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采用溶胶凝胶法以及静电纺丝法, 利用热处理工艺, 成功制备出了多晶锐钛矿型TiO2纳米线, 通过两线法在室温下测试单根TiO2纳米线的V-I曲线来研究其电输运性能及磁阻效应. 结果表明: 在无光照环境下其V-I曲线为不过零点的直线, 零场电阻较大, 在磁场作用下电阻下降, 表现出负磁阻效应; 紫外光辐照环境下TiO2纳米线载流子浓度增加使得电阻变小, 然而在磁场作用下电阻增大, 表现为正磁阻效应. 紫外光辐照导致的载流子浓度变化, 使得负磁阻转变为正磁阻, 我们将磁阻变化归结为d电子局域导致的负磁阻与能带劈裂导致的正磁阻两种机理相互竞争的结果.The polycrystalline anatase TiO2 nanowires with a diameter of about 300 nm are successfully prepared by the sol-gel method together with electrospinning method under a heat treatment at 500℃. The effect of illumination on electronic transport property and magnetoresistance (MR) effect are studied via voltage-current (V-I) curves measured at room temperature in the cases of the dark and the ultraviolet irradiation. The results show that the V-I plots are straight lines without passing through zero point and the resistance of the nanowire is as high as 7.51011 in the dark. The resistance decreases gradually with the magnetic field increasing and after reaching a minimum 4.71011 at B=0.7 T it turns to increase rapidly, but is still smaller than the resistance without magnetic field, indicating a negative MR effect. With the increase of the magnetic field, the negative MR effect increases and then decreases, and the negative MR achieves a maximum value of -37.5% under B=0.7 T. Interestingly, the resistance of nanowires in the ultraviolet irradiation is reduced by about 10 times compared with that in the dark without applying a magnetic field. As the magnetic field increases, the resistance increases monotonically, presenting a positive MR effect. The MR increases rapidly with the increase of magnetic field, and reaches the maximum positive MR effect 620% under B=1.0 T. At room temperature only a few carriers are generated by the thermal excitation in the TiO2 nanowires, which leads to a large resistance in the dark situation. In the ultraviolet irradiation case, the carrier concentration of the nanowires increases because of the generation of a large number of electron-hole pairs, resulting in huge decrease of resistance compared with in the dark. We attribute the change of the MR to the competition betwen two MR mechanisms: negative MR effect due to the localization of d electron and positive MR effect due to spin splitting of the conduction band. In the dark, due to the low carrier concentration, the negative MR mechanism caused by the localization of d electron is dominant under the magnetic field. However, in the ultraviolet irradiation, because carrier concentration increases hugely due to the irradiation, the positive MR mechanism caused by spin splitting of the conduction band is dominant. The fact that the V-I curves does not pass through zero point implies that the contact between TiO2 nanowire and Pt metal is Schottky contact due to the difference in work function. In the dark, the initial voltage first increases with the increase of magnetic field, and then remains steady. In the ultraviolet irradiation the initial voltage is smaller than in the dark and increases monotonically with the magnetic field increasing. In this paper, the physical mechanism of the electrical transport property and MR effect of TiO2 nanowire are discussed, which may provide a meaningful exploration for developing the new electronic device based on the oxide nanowires.
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Keywords:
- TiO2 nanowires /
- electrospinning /
- property of electronic transport /
- magnetoresistance effect
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[1] Zhao F 2011 M. S. Dissertation (Harbin: Harbin Institute Technology) (in Chinese) [赵峰 2011 硕士学位论文(哈尔滨: 哈尔滨工业大学)]
[2] Zhang H N 2011 Ph. D. Dissertation (Changchun: Jilin University) (in Chinese) [张弘楠 2011 博士学位论文(长春: 吉林大学)]
[3] Meng D, Yamazaki T, Kikuta T 2014 Sens. Actuator B 190 838
[4] Li H 2013 M. S. Dissertation (Wuhan: Wuhan University of Technology) (in Chinese) [李寒 2013 硕士学位论文(武汉: 武汉理工大学)]
[5] Peng R X, Chen C, Shen W, Guo Y, Geng H W, Wang M T 2009 Acta Phys. Sin. 58 6582 (in Chinese) [彭瑞祥, 陈冲, 沈薇, 郭颖, 耿宏伟, 王命泰 2009 物理学报 58 6582]
[6] Li D D, Wang L L 2012 Acta Phys. Sin. 61 034212 (in Chinese) [李冬冬, 王丽莉 2012 物理学报 61 034212]
[7] Liang P, Wang L, Xiong S Y, Dong Q M, Li X Y 2012 Acta Phys. Sin. 61 053101 (in Chinese) [梁培, 王乐, 熊斯雨, 董前民, 李晓艳 2012 物理学报 61 053101]
[8] Sani S R 2014 Chin. Phys. B 23 107302
[9] Zhang L, Huang B, Liu Y, Zhang L, Zhang R, Mei L 2003 J. Magn. Magn. Mater. 261 257
[10] Peleckis G, Wang X L, Dou S X, Munroe P, Ding J, Lee B 2008 J. Appl. Phys. 103 07D113
[11] Xu Q, Hartmann L, Schmidt H, Hochmuth H, Lorenz M, Spemann D, Grundmann M 2007 Phys. Rev. B 76 134417
[12] Wang D F, Kim J M, Thuy V T T, Seo M S, Lee Y P 2011 J. Korean Phys. Soc. 58 1304
[13] Hartmann L, Xu Q, Schmidt H, Hochmuth H, Lorenz M, Sturm C, Meinecke C, Grundmann M 2006 J. Phys. D 39 4920
[14] Reuss F, Frank S, Kirchner C, Kling R, Gruber T, Waag A 2005 Appl. Phys. Lett. 87 112104
[15] Liang W J, Yuhas B D, Yang P D 2009 Nano Lett. 9 892
[16] Tian Y F, Yan S, Cao Q, Deng J X, Chen Y X, Liu G L, Mei L M, Qiang Y 2009 Phys. Rev. B 79 115209
[17] Tian Y F, Antony J, Souza R, Yan S S, Mei L M, Qiang Y 2008 Appl. Phys. Lett. 92 192109
[18] Jabeen M, Iqbal M A, Kumar R V, Ahmed M, Javed M T 2014 Chin. Phys. B 23 018504
[19] Yu X X, Zhou Y, Liu J, Jin H B, Fang X Y, Cao M S 2015 Chin. Phys. B 24 127307
[20] Akinaga H, Mizuguchi M, Ono K, Oshima M 2000 Appl. Phys. Lett. 76 2600
[21] Shon Y, Yuldashev S U, Fan X J, Fu D J, Kwon Y H, Hong C Y, Kang T W 2001 Jpn. J. Appl. Phys. 40 3082
[22] Viana E R, Ribeiro G M, Oliveira A G, Peres M L, Rubinger R M, Rubinger C P L 2012 Mater. Res. 15 530
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