β-Zn4Sb3/Zn1-δAlδO复合材料的制备及热电性能研究

周丽梅; 李炜; 蒋俊; 陈建敏; 李勇; 许高杰

doi:10.7498/aps.60.067201

摘要

采用真空熔融淬火结合放电等离子烧结工艺制备了单相β-Zn4Sb3以及β-Zn4Sb3/Zn1-δAlδO复合热电材料,其中第二相Zn1-δAlδO(AZO)的含量分别为0.2 wt%,0.4 wt%和0.7 wt%.对材料的相组成和微结构进行了表征,并在300—673 K的温度

关键词:

Single-phased β-Zn4Sb3 and β-Zn4Sb3/ Zn1-δAlδO composites with different amounts of Zn1-δAlδO (AZO) are prepared by the combination of vacuum melting and spark plasma sintering (SPS). Thermoelectric properties of the materials are investigated in a temperature range from 300 K to 673 K. As a result, the electrical conductivity of each sample increases while the Seebeck coefficient and the thermal conductivity decrease with the increase of AZO. The maximum ZT value of the composite reaches 1.16 at 673 K when the amount of AZO is 0.2 wt%, which is higher than that for the single-phased β-Zn4Sb3 (1.03).

Keywords:

作者及机构信息

1.
中国科学院宁波材料技术与工程研究所,宁波 315201

基金项目: 国家自然科学基金(批准号:50802102)、宁波市自然科学基金(批准号:2009A610013)和国家高技术研究发展计划(批准号:2009AA03Z210)资助的课题.

Authors and contacts

1.
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

参考文献

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[4]	Li K Z, Liang R S, Wei Z J 2008 Chin. Phys. B 17 1349
[5]	Deng S K, Tang X F, Tang R S 2009 Chin. Phys. B 18 3084
[6]	Xiong C, Deng S K, Tang X F, Qi Q, Zhang Q J 2008 Acta Phys. Sin. 57 1190 (in Chinese) [熊聪、邓书康、唐新峰、祁琼、张清杰 2008 物理学报 57 1190]
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[16]	Nylen J, Lidin S, Andersson M, Liu H X, Newman N, Hussermann U 2007 J. Solid State Chem. 180 2603
[17]	Liu F, Qin X Y, Liu M 2009 Chin. Phys. B 18 4386
[18]	Tsutsui M, Zhang L T, Ito K, Yamaguchi M 2004 Intermetallics 12 809
[19]	Cui J L, Fu H, Chen D Y, Mao L D, Liu X L, Yang W 2009 Mater. Charact. 60 824
[20]	Nakamoto G, Souma T, Yamaba M, Kurisu M 2004 J. Alloys Compd. 377 59
[21]	Li W, Zhou L M, Li Y L, Jiang J, Xu G J 2009 J. Alloys Compd. 486 335
[22]	Qi Q, Tang X F, Xiong C, Zhao W Y, Zhang Q J 2006 Acta Phys. Sin. 55 5539 (in Chinese) [祁琼、唐新峰、熊聪、赵文瑜、张清杰 2006 物理学报 55 5539]
[23]	Ueno K, Yamamoto A, Noguchi T, Li C H, Inoue T, Sodeoka S, Obara H 2006 J. Alloys Compd. 417 259
[24]	Cui J L, Mao L D, Chen D Y, Qian X, Liu X L, Yang W 2009 Curr. Appl. Phys. 9 713
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施引文献

[1]	Tang X F, Chen L D, Goto T, Hirai T, Yuan R Z 2002 Acta Phys. Sin. 51 2823 (in Chinese) [唐新峰、陈立东、後藤孝、平井敏雄、袁润章 2002 物理学报 51 2823]
[2]	Disalvo F J 1999 Science 285 703
[3]	Cao W Q, Yan Y G, Tang X F 2010 Acta Phys. Sin. 59 630 (in Chinese) [曹卫强、鄢永高、唐新峰 2010 物理学报 59 630]
[4]	Li K Z, Liang R S, Wei Z J 2008 Chin. Phys. B 17 1349
[5]	Deng S K, Tang X F, Tang R S 2009 Chin. Phys. B 18 3084
[6]	Xiong C, Deng S K, Tang X F, Qi Q, Zhang Q J 2008 Acta Phys. Sin. 57 1190 (in Chinese) [熊聪、邓书康、唐新峰、祁琼、张清杰 2008 物理学报 57 1190]
[7]	Chen X Y, Xu X F, Hu R X, Ren Z, Xu Z A, Cao G H 2007 Acta Phys. Sin. 56 1627 (in Chinese) [陈晓阳、徐象繁、胡荣星、任之、许祝安、曹光旱 2007 物理学报 56 1627]
[8]	Zhang X, Li J, Lu Q M, Zhang J X, Liu Y Q 2008 Acta Phys. Sin. 57 4466 (in Chinese) [张忻、李佳、路清梅、张久兴、刘燕琴 2008 物理学报 57 4466]
[9]	Slack G A, Tsoukala V G 1994 J. Appl. Phys. 76 1665
[10]	Snyder G J, Christensen M, Nishibori E, Caillat T, Iversen B B 2004 Nat. Mater. 3 458
[11]	Caillat T, Borshchevsky A, Fleurial J P 2005 US Patent 6942728B2
[12]	Mozharivskyj Y, Pecharsky A O, Bud’ko S 2004 Chem. Mater. 16 1580
[13]	Caillat T, Fleurial J P, Borshchevsky A 1997 J. Phys. Chem. Solids 58 1119
[14]	Chitroub M, Besse F, Scherrer H 2008 J. Alloys Compd. 460 90
[15]	Pedersen B L, Birkedal H, Nygren M, Frederiksen P T, Iversen B B 2009 J. Appl. Phys. 105 013517
[16]	Nylen J, Lidin S, Andersson M, Liu H X, Newman N, Hussermann U 2007 J. Solid State Chem. 180 2603
[17]	Liu F, Qin X Y, Liu M 2009 Chin. Phys. B 18 4386
[18]	Tsutsui M, Zhang L T, Ito K, Yamaguchi M 2004 Intermetallics 12 809
[19]	Cui J L, Fu H, Chen D Y, Mao L D, Liu X L, Yang W 2009 Mater. Charact. 60 824
[20]	Nakamoto G, Souma T, Yamaba M, Kurisu M 2004 J. Alloys Compd. 377 59
[21]	Li W, Zhou L M, Li Y L, Jiang J, Xu G J 2009 J. Alloys Compd. 486 335
[22]	Qi Q, Tang X F, Xiong C, Zhao W Y, Zhang Q J 2006 Acta Phys. Sin. 55 5539 (in Chinese) [祁琼、唐新峰、熊聪、赵文瑜、张清杰 2006 物理学报 55 5539]
[23]	Ueno K, Yamamoto A, Noguchi T, Li C H, Inoue T, Sodeoka S, Obara H 2006 J. Alloys Compd. 417 259
[24]	Cui J L, Mao L D, Chen D Y, Qian X, Liu X L, Yang W 2009 Curr. Appl. Phys. 9 713
[25]	Guan Z D, Zhang Z T, Jiao J S 1992 Physical Properties of Inorganic Material (Beijing: Tsinghua University Press) p265 (in Chinese)[关振铎、张中太、焦金生 1992 无机材料物理性能(北京:清华大学出版社)第265页]

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