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物理学报. 2007, 56(5): 2962-2967.
doi: 10.7498/aps.56.2962.
用偏振荧光光谱表征乙醇-水团簇分子的取向行为
- 收稿日期: 2006-08-19
- 修回日期: 2006-09-27
- 刊出日期: 2007-05-20
English Abstract
Characterization of the orientation of ethanol-water clusters by polarized fluorescence spectrum
- Received Date:
19 August 2006
- Accepted Date:
27 September 2006
- Published Online:
20 May 2007
Abstract: The fluorescence spectra of the ethanol-water mixture excited by 236nm UV-light and the polarization of the fluorescence are investigated respectively. With different polarization degree of an incident light, the fluorescence was collected between 300nm and 400nm both in horizontal and vertical polarization direction. The experimental result shows that the fluorescence, emitted from the ethanol-water solution when excited by linearly polarized light, is a polarized light and its polarization degree is calculated too. By analyzing theoretically, the Stokes vector of the fluorescence polarization condition has been obtained, and the polarization condition is testified. By calculating Mueller matrix of the solution, the orientation characteristic of ethanol-water cluster molecules has been analyzed. The research can contribute to the study of the new molecule clusters of ethanol-water.
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