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In practical applications, flexibility, lightweight, and high performance are the characteristics that polymer-based electromagnetic shielding materials should have. At present, it is still a great challenge to prepare polymer-based electromagnetic shielding materials with excellent conductivity, electromagnetic shielding properties, and mechanical properties. Therefore, in this work, single-walled carbon nanotubes/polyetherimide composite films are prepared by electrostatic spinning and vacuum-assisted filtration using single-walled carbon nanotubes and polyetherimide as raw materials. By regulating the surface density of single-walled carbon nanotubes, the conductivity of the composite film can be enhanced to 1866 S/cm. For the electromagnetic shielding performance, the total electromagnetic shielding efficacy of single-walled carbon nanotubes/polyetherimide composite film in Ku band (12~18 GHz) is 75.78~81.83 dB, which is higher than the electromagnetic shielding efficacy of pure single-walled electromagnetic shielding effectiveness of carbon nanotube films (65.19~69.81 dB). This is attributed to the formation of interfaces between the polyetherimide fibers and the single-walled carbon nanotubes, with more interfaces consuming more electromagnetic wave energy for a given range of single-walled carbon nanotube surface densities. For the mechanical properties, the maximum tensile strength and elongation at break of the single-walled carbon nanotube/polyetherimide film are 1.13 and 1.5 times higher than those of the single-walled carbon nanotube film, with values of 28.52 MPa and 7.91 %, respectively. As the surface density of single-walled carbon nanotubes increases, the interaction between single-walled carbon nanotubes as well as the interaction between polyetherimide fibers and single-walled carbon nanotubes at the interface plays a role in enhancing the mechanical properties of the composite films. The single-walled carbon nanotube/polyetherimide composite films, as an excellent polymer-based electromagnetic shielding composite material, can be used in fields such as the protection of precision electronic instruments and wearable electronic devices.
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Keywords:
- Single-walled carbon nanotube /
- Polyetherimide /
- Electrostatic spinning /
- Electromagnetic shielding
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