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中国物理学会期刊

振荡场作用下聚合物/纳米棒混合体系的自组装

CSTR: 32037.14.aps.72.20222207

The self-assembly behavior of polymer/nanorods hybrid system under oscillation field

CSTR: 32037.14.aps.72.20222207
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  • 采用元胞动力学和布朗动力学联用方法研究了振荡场作用下两嵌段共聚物/均聚物/纳米棒混合体系的自组装相行为. 通过计算模拟, 探讨了振荡场的振幅和频率对混合体系相形貌形成和演化的影响. 研究发现振荡场对体系有序结构的形成和转变有重要作用, 随着外加振荡场频率的增大, 混合体系形貌从平行于场方向的条纹结构过渡到斜层状结构再转变为垂直于场方向的条纹结构. 进一步分析了振荡场作用下体系畴尺寸的演化及纳米棒取向角的变化情况. 研究结果为制备和调控聚合物纳米复合材料有序结构提供了新的方法和参考.

     

    The self-assembly behavior of diblock copolymer/homopolymer/nanorods hybrid system under oscillation field is performed by using Cell Dynamics Scheme (CDS) and Brownian Dynamics (BD). The effects of the amplitude and frequency of the oscillation field on the formation and evolution of the mixture morphology are investigated systematically. It is found that the oscillation field plays an important role in the formation and transformation of the ordered structure. With the frequency increasing, the orientation of the lamellar structure transforms from parallel to the field direction to random angle and then to perpendicular to the field direction. Compared with the pure rod system, the addition of polymers has a combing effect. Under high amplitude and low frequency ( \rm\omega \leqslant 0.01 ) of the oscillation field, the arrangement of nanorods transforms from vertical to horizontal. However, under high amplitude and high frequency ( \omega > 0.01 ), the nanorods change from vertical/horizontal hybrid arrangement to vertical arrangement. The evolution of domain size and orientation angle of nanorods under oscillation field are further analysed. The results provide a new method and reference for fabricating and regulating the ordered structure of polymer nanocomposites.

     

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