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In this paper we report on a new kind of tri-color luminescence glass which can be excited efficiently by long-wavelength ultraviolet. These samples are prepared by melting silicon-borate raw material co-doped with Ce3+/Mn2+, Ce3+/Tb3+ and Eu2+, respectively. Among these doped ions, Mn2+, Tb3+ and Eu2+ are activators and Ce3+ is sensibilizer. Because the sencibilzer can provide energy for activator so the intense tri-color luminescence can be obtained by long-wavelength ultraviolet excitation. At the same time, the role of Al in the fluorescence enhancement, the energy transfer process, and the control of the ions valence are discussed.
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Keywords:
- tri-color luminescence /
- energy transfer /
- long-wavelength ultraviolet /
- luminescent glass
[1] Sun X Y Y, Zhang J H, Zhang X, Lu S Z, Wang X 2007 J.Lumin. 122 955
[2] Jayasimhadri M, Jang K, Lee H, Chen B, Yi S, Jeong J 2009 J. Appl. Phys. 106 3105
[3] Chen D P, Miyoshi H, Akai T, Yazawa T 2005 Appl. Phys. Lett. 86 231908
[4] Liu W, Chen D P, Miyoshi H, Kadono K, Akai T 2005 Chem. Lett. 34 1176
[5] Silversmith A J, Boye D M, Brewer K S, Gillespie C E, Lu Y, Campbell D L 2006 J.Lumin. 121 14
[6] Yang L Y, Yamashita M, Akai T 2009 Opt. Express 17 6688
[7] Babu P, Jang K H, Kim E S, Shi L, Seo H J, Lopez F E, Rodriguez-Mendoza U R, Lavin V, Vijaya R, Jayasankarm C K, Moorthy L R 2009 J. Appl. Phys. 105 013516
[8] Luo Q, Qiao X, Fan X, Yang H, Zhang X, Cui S, Wang L, Wang G 2009 J. Appl. Phys. 105 043506
[9] Gouveia-Neto A S, Bueno L A, do Nascimento R F, da Silva E A, da Costa E B, do Nascimento V B 2007 Appl. Phys. Lett. 91 091114
[10] Liu S, Zhao G, Lin X, Ying H, Liu J, Wang J, Han G 2008 J. Solid State Chem. 181 2725
[11] Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese)[杨志平、刘玉峰、王利伟、余泉茂、熊志军、徐小岭 2007 物理学报 56 546]
[12] Dexter D C 1953 J. Chem. Phys. 21 836
[13] Zhang J C, Parent C, le Flem G, Hagenmuller P 1991 J. Solid State Chem. 93 17
[14] Liu X Z, Wang Z K, Wang X J 1989 Acta Phys. Sin. 38 430 (in Chinese) [刘行仁、王宗凯、王晓君 1989 物理学报 38 430]
[15] Wang Z J, Li P L, Wang Y, Yang Z P, Guo Q L 2009 Acta Phys. Sin. 58 1257 (in Chinese) [王志军、李盼来、王 颖、杨志平、郭庆林 2009 物理学报 58 1257]
[16] Duffy J A, Ingram M D 1976 J. Non-Cryst. Solids 21 373
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[1] Sun X Y Y, Zhang J H, Zhang X, Lu S Z, Wang X 2007 J.Lumin. 122 955
[2] Jayasimhadri M, Jang K, Lee H, Chen B, Yi S, Jeong J 2009 J. Appl. Phys. 106 3105
[3] Chen D P, Miyoshi H, Akai T, Yazawa T 2005 Appl. Phys. Lett. 86 231908
[4] Liu W, Chen D P, Miyoshi H, Kadono K, Akai T 2005 Chem. Lett. 34 1176
[5] Silversmith A J, Boye D M, Brewer K S, Gillespie C E, Lu Y, Campbell D L 2006 J.Lumin. 121 14
[6] Yang L Y, Yamashita M, Akai T 2009 Opt. Express 17 6688
[7] Babu P, Jang K H, Kim E S, Shi L, Seo H J, Lopez F E, Rodriguez-Mendoza U R, Lavin V, Vijaya R, Jayasankarm C K, Moorthy L R 2009 J. Appl. Phys. 105 013516
[8] Luo Q, Qiao X, Fan X, Yang H, Zhang X, Cui S, Wang L, Wang G 2009 J. Appl. Phys. 105 043506
[9] Gouveia-Neto A S, Bueno L A, do Nascimento R F, da Silva E A, da Costa E B, do Nascimento V B 2007 Appl. Phys. Lett. 91 091114
[10] Liu S, Zhao G, Lin X, Ying H, Liu J, Wang J, Han G 2008 J. Solid State Chem. 181 2725
[11] Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese)[杨志平、刘玉峰、王利伟、余泉茂、熊志军、徐小岭 2007 物理学报 56 546]
[12] Dexter D C 1953 J. Chem. Phys. 21 836
[13] Zhang J C, Parent C, le Flem G, Hagenmuller P 1991 J. Solid State Chem. 93 17
[14] Liu X Z, Wang Z K, Wang X J 1989 Acta Phys. Sin. 38 430 (in Chinese) [刘行仁、王宗凯、王晓君 1989 物理学报 38 430]
[15] Wang Z J, Li P L, Wang Y, Yang Z P, Guo Q L 2009 Acta Phys. Sin. 58 1257 (in Chinese) [王志军、李盼来、王 颖、杨志平、郭庆林 2009 物理学报 58 1257]
[16] Duffy J A, Ingram M D 1976 J. Non-Cryst. Solids 21 373
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