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低维半导体偏振光探测器研究进展

魏钟鸣 夏建白

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低维半导体偏振光探测器研究进展

魏钟鸣, 夏建白

Recent progress in polarization-sensitive photodetectors based on low-dimensional semiconductors

Wei Zhong-Ming, Xia Jian-Bai
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  • 偏振光探测在遥感成像、环境监测、医疗检测和军事设备等领域都具有很好的应用价值, 目前已经有一系列偏振探测和成像产品. 随着信息器件进一步小型化、集成化, 基于新型低维材料的偏振光探测器可以直接利用材料本征的各向异性对偏振光进行感知, 在未来偏振光探测领域有很好的应用前景. 很多二维/一维半导体材料, 例如: 黑磷, ReS2, GaTe, GeSe, GeAs及ZrS3等, 都具有较强的本征面内各向异性, 可以用于高性能偏振光探测器. 基于此类低维半导体材料设计的不同结构类型的偏振光探测器已经覆盖了紫外、可见以及红外等多个波段. 本文总结了近年来相关领域的研究进展和我们课题组的一些工作.
    Polarized photodetection technology has good application value in the fields of remote sensing imaging, environmental monitoring, medical detection and military equipment. Polarized photodetectors based on low-dimensional materials can use the natural anisotropy of materials to detect polarized information. Some two-dimensional materials have strong in-plane anisotropy due to their low-symmetrical crystal structure, such as black-phosphorus, black-arsenic, ReS2, GaTe, GeSe, GeAs, and TiS3. These anisotropic two-dimensional materials are appropriate for the working medium of polarized photodetectors. Numerous researchs focused on polarized photodetectors with different materials and device structures and our works are introduced. Polarized photodetectors based on such low-dimensional materials have realized a broadband photodetection, including ultraviolet, visible, and infrared lights.
      通信作者: 魏钟鸣, zmwei@semi.ac.cn
    • 基金项目: 国家自然科学基金(批准号: 61622406).
      Corresponding author: Wei Zhong-Ming, zmwei@semi.ac.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 61622406).
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  • 图 1  黑磷的特性[50] (a)原子结构; (b)典型的偏振拉曼光谱; (c)三层黑磷的能带结构和理论计算的各向异性吸收

    Fig. 1.  Characteristics of black-phosphorus[50](Reproduced with permission, Copyright 2016, American Chemical Society): (a) Atomic structure; (b) typical polarized Raman spectra; (c) band structure of trilayer black-phosphorus and theoretical polarized absorption

    图 2  (a)圆形电极的偏振光探测器的显微镜照片[52]; (b) 沿扶手和锯齿方向400−1700 nm波长范围内黑磷的偏振光电流响应[52]; (c) 黑磷/MoS2异质结偏振光探测器[54]; (d)等离激元修饰的黑磷偏振光探测器[29]

    Fig. 2.  (a) Optical image of the polarized-light detector with the circular electrode, (b) polarized photoresponse along armchair and zigzag orientations under 400−1700 nm illumination of black-phosphorus (reproduced with permission[52], Copyright 2015, Springer Nature); (c) polarized-light detector based on the black-phosphorus/MoS2 heterojunction(reproduced with permission[54], Copyright 2018, Springer Nature); (d) polarized-light detectorenhanced by the plasmonic structure(reproduced with permission[29], Copyright 2018, American Chemical Society).

    图 3  原子结构 (a) ReS2[32]; (b) WTe2[71]

    Fig. 3.  Crystal structures: (a) ReS2(reproduced with permission[32], Copyright 2015, American Chemical Society); (b) WTe2(reproduced with permission[71], Copyright 2016, RSC Publishing).

    图 4  (a)偏振光电测试示意图[34]; (b) 极坐标下ReS2的偏振光吸收和光电流[33]; (c) ReS2/ReSe2异质结偏振光响应[79]; (d) WTe2偏振光探测性能[35]

    Fig. 4.  (a) Schematic of polarized photoelectric test(reproduced with permission[34], Copyright 2016, American Chemical Society); (b) photocurrent and absorption of ReS2 in the polar coordinates(Reproduced with permission[33], Copyright 2016, John Wiley and Sons); (c) polarized photoresponse of ReS2/ReSe2 heterojunction(reproduced with permission[79], Copyright 2018, John Wiley and Sons); (d) polarized photoresponse of WTe2(reproduced with permission[35], Copyright 2018, John Wiley and Sons).

    图 5  (a) GaTe的晶体结构[80]; (b) TlSe的STEM图像[37]; (c) 基于TlSe的偏振光探测器的角分辨光电流[37]

    Fig. 5.  (a) Crystal structure of GaTe(reproduced with permission[80], Copyright 2016, American Chemical Society); (b) STEM image of TlSe and (c) photocurrent of the polarized photodetector based on TlSe (reproduced with permission[37], Copyright 2018, American Chemical Society).

    图 6  (a) MX晶体的原子结构[83]; (b) GeS2晶体的原子结构[41]; (c) SnS沿不同方向的光电流响应速度[38]; (d) GeSe2对450 nm偏振光响应[42]

    Fig. 6.  (a) Crystal structure of MX (reproduced with permission[83], Copyright 2015, AIP Publishing); (b) crystal structure of GeS2(reproduced with permission[41], Copyright 2019, John Wiley and Sons); (c) response times of SnS along different directions(reproduced with permission[38], Copyright 2017, Royal Society of Chemistry); (d) polarized photocurrent of GeSe2 under the 450 nm illumination(reproduced with permission[42], Copyright 2018, American Chemical Society).

    图 7  (a) GeAs, SiAs, GeP和SiP的晶体结构; (b) GeAs2的晶体结构[45]

    Fig. 7.  (a) Crystal structures of GeAs, SiAs, GeP, and Si; (b) crystal structures of GeAs2 (reproduced with permission[45], Copyright 2018, John Wiley and Sons).

    图 8  (a) ZrS3的光学图像[46]; (b) ZrS3的晶体结构[46]; (c) KP15原子结构示意图[99]

    Fig. 8.  (a) Optical image of ZrS3 and (b) crystal structure of ZrS3(reproduced with permission[46], Copyright 2019, John Wiley and Sons); (c) crystal structure of KP15(reproduced with permission[99], Copyright 2018, American Chemical Society).

    图 9  (a) GeSe的偏振光吸收谱[40]; (b) 不同方向的偏振光下准一维ZrS3纳米带的吸收光谱[46]; (c)准一维ZrS3纳米带在450 nm和532 nm的激光下的偏振光电流[46]

    Fig. 9.  (a) Polarization-resolved absorption spectra of GeSe(reproduced with permission[40], Copyright 2017, American Chemical Society); (b) absorption spectra of ZrS3 nanoribbon under polarized light in different directions and (c) polarized photocurrent of ZrS3 nanoribbon under 450 nm and 532 nm laser illumination(reproduced with permission[46], Copyright 2019, John Wiley and Sons).

    图 10  (a) GeSe对808 nm光照的偏振光电流[40]; (b) GeAs偏振光吸收光谱图[43]; (c) GeAs在520 nm和830 nm偏振光照射下的光响应极坐标图[43]; (d) GeAs 30 mV栅压下角度依赖的空间分辨光响应分布图[43]

    Fig. 10.  (a) Polarized photocurrent of GeSe under the 808 nm laser illumination(reproduced with permission[40], Copyright 2017, American Chemical Society); (b) polarization-resolved absorption spectra of GeAs, (c) polarization-sensitive photocurrents plotted with the linear-polarization laser of 520 and 830 nm of GeAs in the polar coordinates, and (d) polarization-dependent photocurrent mapping of GeAs device under 30 mV gate voltage and the linear-polarization laser (reproduced with permission[43], Copyright 2018, American Chemical Society).

    表 1  低维半导体材料的各向异性光电性能

    Table 1.  Anisotropic optoelectronic properties of low-dimensional semiconductors.

    禁带宽度/eV载流子迁移率/cm2·V–1·s–1光响应强度二向色性比值参考文献
    黑磷0.3 (体材料)
    1.5 (单层)
    1000 (空穴, x)600 (空穴, y)14.2 mA/W8.7 (1550 nm)[29]
    黑砷0.3 (体材料)1—
    1.5 (单层)
    376.7 (电子, zigzag)1.5 (电子, armchair)
    60.7 (空穴, zigzag)10606 (空穴, armchair)
    [14,30]
    锑烯1.3—1.7100 (3.2 eV)[31]
    ReS21.4 (体材料)23.1 (电子, DS-chains方向)14.8 (电子, 垂直DS-chains方向)103 A·W–1 (532 nm)~ 4[32,33]
    ReSe21.17—1.2101.5 mA·W–1 (633 nm)2 (633 nm)[34]
    MoTe2外尔半金属110 mA·W–1 (1064 nm)[10]
    WTe2外尔半金属4.9 (514.5 nm)[35]
    GaTe1.70.2 (空穴)104 A·W–1 (532 nm)[36]
    TlSe0.731.48 A·W–1 (633 nm)2.56 (633 nm)[37]
    SnS1.320 (zisgzag)μzigzagarmchair ≈ 1.7365 A·W–1 (808 nm)1.49 (808 nm)[38,39]
    GeSe1.34 (体材料)
    1.7 (单层)
    4.25 A·W–12.16 (808 nm)[40]
    GeS2> 32.1 (325 nm)[41]
    GeSe22.743.4 (450 nm)[42]
    GeAs0.83 (体材料)
    2.07 (单层)
    4.4 (808 nm)[43]
    GeP0.51 (体材料)
    1.68 (单层)
    电导率比值: 1.523.11—0.43 A·W–11.83 (532 nm)[44]
    GeAs20.98 (体材料)
    1.62 (单层)
    2.5 (空穴, a)1.3 (空穴, b)2[45]
    ZrS31.79 (体材料)230 m A·W–1 (520 nm)2.55 (520 nm)[46]
    TiS31.132500 A·W–1 (808 nm)4[47]
    α-MoO32.70.06–0.09 (电子, b)0.03—0.04 (电子, c)67.9 A·W–15 (254 nm)[12]
    下载: 导出CSV
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出版历程
  • 收稿日期:  2019-06-29
  • 修回日期:  2019-08-12
  • 上网日期:  2019-08-19
  • 刊出日期:  2019-08-20

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