Two-magnon Raman spectra of RbNiF3 are calculated for the temperature range between 0 K to Néel point TN(= 133 K). From considerations of the general symmetry principle and the experimental results, we have derived the Hamiltonian of interaction between the magnetic system and the radiation field. The method of the equation of motion of retarded Green's function is used to obtain the analytic expression of the two-magnon Raman scattering intensity. In the two-magnon propagator, both the effects of energy renormalization and the life time have been taken into account. Finally, quantitative calculations are performed with proper approximations using computer. Although there are no adjustable parameters, the results account very well for the observed temperature dependence of both the. peak position and the line width in the range from 0 K up to TN.