异常双钙钛矿A2BB'O6氧化物的多铁性

吴枚霞; 李满荣

doi:10.7498/aps.67.20180817

摘要

异常钙钛矿结构氧化物是多铁性材料家族中研究得最为广泛的体系之一.本文从ABO3钙钛矿结构出发，引入了异常A2BB'O6双钙钛矿材料，首先简要介绍了传统及异常A2BB'O6双钙钛矿氧化物的结构特点；然后讨论了A2BB'O6多铁性材料的研究进展，包括A位为Mn，Ni等过渡金属离子的极性磁体多铁性材料和A2CoMnO6（A=Lu，Y，Yb，Lu）以及Mn2FeSbO6等第Ⅱ类多铁性材料；最后，在以上基础上展望了异常A2BB'O6双钙钛矿多铁性研究中存在的问题及新型多铁性材料研究的方向.

关键词:

Abstract

Multiferroic material in which there co-exist at least two of the ferro-phases,namely ferroelectricity,(anti-) ferromagnetism,and ferroelasticity,has attracted considerable attention in recent years due to its intriguing physics and potential applications for advanced multifunctional devices.However,multiferroic materials are rare due to the contradictory requirements between electrical polarization and magnetism.So far,only several compounds have been reported to show above-room temperature multiferroics.Thus,it is essential to search for new materials.The two most significant strategies to obtain multiferroics are 1) to incorporate magnetic transition-metal ions into polar structures to obtain polar magnets,and 2) to introduce special magnetic structure to drive ferroelectricity (the so-called type-Ⅱ multiferroics).Exotic double perovskite-related oxide A2BB'O6 with small A-site cations is one of the most extensively studied multiferroic families in recent years. The small A-site cations give small perovskite tolerance factor (t),and mostly high-pressure synthesis is required to stabilize the exotic perovskite structure.The crystal structure of exotic A2BB' O6 oxides can crystallize into either the centrosymmetric alumina corundum (AL),ilmenite (IL),or distorted GdFeO3-type perovskite structure,or the polar LiNbO3(LN),Ni3TeO6(NTO),or ordered ilmenite (OIL) structure.The polar LN,NTO,and OIL structures can accommodate magnetic transition-metal ions at both the A and B/B'sites in octahedral coordination,giving enhanced magnetic interactions and thus robust magneto-electric effect and high spontaneous polarization as well (usually above 50 C/cm-2,more than twice that in the renown BaTiO3),examples include the LN-type Mn2FeNbO6,and Mn2FeTaO6,OIL-type Mn2FeMoO6,and NTO-type Mn2FeMoO6,Mn2FeWO6,and Mn2MnWO6.These polar magnets show potential multiferroic responses even above room temperature (e.g.,ferromagnetic ordering temperature up to 340 K in NTO-type Mn2FeMoO6) and magnetoelectric coupling effect as in Mn2MnWO6.Magnetoelectric coupling can also arise in centrosymmetric IL structure in the absence of helical spin structure,such as those that are observed in Mn2FeSbO6,which exhibits colinear ferrimagnetic spin arrangement but magnetostriction induced antiferroelectricity.The corundum derivatives (AL,LN,IL,OIL,and NTO) and perovskite phases are competitive,depending on the electron configuration and synthesis pressure,and usually higher pressure favors the formation of perovskite structure.Compared with polar magnets in the corundum family,the exotic double perovskite adopts distorted GdFeO3-type structure (P21/n) with eight-coordination of the A-sites.In some double perovskite materials,the electric polarization can be induced by the special magnetic order,such as the ⇈⇊ magnetic structure induced type-Ⅱ multiferroics exemplified by A2CoMnO6(A=Lu,Y,Yb,Lu).In this review paper,we first compare the structure features of conventional and exotic double perovskite A2BB'O6 derived from the simple ABO3 analog,then summarize the recent progress of multiferroics in exotic double perovskite family,such as the polar magnets with transition-metal (Mn and Ni) cations at the A sites,type-Ⅱ multiferroic Mn2FeSbO6,and A2CoMnO6(A=Lu,Y,Yb,Lu). Finally,the problems and prospection of multiferroics in exotic double perovskite A2BB'O6 are also discussed to give a reference for the future research.

Keywords:

作者及机构信息

1.
中山大学化学学院, 生物无机和合成化学教育部重点实验室, 广州 510275

通信作者: 李满荣, limanrong@mail.sysu.edu.cn

基金项目: 国家青年千人计划资助的课题.

Authors and contacts

1.
Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: Li Man-Rong, limanrong@mail.sysu.edu.cn

Funds: Project supported by One Thousand Youth Talents Program of China.

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[47]	Choi H Y, Moon J Y, Kim J H, Choi Y J, Lee N 2017 Crystals 7 67
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施引文献

[1]	Tian G, Zhang F, Yao J, Fan H, Li P, Li Z, Song X, Zhang X, Qin M, Zeng M, Zhang Z, Yao J, Gao X, Liu J 2016 ACS Nano 10 1025
[2]	Li H B, Lu N, Zhang Q, Wang Y, Feng D, Chen T, Yang S, Duan Z, Li Z, Shi Y, Wang W, Wang W H, Jin K, Liu H, Ma J, Gu L, Nan C, Yu P 2017 Nat. Commun. 8 2156
[3]	Zhou L, Dai J, Chai Y, Zhang H, Dong S, Cao H, Calder S, Yin Y, Wang X, Shen X, Liu Z, Saito T, Shimakawa Y, Hojo H, Ikuhara Y, Azuma M, Hu Z, Sun Y, Jin C, Long Y 2017 Adv. Mater. 29 1703435
[4]	Yu P, Chu Y, Ramesh R 2012 Phil. Trans. R. Soc. A 370 4856
[5]	Zhao L, Lu Z, Zhang F, Tian G, Song X, Li Z, Huang K, Zhang Z, Qin M, Wu S, Lu X, Zeng M, Gao X, Dai J, Liu J 2015 Sci. Rep. 5 9680
[6]	Khomskii D 2009 Physics 2 20
[7]	Wang Y, Pascut G L, Gao B, Tyson T A, Haule K, Kiryukhin V, Cheong S W 2015 Sci. Rep. 5 12268
[8]	Caignaert V, Maignan A, Singh K, Simon C, Pralong V, Raveau B, Mitchell J F, Zheng H, Huq A, Chapon L C 2013 Phys. Rev. B 88 174403
[9]	Ghara S, Suard E, Fauth F, Tran T T, Halasyamani P S, Iyo A, Rodrg uez-Carvajal J, Sundaresan A 2017 Phys. Rev. B 95 224416
[10]	Chi Z H, Jin C Q 2007 Prog. Phys. 27 225 (in Chinese) [迟振华, 靳常青 2007 物理学进展 27 225]
[11]	Wang K F, Liu J M, Wang Y 2009 Prog. Phys. 29 215 (in Chinese) [段纯刚 2009 物理学进展 29 215]
[12]	Sun Y 2014 Physics 43 166 (in Chinese) [孙阳 2014 物理 43 166]
[13]	Cheong S W, Mostovoy M 2007 Nat. Mater. 6 13
[14]	Fiebig M 2005 J. Phys. D: Appl. Phys. 38 R123
[15]	Dong S, Xiang H J 2014 Physics 43 173 (in Chinese) [董帅, 向红军 2014 物理 43 173]
[16]	Liu J M, Nan C W 2014 Physics 43 88 (in Chinese) [刘俊明, 南策文 2014 物理 43 88]
[17]	Smolenskii G A, Chupis I E 1982 Sov. Phys. Usp. 25 475
[18]	Bokov V, Mylnikova I, Smolenskii G 1962 Sov. Phys. Jetp-Ussr 15 447
[19]	Ivanov S A, Tellgren R, Rundlof H, Thomas N W, Ananta S 2000 J. Phys.: Condens. Matter 12 2393
[20]	Wang J, Neaton J, Zheng H, Nagarajan V, Ogale S, Liu B, Viehland D, Vaithyanathan V, Schlom D, Waghmare U 2003 Science 299 1719
[21]	Dho J, Qi X, Kim H, MacManus-Driscoll J L, Blamire M G 2006 Adv. Mater. 18 1445
[22]	Azuma M, Takata K, Saito T, Ishiwata S, Shimakawa Y, Takano M 2005 J. Am. Chem. Soc. 127 8889
[23]	Nechache R, Cojocaru C V, Harnagea C, Nauenheim C, Nicklaus M, Ruediger A, Rosei F, Pignolet A 2011 Adv. Mater. 23 1724
[24]	Shi L, Bai F M 2011 J. Chin. Cera. Soc. 39 550 (in Chinese) [石雷, 白飞明 2011 硅酸盐学报 39 550]
[25]	Kwei G H, Lawson A C, Billinge S J L, Cheong S W 1993 J. Phys. Chem. 97 2368
[26]	Cai G H, Greenblatt M, Li M R 2017 Chem. Mater. 29 5447
[27]	Živkovi I, Pra K, Zaharko O, Berger H 2010 J. Phys.: Condens. Matter 22 056002
[28]	Oh Y S, Artyukhin S, Yang J J, Zapf V, Kim J W, Vanderbilt D, Cheong S W 2014 Nat. Commun. 5 3201
[29]	Ivanov S A, Mathieu R, Nordblad P, Tellgren R, Ritter C, Politova E, Kaleva G, Mosunov A, Stefanovich S, Weil M 2013 Chem. Mater. 25 935
[30]	Solana-Madruga E, Dos santos-Garcia A J, Arvalo-Lpez A M, vila-Brande D, Ritter C, Attfield J P, Sez-Puche R 2015 Dalton Trans. 44 20441
[31]	Li M R, McCabe E E, Stephens P W, Croft M, Collins L, Kalinin S V, Deng Z, Retuerto M, Gupta A S, Padmanabhan H, Gopalan V, Grams C P, Hemberger J, Orlandi F, Manuel P, Li W M, Jin C Q, Walker D, Greenblatt M 2017 Nat. Commun. 8 2037
[32]	Li M R, Croft M, Stephens P W, Ye M, Vanderbilt D, Retuerto M, Deng Z, Grams C P, Hemberger J, Hadermann J, Li W M, Jin C Q, Saouma F O, Jang J I, Akamatsu H, Gopalan V, Walker D, Greenblatt M 2015 Adv. Mater. 27 2177
[33]	Li M R, Walker D, Retuerto M, Sarkar T, Hadermann J, Stephens P W, Croft M, Ignatov A, Grams C P, Hemberger J, Nowik I, Halasyamani P S, Tran T T, Mukherjee S, Dasgupta T S, Greenblatt M 2013 Angew. Chem. Int. Ed. 52 8406
[34]	Li M R, Retuerto M, Walker D, Sarkar T, Stephens P W, Mukherjee S, Dasgupta T S, Hodges J P, Croft M, Grams C P, Hemberger J, Snchez-Bentez J, Huq A, Saouma F O, Jang J I, Greenblatt M 2014 Angew. Chem. Int. Ed. 53 10774
[35]	Li M R, Retuerto M, Stephens P W, Croft M, Sheptyakov D, Pomjakushin V, Deng Z, Akamatsu H, Gopalan V, Snchez-Bentez J, Saouma F O, Jang J I, Walker D, Greenblatt M 2016 Angew. Chem. Int. Ed. 128 10016
[36]	Li M R, Stephens P W, Retuerto M, Sarkar T, Grams C P, Hemberger J, Croft M C, Walker D, Greenblatt M 2014 J. Am. Chem. Soc. 136 8508
[37]	Wang P S, Ren W, Bellaiche L, Xiang H J 2015 Phys. Rev. Lett. 114 147204
[38]	Song G, Zhang W 2016 Sci. Rep. 6 20133
[39]	Zhao L, Du C H, Komarek A C 2017 Phys. Status Solidi: Rap. Res. Lett. 11 1700073
[40]	Ivanov S, Nordblad P, Mathieu R, Tellgren R, Politova E, Andr G 2011 Eur. J. Inorg. Chem. 2011 4691
[41]	Ye M, Vanderbilt D 2016 Phys. Rev. B 93 134303
[42]	Choi Y J, Yi H T, Lee S, Huang Q, Kiryukhin V, Cheong S W 2008 Phys. Rev. Lett. 100 047601
[43]	Tokura Y, Seki S, Nagaosa N 2014 Rep. Prog. Phys. 77 076501
[44]	Yez-Vilar S, Mun E D, Zapf V S, Ueland B G, Gardner J S, Thompson J D, Singleton J, Snchez-Andjar M, Mira J, Biskup N, Sears-Rodr guez M A, Batista C D 2011 Phys. Rev. B 84 134427
[45]	Sharma G, Saha J, Kaushik S, Siruguri V, Patnaik S 2013 Appl. Phys. Lett. 103 012903
[46]	Blasco J, Garca-Muoz J, Garca J, Stankiewicz J, Subas G, Ritter C, Rodrguez-Velamazn J 2015 Appl. Phys. Lett. 107 012902
[47]	Choi H Y, Moon J Y, Kim J H, Choi Y J, Lee N 2017 Crystals 7 67
[48]	Yi W, Princep A J, Guo Y, Johnson R D, Khalyavin D, Manuel P, Senyshyn A, Presniakov I A, Sobolev A V, Matsushita Y 2015 Inorg. Chem. 54 8012
[49]	Dos santos-Garca A J, Solana-Madruga E, Ritter C, Andrada-Chacn A, Snchez-Bentez J, Mompean F J, Garcia-Hernandez M, Sez-Puche R, Schmidt R 2017 Angew. Chem. Int. Ed. 129 4438
[50]	Mathieu R, Ivanov S A, Solovyev I V, Bazuev G V, Anil Kumar P, Lazor P, Nordblad P 2013 Phys. Rev. B 87 014408
[51]	Zhao H J, Ren W, Yang Y, iguez J, Chen X M, Bellaiche L 2014 Nat. Commun. 5 4021

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