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基于激光诱导击穿光谱技术, 利用Nd:YAG脉冲激光激发Al2O3 (含量为99%)陶瓷片产生等离子体, 获得了AlO自由基B2+X2+跃迁的33条发射谱线. 就AlO自由基光谱的时间演化规律和激光能量对谱线的影响规律进行了研究与分析. 结果表明, AlO自由基光谱出现在Al原子和Al离子光谱之后, 且持续时间较长. 当激光的脉冲能量由10 mJ起不断增加时, AlO自由基光谱强度逐渐减小, 且最大值出现时间随激光能量的增加而后移. 在此基础上, 进行了陶瓷等离子体在空气和氩气环境下的对比试验, 发现从Al2O3陶瓷片中激发所产生的AlO自由基必须有空气中O2参与反应.
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关键词:
- 激光诱导击穿光谱 /
- AlO自由基 /
- B2+X2+跃迁光谱
Based on laser-induced breakdown spectroscopy, a short pulse laser is used to excite Al2O3 (content of 99%) ceramic to produce ceramic plasma. The plasma emission spectrum is collected, and 33 spectral lines of AlO radical B2+X2+ transition are obtained. The time-resolved AlO radical spectrum and its relationship with laser pulse energy are investigated. The results show that the emission spectrum of AlO radical appears later and lasts longer than those of Al atom and Al ion. With the increase of the laser pulse energy, the spectral intensity of AlO radical decreases and the time when the maximum spectral intensity appears moves backward. Finally, the ceramic plasma produced in air is compared with that produced in Ar environment. The results prove that the formation of AlO radical spectrum has an important relationship with O2 in air.[1] Lu C P, Liu W Q, Zhao N J, Liu L T, Chen D, Zhang Y J, Liu J G 2011 Acta Phys. Sin. 60 045206 (in Chinese) [卢翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国 2011 物理学报 60 045206]
[2] Nakimana A, Tao H Y, Hao Z Q, Sun C K, Gao X, Lin J Q 2013 Chin. Phys. B 22 014209
[3] Zhang D C, Ma X W, Zhu X L, Li B, Zu K L 2008 Acta Phys. Sin. 57 6348 (in Chinese) [张大成, 马新文, 朱小龙, 李斌, 祖凯玲 2008 物理学报 57 6348]
[4] Parigger C G 2013 Spectrochim. Acta B 79 4
[5] Zhang D C, Ma X W, Wen W Q, Zhang P J, Zhu X L, Li B, Liu H P 2010 Chin. Phys. Lett. 27 063202
[6] Guo L B, Li C M, Hu W, Zhou Y S, Zhang B Y, Cai Z X, Zeng X Y, Lu Y F 2011 Appl. Phys. Lett. 98 131501
[7] Abdellatif G, Imam H 2002 Spectrochim. Acta B 57 1155
[8] Guo L B, Hu W, Zhang B Y, He X N, Li C M, Zhou Y S, Cai Z X, Zeng X Y, Lu Y F 2011 Opt. Express 19 14067
[9] Portnov A, Rosenwaks S, Bar I 2003 Appl. Opt. 42 2835
[10] Baudelet M, Boueri M, Yu J, Mao S S, Piscitelli V, Mao X L, Russo R E 2007 Spectrochim. Acta B 62 1329
[11] Vivien C, Hermann J, Perrone A, Leborgne C B, Luches A 1998 Appl. Phys. 31 1263
[12] Ma J, Li A, Li C Y 2003 J. Anhui Normal Univ. 26 133 (in Chinese) [马靖, 李昂, 李春燕 2003 安徽师范大学学报 26 133]
[13] Ming D, Fan Q C, Sun W G 2011 J. Xihua Univ. 30 21 (in Chinese) [明东, 樊群超, 孙卫国 2011 西华大学学报 30 21]
[14] Jones M R, Brewster M Q 1991 J. Quant. Spectrosc. Radiat. Transfer 46 109
[15] Li Z N, Wang Y G, Hu D, Gou Q Q 1996 Chin. J. At. Mol. Phys. 13 312 (in Chinese) [李招宁, 王永国, 胡栋, 苟清泉 1996 原子与分子物理学报 13 312]
[16] Jin J, Chen Y, Pei L S, Hu C J, Ma X X, Chen C X 2000 Acta Phys. Sin. 49 1689 (in Chinese) [金瑾, 陈旸, 裴林森, 胡长进, 马兴孝, 陈从香 2000 物理学报 49 1689]
[17] Peng Z M, Yang Q S, Liu C, Zhu N Y, Jiang Z L 2010 Spectrosc. Spec. Anal. 30 865 (in Chinese) [彭志敏, 杨乾锁, 刘春, 竺乃宜, 姜宗林 2010光谱学与光谱分析 30 865]
[18] Liu Y H, Chen M, Liu X D, Cui Q Q, Zhao M W 2013 Acta Phys. Sin. 62 025203 (in Chinese) [刘月华, 陈明, 刘向东, 崔清强, 赵明文 2013 物理学报 62 025203]
[19] Xiong Y, Chen Y K, Chang X L 1986 J. Yunnan Univ. 8 264 (in Chinese) [熊烨, 陈永康, 长校良 1986 云南大学学报 8 264]
[20] Xu C C, Guo S J 1989 Atomic and Molecular Spectroscopy (Dalian: Dalian University of Technology Press) p243 (in Chinese) [许长存, 过巳吉 1989 原子和分子光谱学(大连: 大连理工大学出版社)第243页]
[21] Lee S H, Yoh J J 2012 Appl. Spectrosc. 66 107
[22] Hahn D W, Omenetto N 2012 Appl. Spectrosc. 66 387
[23] Messaci S A, Kerdja T, Bendib A, Malek S 2005 Spectrochim. Acta B 60 959
[24] Varenne O, Fournier P G, Fournier J, Boujemaa B, Fake A I, Rostas J, Taieb G 2000 Nucl. Instrum. Meth. Phys. Res. B 171 259
[25] Kasatani K, Higashide H, Shinoara H, Sato H 1990 Chem. Phys. Lett. 174 71
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[1] Lu C P, Liu W Q, Zhao N J, Liu L T, Chen D, Zhang Y J, Liu J G 2011 Acta Phys. Sin. 60 045206 (in Chinese) [卢翠萍, 刘文清, 赵南京, 刘立拓, 陈东, 张玉钧, 刘建国 2011 物理学报 60 045206]
[2] Nakimana A, Tao H Y, Hao Z Q, Sun C K, Gao X, Lin J Q 2013 Chin. Phys. B 22 014209
[3] Zhang D C, Ma X W, Zhu X L, Li B, Zu K L 2008 Acta Phys. Sin. 57 6348 (in Chinese) [张大成, 马新文, 朱小龙, 李斌, 祖凯玲 2008 物理学报 57 6348]
[4] Parigger C G 2013 Spectrochim. Acta B 79 4
[5] Zhang D C, Ma X W, Wen W Q, Zhang P J, Zhu X L, Li B, Liu H P 2010 Chin. Phys. Lett. 27 063202
[6] Guo L B, Li C M, Hu W, Zhou Y S, Zhang B Y, Cai Z X, Zeng X Y, Lu Y F 2011 Appl. Phys. Lett. 98 131501
[7] Abdellatif G, Imam H 2002 Spectrochim. Acta B 57 1155
[8] Guo L B, Hu W, Zhang B Y, He X N, Li C M, Zhou Y S, Cai Z X, Zeng X Y, Lu Y F 2011 Opt. Express 19 14067
[9] Portnov A, Rosenwaks S, Bar I 2003 Appl. Opt. 42 2835
[10] Baudelet M, Boueri M, Yu J, Mao S S, Piscitelli V, Mao X L, Russo R E 2007 Spectrochim. Acta B 62 1329
[11] Vivien C, Hermann J, Perrone A, Leborgne C B, Luches A 1998 Appl. Phys. 31 1263
[12] Ma J, Li A, Li C Y 2003 J. Anhui Normal Univ. 26 133 (in Chinese) [马靖, 李昂, 李春燕 2003 安徽师范大学学报 26 133]
[13] Ming D, Fan Q C, Sun W G 2011 J. Xihua Univ. 30 21 (in Chinese) [明东, 樊群超, 孙卫国 2011 西华大学学报 30 21]
[14] Jones M R, Brewster M Q 1991 J. Quant. Spectrosc. Radiat. Transfer 46 109
[15] Li Z N, Wang Y G, Hu D, Gou Q Q 1996 Chin. J. At. Mol. Phys. 13 312 (in Chinese) [李招宁, 王永国, 胡栋, 苟清泉 1996 原子与分子物理学报 13 312]
[16] Jin J, Chen Y, Pei L S, Hu C J, Ma X X, Chen C X 2000 Acta Phys. Sin. 49 1689 (in Chinese) [金瑾, 陈旸, 裴林森, 胡长进, 马兴孝, 陈从香 2000 物理学报 49 1689]
[17] Peng Z M, Yang Q S, Liu C, Zhu N Y, Jiang Z L 2010 Spectrosc. Spec. Anal. 30 865 (in Chinese) [彭志敏, 杨乾锁, 刘春, 竺乃宜, 姜宗林 2010光谱学与光谱分析 30 865]
[18] Liu Y H, Chen M, Liu X D, Cui Q Q, Zhao M W 2013 Acta Phys. Sin. 62 025203 (in Chinese) [刘月华, 陈明, 刘向东, 崔清强, 赵明文 2013 物理学报 62 025203]
[19] Xiong Y, Chen Y K, Chang X L 1986 J. Yunnan Univ. 8 264 (in Chinese) [熊烨, 陈永康, 长校良 1986 云南大学学报 8 264]
[20] Xu C C, Guo S J 1989 Atomic and Molecular Spectroscopy (Dalian: Dalian University of Technology Press) p243 (in Chinese) [许长存, 过巳吉 1989 原子和分子光谱学(大连: 大连理工大学出版社)第243页]
[21] Lee S H, Yoh J J 2012 Appl. Spectrosc. 66 107
[22] Hahn D W, Omenetto N 2012 Appl. Spectrosc. 66 387
[23] Messaci S A, Kerdja T, Bendib A, Malek S 2005 Spectrochim. Acta B 60 959
[24] Varenne O, Fournier P G, Fournier J, Boujemaa B, Fake A I, Rostas J, Taieb G 2000 Nucl. Instrum. Meth. Phys. Res. B 171 259
[25] Kasatani K, Higashide H, Shinoara H, Sato H 1990 Chem. Phys. Lett. 174 71
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