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Bulk metallic glass has aroused intensive interest due to its unique atomic structure and properties, while its structural application is restricted by the shortcomings of its mechanical properties-room temperature brittleness and strain softening. To make up for these shortcomings, various approaches have been proposed, including tailoring intrinsic parameters such as elastic modulus and structural heterogeneity, and changing stress state or defect concentration. Bulk metallic glass composites with ex-situ added or in-situ formed crystallites have been fabricated, series of bulk metallic glasses and their composites with good mechanical properties have been designed, especially TRIP (Transformation-induced plasticity)-reinforced bulk metallic glass composites with large tensile ductility and work-hardening. In this paper, we review the ductilization of bulk metallic glass and its composites, as well as the related mechanism. Particularly, fabrication, properties, structure control and the ductilization mechanism of TRIP-reinforced bulk metallic glass composite are introduced in detail. A perspective of the challenges of ductilization of bulk metallic glassy materials is also mentioned briefly.
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Keywords:
- bulk metallic glasses /
- ductilization /
- transformation-induced plasticity /
- glass-forming ability
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[1] Peker A, Johnson W L 1993 Appl. Phys. Lett. 63 2342
[2] Sheng H W, Luo W K, Alamgir F M, Bai J M, Ma E 2006 Nature 439 419
[3] Schuh C A, Hufnagel T C, Ramamurty U 2007 Acta Mater. 55 4067
[4] Inoue A 2000 Acta Mater. 48 279
[5] Zhang Z F, Eckert J, Schultz L 2003 Acta Mater. 51 1167
[6] Greer A L, Cheng Y Q, Ma E 2013 Mater. Sci. Eng. A 74 71
[7] Spaepen F 1977 Acta Metall. 25 407
[8] Pan J, Liu L, Chan K C 2009 Scr. Mater. 60 822
[9] Park E S, Kim D H 2006 Acta Mater. 54 2597
[10] Fan C, Li C, Inoue A, Haas V 2000 Phys. Rev. B 61 R3761
[11] Chen M W, Inoue A, Zhang W, Sakurai T 2006 Phys. Rev. Lett. 96 245502
[12] Schroers J, Johnson W L 2004 Phys. Rev. Lett. 93 255506
[13] Cheng J L, Chen G, Liu C T, Li Y 2013 Sci. Rep. 3 2097
[14] Hui X, Dong W, Chen G L, Yao K F 2007 Acta Mater. 55 907
[15] Qiao J W, Wang S, Zhang Y, Liaw P K, Chen G L 2009 Appl. Phys. Lett. 94 151905
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[18] Conner R D, Dandliker R B, Johnson W L 1998 Acta Mater. 46 6089
[19] Chu X M, Liu X J, Nieh T G, Lu Z P 2013 Compos. Sci. Technol. 75 49
[20] Wang Z T, Pan J, Li Y, Schuh C A 2013 Phys. Rev. Lett. 111 135504
[21] Sarac B, Schroers J 2013 Nat. Cummun. 4 2158
[22] Hofmann D C, Suh J Y, Wiest A, Duan G, Lind M L, Demetriou M D, Johnson W L 2008 Nature 451 1085
[23] Wu Y, Xiao Y H, Chen G L, Liu C T, Lu Z P 2010 Adv. Mater. 22 2770
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[42] Argon A S 1979 Acta Metall. 27 47
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