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弱磁场对Zn分枝状电解沉积物形貌的影响

罗成林 杨兵初 戎茂华

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弱磁场对Zn分枝状电解沉积物形貌的影响

罗成林, 杨兵初, 戎茂华

Influence of weak magnetic field on growth morphology of Zn branched electrodeposits

Luo Cheng-Lin, Yang Bing-Chu, Rong Mao-Hua
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  • 用金相显微镜和原子力显微镜分析了存在外加磁场情况下的Zn分枝状电解沉积物的微观形貌 ,并且根据实验结果提出了磁场使沉积物分枝呈现螺旋状偏转的机理.1)在沉积物晶粒的早 期生长阶段,当晶粒已经形成了择优生长方向但又非常小,仍然悬浮于电解液中时,磁流体 动力学对流作用于它上面的不平衡力使得晶粒连同它的择优生长方向向着对流下方偏转,直 到晶粒足够大,和它的前一个单晶枝晶连接在一起为止.2)当晶粒和它的前一个单晶枝晶连 接在一起以后,磁流体动力学对流的作用力已不足使它偏转.此时,如果电解液的浓度比较 高,单晶枝晶的一级分枝和二级分枝之间不存在对电解质的竞争关系,则此单晶枝晶将完全 按照初期形成的晶体择优生长方向直线生长,直到新的晶粒形核为止;如果电解液浓度较低 ,造成第一级分枝与第二级分枝的竞争关系,二级分枝总在第一级分枝的上游侧生长,使得 一级分枝向下游方向偏转.通过上述两个步骤,无论是枝晶沉积物还是分形沉积物都产生螺 旋状偏转.
    The influence of a weak magnetic field on the microstructure of the Zn electrode posits prepared in a thin concentric electrode cell is investigated. Mechanism o f the effect of the magnetohydrodynamic (MHD) flow on the morphological transiti on is proposed through experimental evidences. 1) In the early growth phase of a crystallite, the unbalanced force caused by the MHD flow on the crystallite, wh ich suspends in the electrolyte close to the previous branch, rotates its prefer ential growth orientation towards the downstream of the MHD flow; 2) A stable co ncentration profile is formed in the vicinity of the electrodeposits by the MHD flow. After the crystallite grows large enough to stick on its previous branch, and the concentration of the electrolyte is high enough for both the primary bra nch and its secondary branches, the single-crystalline dendrites will grow strai ght. But if the concentration of the electrolyte is small, the secondary branche s crowd to the side facing the upstream of the MHD flow and the primary branch i s forced to bend towards the downstream of the MHD flow. A spiral structure in t he branched electrodeposits grown in a magnetic field is formed by this mechanis m.
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出版历程
  • 收稿日期:  2005-03-24
  • 修回日期:  2005-09-01
  • 刊出日期:  2006-03-20

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