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We synthesize MAl12O19 (M = Ca, Sr, Ba) singly doped with Eu2+ or Cr3+ and co-doped with Eu2+ and Cr3+ by high-temperature solid-state reaction under reducing atmosphere. It is observed that there exit energy transfers from Eu2+ to Cr3+ in MAl12O19 (M = Ca, Sr, Ba) hosts. Although the MAl12O19 (M= Ca, Sr, Ba) hosts have similar crystal structures, the energy transfer efficienies and the conversion rates of the blue light to the red light are different. Both experiment and calculation show that the energy transfer from Eu to Cr in CaAl12O19 host is most efficient, and the ratio of the red emission to the blue emission in CaAl12O19 host is the highest among the three different hosts.
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Keywords:
- MAl12O19 /
- Eu2+ /
- Cr3+ /
- energy transfer
[1] Wu C C, Cheng B M, Chen T M 2006 J. Rare Earths 24 179
[2] Rao R P 2005 J. Lumin. 113 271
[3] Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 物理学报 57 4575]
[4] Nishida T, Ban T, Kobayashi N 2003 Appl. Phys. Lett. 82 3817
[5] Minami T, Miyata T, Suzuki Y, Mochizuki Y 2004 Thin Solid Films 69 46965
[6] Lin C K, Pang M L, Yu M, Lin J 2005 J. Lumin. 114 299
[7] Douy A, Capron M J 2003 Eur. Ceram. Soc. 23 2075
[8] Chen I C, Chen T M 2001 J. Mater. Res. 16 129
[9] Lee D Y, Kang Y C, Park H D, Ryu S K 2003 J. Alloys Compd. 353 252
[10] Merkle L D, Zandi B, Moncorge R, Guyot Y, Verdun H R, McIntosh B 1996 J. Appl. Phys. 79 1849
[11] Zhong R X, Zhang J H, Zhang X, Lu S Z, Wang X J 2008 Nanotechnology 18 445707
[12] Zhong R X, Zhang J H, Zhang X, Lu S Z, Ren X G, Wang X J 2010 J. Phys. D: Appl. Phys. 41 065104
[13] Park J G, Cormack A N 2000 Korean J. Crystallography 11 176
[14] Zhong R X, Zhang J H 2010 J. Lumin. 130 206
[15] Liu Y L, Tang X M, Chen X D 1999 Chin. Chem. Lett. 10 709
[16] Stefani R, Rodrigues L C V, Carvalho C A A, Felinto M C F C, Brito H F, Lastusaari M 2009 Opt. Mater 31 1815
[17] Broer M M, Huver D L, Yen W M, Zwicker W K 1982 Phys. Rev. Lett. 49 394
[18] Broer M M, Huver D L, Yen W M, Zwicker W K 1984 Phys. Rev. B 29 2382
[19] Inokuti M, Hirayama F 1965 J. Chem. Phys. 43 1978
[20] Paulose P I, Jose G, Thomas V, Unnikrishnan N V, Warrier M K R 2003 J. Phys. Chem. Solids 64 841
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[1] Wu C C, Cheng B M, Chen T M 2006 J. Rare Earths 24 179
[2] Rao R P 2005 J. Lumin. 113 271
[3] Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 物理学报 57 4575]
[4] Nishida T, Ban T, Kobayashi N 2003 Appl. Phys. Lett. 82 3817
[5] Minami T, Miyata T, Suzuki Y, Mochizuki Y 2004 Thin Solid Films 69 46965
[6] Lin C K, Pang M L, Yu M, Lin J 2005 J. Lumin. 114 299
[7] Douy A, Capron M J 2003 Eur. Ceram. Soc. 23 2075
[8] Chen I C, Chen T M 2001 J. Mater. Res. 16 129
[9] Lee D Y, Kang Y C, Park H D, Ryu S K 2003 J. Alloys Compd. 353 252
[10] Merkle L D, Zandi B, Moncorge R, Guyot Y, Verdun H R, McIntosh B 1996 J. Appl. Phys. 79 1849
[11] Zhong R X, Zhang J H, Zhang X, Lu S Z, Wang X J 2008 Nanotechnology 18 445707
[12] Zhong R X, Zhang J H, Zhang X, Lu S Z, Ren X G, Wang X J 2010 J. Phys. D: Appl. Phys. 41 065104
[13] Park J G, Cormack A N 2000 Korean J. Crystallography 11 176
[14] Zhong R X, Zhang J H 2010 J. Lumin. 130 206
[15] Liu Y L, Tang X M, Chen X D 1999 Chin. Chem. Lett. 10 709
[16] Stefani R, Rodrigues L C V, Carvalho C A A, Felinto M C F C, Brito H F, Lastusaari M 2009 Opt. Mater 31 1815
[17] Broer M M, Huver D L, Yen W M, Zwicker W K 1982 Phys. Rev. Lett. 49 394
[18] Broer M M, Huver D L, Yen W M, Zwicker W K 1984 Phys. Rev. B 29 2382
[19] Inokuti M, Hirayama F 1965 J. Chem. Phys. 43 1978
[20] Paulose P I, Jose G, Thomas V, Unnikrishnan N V, Warrier M K R 2003 J. Phys. Chem. Solids 64 841
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