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输运过程的红外发散理论

邓辉舫 刘福绥

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输运过程的红外发散理论

邓辉舫, 刘福绥

TRANSPORT THEORY WITH INFRARED DIVERGENCE

DENG HUI-FANG, LIU FU-SUI
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  • 本文基于低频涨落、耗散和弛豫现象的普适理论所提供的物理图象,探讨了非Markov过程的输运特点。发现:1.由于红外发散的影响、扩散系数、迁移率与粘滞系数以及它们之间所存在的广义Nernst-Einstein关系(以下简称MD关系)和广义DV关系(以下简称DV关系)一般说来都是色散的,色散的程度与表征物质内部结构差异的一个单参数——红外发散指数n有关。如果n=0,则所有的结果立即化为经典形式。2.在所讨论的模型中,按假设条件MV关系不依赖过程的性质和过程的结构。3.广义扩散系数与广义迁移率和MV,DV关系具
    In this paper, based on a physical picture of the unified theory of the low frequency fluctuation, dissipation and relaxation phenomenon, some transport features of a non-Markovian process are explored. It is found that: (1) due to the effect of infrared divergence the diffusion coefficient, the mobility, and the viscosity as well as the generalized MD relation (MD) (i.e., Nernst-Einstein relation) and the generalized DV relation (DV) which exist among these coefficients, in general, are dispersive and the degree of the dispersion depends on a single parameter n, the infrared divergence exponent. If n goes to zero, all results immediately reduce to the classical forms; (2) the MV relation, neither depending on the nature of the transport process nor on the structure of the medium, seems to be generally valid and (3) the functional form of the generalized diffusion coefficient is identical with that of the generalized mobility, and that of the MD relation with that of the DV relation. The prediction of the dispersive diffusion is in good agreement with the recent experiment. The MD relation has been surmised ought to exist. If it exists, the prediction of dispersive mobility would be true.
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  • 文章访问数:  6585
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  • 被引次数: 0
出版历程
  • 收稿日期:  1984-04-25
  • 刊出日期:  1985-03-05

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