,0.13,0.18,0.2)和Ni2-xMn1+x/2Ga1+x/2(x=-0.1,0,0.04,0.06,0.1)两个系列多晶样品的交流磁化率随温度的变化行为,得到了化合物在不同组分下的马氏体相变温度TM和居里温度TC.发现随着Ni成分的增加,前者的马氏体相变温度Tm增加,而居里温度TC降低,后者的马氏体相变温度Tm和居里温度TC均是先增大后减小.报道了Tm在室温附近的单晶样品Ni52Mn24Ga24的磁场增强双向形状记忆效应.发现伴随着马氏体相变,样品在[001]方向可产生1.2%的收缩.如果在该方向施加1.2T的偏磁场可以使该应变值增大到4.0%.而垂直于[001]方向施加1.2T的偏磁场时,在[001]方向产生1.6%的膨胀.阐明了产生大应变的原因并非相界移动,而是单晶的杂散内应力小和外加磁场通过孪晶界移动使马氏体变体重组的共同结果.
    The martensitic phase transformation temperature,Tm and the Curie temperature, TC, of polycrystalline samples Ni2+xMn1-x Ga(x=-0.1,0,0.08,0.13,0.18,0.2) and Ni2-xMn1+x/2Ga1+x/2(x=-0.1,0,0.04,0.06,0.1) have been investigated by measuring the temperature dependence of alternating-current susceptibility. It was found that, with the increase of Ni content,TC decreases and Tm increases for Ni2+xMn1-xGa, and both TC and Tm increase first and decrease afterwards for Ni2-xMn1+x/2Ga1+x/2. Stress-free and two-way thermoelastic shape memory, with 1.2% strain, has been found in single crystal Ni52Mn24Ga24. The deformation can be enhanced more than three times, up to 4.0% shrinkage with a bias field 1.2T applied along the measurement direction. The origin of large recoverable strain should be attributed to the low level of internal stress and the field-induced rearrangement of martensitic variants through twin boundary motion rather than the phase boundary motion.
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  • 文章访问数:  7019
  • PDF下载量:  888
  • 被引次数: 0
出版历程
  • 收稿日期:  2000-07-05
  • 修回日期:  2000-08-17
  • 刊出日期:  2001-01-05

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