聚氧乙烯基聚合物固态电池的界面研究进展

刘玉龙; 辛明杨; 丛丽娜; 谢海明

doi:10.7498/aps.69.20201588

摘要

聚氧乙烯基聚合物固态电池具有高安全性和高能量密度的特点, 极有可能成为下一代储能器件. 然而, 聚氧乙烯基电解质本身的电化学窗口窄, 极大的限制了其能量密度的进一步提升. 目前适配聚氧乙烯基电解质且长循环稳定的正负极材料较少, 这严重阻碍了聚氧乙烯基聚合物固态电池的广泛应用. 其主要问题在于电极材料与聚氧乙烯聚合物电解质之间的负极界面和正极界面都容易发生副反应, 大大地缩短了电池的循环寿命. 为了抑制这些副反应, 人们采取了相应的策略, 取得了一定的成效. 为充分理解固态电池界面处的变化, 可采用各类先进表征手段对其进行研究, 这将为下一步提高固态电池循环稳定性提供更科学的依据.

关键词:

Abstract

Polyethylene oxide(PEO) based solid-state batteries have high safety and high energy density, making them suitable for next-generation energy storage devices. However, their energy density reaches a limitation due to the narrow electrochemical window of PEO solid electrolyte. The electrode materials that are compatible with PEO electrolyte is less, thus handering it from being put into wide application. At the PEO/electrode interface, there are side reactions between anode/PEO and PEO cathode. Some strategies are proposed to reduce the side reactions, electrochemical performances of solid-state batteries are improved. To understand the change of interface, several advanced characterizations are employed, which can offer scientific evidence of increasing the interface stability in the future.

Keywords:

作者及机构信息

东北师范大学化学学院, 国家地方动力电池联合工程实验室, 长春　130024

通信作者: 丛丽娜, congln816@nenu.edu.cn ; 谢海明, xiehm136@nenu.edu.cn

基金项目: 重点技术研发专项资金(批准号: 20180201097GX, 20180201099GX, 20180201096GX)、东北师范大学物理化学重点学科建设、低温高能量动力电池研发项目、长春市科技厅项目(批准号: 19SS013)、国家自然科学基金委青年科学基金(批准号: 21905041)、吉林省教育厅自然科学基金(批准号: JJKH20190265KJ)、吉林省产业技术研究与开发专项项目(批准号: 2019C042)和中央高校基本科研业务费专项资金资(批准号: 2412020QD006)资助的课题

Authors and contacts

National & Local United Engineering Laboratory for Power Battery, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: Cong Li-Na, congln816@nenu.edu.cn ; Xie Hai-Ming, xiehm136@nenu.edu.cn

Funds: Project supported by the Special Fund of Key Technology Research and Development Projects, China (Grant Nos. 20180201097GX, 20180201099GX, 20180201096GX), the Key Subject Construction of Physical Chemistry of Northeast Normal University, the R&D Program of Power Batteries with Low Temperature and High Energy, the Science and Technology Bureau of Changchun, China (Grant No. 19SS013), the Young Scientists Fund of the National Natural Science Foundation of China (Grant No. 21905041), the Natural Science Foundation of the Education Department of Jilin Province, China (Grant No. JJKH20190265KJ), the Special Foundation of the Industrial Technology Research and Development of Jilin Province, China (Grant No. 2019C042), and the Fundamental Research Funds for the Central Universities (Grant No. 2412020QD006)

文章全文 : translate this paragraph

参考文献

[1]	Berthier C, Gorecki W, Minier M, Armand M B, Chabagno J M, Rigaud P 1983 Solid State Ionics 11 91 Google Scholar
[2]	Gauthier M, Fauteux D, Vassort G, Bélanger A, Duval M, Ricoux P, Chabagno J M, Muller D, Rigaud P, Armand M B, Deroo D 1985 J. Electrochem. Soc. 132 1333 Google Scholar
[3]	Armand M 1994 Solid State Ionics 69 309 Google Scholar
[4]	Koksbang R, Olsen I I, Shackle D 1994 Solid State Ionics 69 320 Google Scholar
[5]	Zhou D, Shanmukaraj D, Tkacheva A, Armand M, Wang G 2019 Chem 5 2326 Google Scholar
[6]	Shi J, Vincent C A 1993 Solid State Ionics 60 11 Google Scholar
[7]	Teran A A, Tang M H, Mullin S A, Balsara N P 2011 Solid State Ionics 203 18
[8]	Marchiori C F N, Carvalho R P, Ebadi M, Brandell D, Araujo C M 2020 Chem. Mater. 32 7237 Google Scholar
[9]	Xue Z, He D, Xie X 2015 J. Mater. Chem. A 3 19218 Google Scholar
[10]	Tan S J, Zeng X X, Ma Q, Wu X W, Guo Y G 2018 Electrochem. Energ. Rev. 1 113 Google Scholar
[11]	Niitani T, Shimada M, Kawamura K, Kanamura K 2005 J. Power Sources 146 386 Google Scholar
[12]	Tan J, Ao X, Dai A, Yuan Y, Zhuo H, Lu H, Zhuang L, Ke Y, Su C, Peng X, Tian B, Lu J 2020 Energy Storage Mater. 33 173 Google Scholar
[13]	Liu L, Mo J, Li J, Liu J, Yan H, Lyu J, Jiang B, Chu L, Li M 2020 J. Energy Chem. 48 334 Google Scholar
[14]	Bouchet R, Maria S, Meziane R, Aboulaich A, Lienafa L, Bonnet J-P, Phan T N T, Bertin D, Gigmes D, Devaux D, Denoyel R, Armand M 2013 Nat. Mater. 12 452 Google Scholar
[15]	Yue L, Ma J, Zhang J, Zhao J, Dong S, Liu Z, Cui G, Chen L 2016 Energy Storage Mater. 5 157
[16]	Zhou W, Wang Z, Pu Y, Li Y, Xin S, Li X, Chen J, Goodenough J B 2019 Adv. Mater. 31 1805574 Google Scholar
[17]	Liang W, Shao Y, Chen Y-M, Zhu Y 2018 ACS Appl. Energy Mater. 1 6064 Google Scholar
[18]	Zaghib K, Charest P, Guerfi A, Shim J, Perrier M, Striebel K 2005 J. Power Sources 146 380 Google Scholar
[19]	Zaghib K, Charest P, Guerfi A, Shim J, Perrier M, Striebel K 2004 J. Power Sources 134 124 Google Scholar
[20]	Fiory F S, Croce F, D'Epifanio A, Licoccia S, Scrosati B, Traversa E 2004 J. Eur. Ceram. Soc. 24 1385 Google Scholar
[21]	Chen R, Qu W, Guo X, Li L, Wu F 2016 Mater. Horiz. 3 487 Google Scholar
[22]	Croce F, Scrosati B 1993 J. Power Sources 43 9 Google Scholar
[23]	Baudry P, Lascaud S, Majastre H, Bloch D 1997 J. Power Sources 68 432 Google Scholar
[24]	Persi L, Croce F, Scrosati B, Plichta E, Hendrickson M A 2002 J. Electrochem. Soc. 149 A212 Google Scholar
[25]	Li Q, Itoh T, Imanishi N, Hirano A, Takeda Y, Yamamoto O 2003 Solid State Ionics 159 97 Google Scholar
[26]	Hallinan D T, Mullin S A, Stone G M, Balsara N P 2013 J. Electrochem. Soc. 160 A464 Google Scholar
[27]	Le Granvalet-Mancini M, Hanrath T, Teeters D 2000 Solid State Ionics 135 283 Google Scholar
[28]	Brissot C, Rosso M, Chazalviel J N, Lascaud S 1999 J. Electrochem. Soc. 146 4393 Google Scholar
[29]	Harry K J, Liao X, Parkinson D Y, Minor A M, Balsara N P 2015 J. Electrochem. Soc. 162 A2699 Google Scholar
[30]	Maslyn J A, Loo W S, McEntush K D, Oh H J, Harry K J, Parkinson D Y, Balsara N P 2018 J. Phys. Chem. C 122 26797 Google Scholar
[31]	Maslyn J A, Frenck L, Loo W S, Parkinson D Y, Balsara N P 2019 ACS Appl. Energy Mater. 2 8197 Google Scholar
[32]	Dollé M l, Sannier L, Beaudoin B, Trentin M, Tarascon J M 2002 Electrochem. Solid-State Lett. 5 A286 Google Scholar
[33]	Frenck L, Maslyn J A, Loo W S, Parkinson D Y, Balsara N P 2019 ACS Appl. Mater. Interfaces 11 47878 Google Scholar
[34]	Zhang J, Zhao N, Zhang M, Li Y, Chu P K, Guo X, Di Z, Wang X, Li H 2016 Nano Energy 28 447 Google Scholar
[35]	Golozar M, Hovington P, Paolella A, Bessette S, Lagacé M, Bouchard P, Demers H, Gauvin R, Zaghib K 2018 Nano Lett. 18 7583 Google Scholar
[36]	Barai P, Higa K, Srinivasan V 2017 Phys. Chem. Chem. Phys. 19 20493 Google Scholar
[37]	Galluzzo M D, Halat D M, Loo W S, Mullin S A, Reimer J A, Balsara N P 2019 ACS Energy Lett. 4 903 Google Scholar
[38]	Zaghib K 1998 J. Electrochem. Soc. 145 3135 Google Scholar
[39]	Imanishi N, Ono Y, Hanai K, Uchiyama R, Liu Y, Hirano A, Takeda Y, Yamamoto O 2008 J. Power Sources 178 744
[40]	Kobayashi Y, Seki S, Mita Y, Ohno Y, Miyashiro H, Charest P, Guerfi A, Zaghib K 2008 J. Power Sources 185 542 Google Scholar
[41]	Si Q, Kakubo M, Matsui M, Horiba T, Yamamoto O, Takeda Y, Seki N, Imanishi N 2014 J. Power Sources 248 1275 Google Scholar
[42]	Xu X, Li Y, Cheng J, Hou G, Nie X, Ai Q, Dai L, Feng J, Ci L 2020 J. Energy Chem. 41 73 Google Scholar
[43]	Appetecchi G B, Croce F, Dautzenberg G, Mastragostino M, Ronci F, Scrosati B, Soavi F, Zanelli A, Alessandrini F, Prosini P P 1998 J. Electrochem. Soc. 145 4126 Google Scholar
[44]	Appetecchi G B, Croce F, Mastragostino M, Scrosati B, Soavi F, Zanelli A 1998 J. Electrochem. Soc. 145 4133 Google Scholar
[45]	Bac A, Ciosek M, Bukat M, Siekierski M, Wieczorek W 2006 J. Power Sources 159 438 Google Scholar
[46]	Delaporte N, Guerfi A, Demers H, Lorrmann H, Paolella A, Zaghib K 2019 ChemistryOpen 8 192 Google Scholar
[47]	Zeng X X, Yin Y X, Li N W, Du W C, Guo Y G, Wan L J 2016 JACS 138 15825 Google Scholar
[48]	Zhao C Z, Zhang X Q, Cheng X B, Zhang R, Xu R, Chen P Y, Peng H J, Huang J Q, Zhang Q 2017 PNAS 114 11069 Google Scholar
[49]	Huo H, Chen Y, Luo J, Yang X, Guo X, Sun X 2019 Adv. Energy Mater. 9 1804004 Google Scholar
[50]	Pawłowska M, Żukowska G Z, Kalita M, Sołgała A, Parzuchowski P, Siekierski M 2007 J. Power Sources 173 755 Google Scholar
[51]	Chintapalli M, Chen X C, Thelen J L, Teran A A, Wang X, Garetz B A, Balsara N P 2014 Macromolecules 47 5424 Google Scholar
[52]	Yuan R, Teran A A, Gurevitch I, Mullin S A, Wanakule N S, Balsara N P 2013 Macromolecules 46 914 Google Scholar
[53]	Fu C, Venturi V, Kim J, Ahmad Z, Ells A W, Viswanathan V, Helms B A 2020 Nat. Mater. 19 758 Google Scholar
[54]	Niitani T, Shimada M, Kawamura K, Dokko K, Rho Y H, Kanamura K 2005 Electrochem. Solid-State Lett. 8 A385 Google Scholar
[55]	Ismail I, Noda A, Nishimoto A, Watanabe M 2001 Electrochim. Acta 46 1595 Google Scholar
[56]	Sun B, Xu C, Mindemark J, Gustafsson T, Edström K, Brandell D 2015 J. Mater. Chem. A 3 13994 Google Scholar
[57]	Xu C, Sun B, Gustafsson T, Edström K, Brandell D, Hahlin M 2014 J. Mater. Chem. A 2 7256 Google Scholar
[58]	Rosso M, Gobron T, Brissot C, Chazalviel J N, Lascaud S 2001 J. Power Sources 97 804
[59]	Dolle M, Sannier L, Beaudoin B, Trentin M, Tarascon J M 2002 Electrochemical and Solid State Letters 5 A286
[60]	Hovington P, Lagace M, Guerfi A, Bouchard P, Mauger A, Julien C M, Armand M, Zaghib K 2015 Nano Lett. 15 2671 Google Scholar
[61]	Harry K J, Hallinan D T, Parkinson D Y, MacDowell A A, Balsara N P 2014 Nat. Mater. 13 69 Google Scholar
[62]	Choi J W, Aurbach D 2016 Nat. Rev. Mater. 1 16013
[63]	Boaretto N, Meabe L, Martinez-Ibañez M, Armand M, Zhang H 2020 J. Electrochem. Soc. 167 070524 Google Scholar
[64]	Myung S, Maglia F, Park K J, Yoon C S, Lamp P, Kim S, Sun Y 2017 ACS Energy Lett. 2 196 Google Scholar
[65]	Ding Y, Mu D, Wu B, Wang R, Zhao Z, Wu F 2017 Appl. Energy 195 586 Google Scholar
[66]	Manthiram A, Knight J C, Myung S, Oh S M, Sun Y 2016 Adv. Energy Mater. 6 1501010 Google Scholar
[67]	Judez X, Eshetu G G, Li C, Rodriguezmartinez L M, Zhang H, Armand M 2018 Joule 2 2208 Google Scholar
[68]	Zhang H, Zhang J, Ma J, Xu G, Dong T, Cui G 2019 Electrochem. Energy Rev. 2 128 Google Scholar
[69]	Nie K, Wang X, Qiu J, Wang Y, Yang Q, Xu J, Yu X, Li H, Huang X, Chen L 2020 ACS Energy Lett. 5 826 Google Scholar
[70]	Li Z, Li A, Zhang H, Lin R, Jin T, Cheng Q, Xiao X, Lee W, Ge M, Zhang H 2020 Nano Energy 72 104655 Google Scholar
[71]	Liang J, Sun Y, Zhao Y, Sun Q, Luo J, Zhao F, Lin X, Li X, Li R, Zhang L, Lu S, Huang H, Sun X 2020 J. Mater. Chem. A 8 2769 Google Scholar
[72]	Ma J, Liu Z, Chen B, Wang L, Yue L, Liu H, Zhang J, Liu Z, Cui G 2017 J. Electrochem. Soc. 164 A3454 Google Scholar
[73]	Miyashiro H, Kobayashi Y, Seki S, Mita Y, Usami A, Nakayama M, Wakihara M 2005 Chem. Mater. 17 5603 Google Scholar
[74]	Seki S, Kobayashi Y, Miyashiro H, Mita Y, Iwahori T 2005 Chem. Mater. 17 2041 Google Scholar
[75]	Yang Q, Huang J, Li Y, Wang Y, Qiu J, Zhang J, Yu H, Yu X, Li H, Chen L 2018 J. Power Sources 388 65 Google Scholar
[76]	Morimoto H, Awano H, Terashima J, Shindo Y, Nakanishi S, Ito N, Ishikawa K, Tobishima S I 2013 J. Power Sources 240 636 Google Scholar
[77]	Shim J, Han J, Lee J, Lee S 2016 ACS Appl. Mater. Interfaces 8 12205 Google Scholar
[78]	Fu C, Lou S, Xu X, Cui C, Li C, Zuo P, Ma Y, Yin G, Gao Y 2020 Chem. Eng. J. 392 123665 Google Scholar
[79]	Wang Y, Liu B, Zhou G, Nie K, Zhang J, Yu X, Li H 2019 Chin. Phys. B 28 068202 Google Scholar
[80]	Zhao Y, Zheng K, Sun X 2018 Joule 2 2583 Google Scholar
[81]	Liang J, Hwang S, Li S, Luo J, Sun Y, Zhao Y, Sun Q, Li W, Li M, Banis M N, Li X, Li R, Zhang L, Zhao S, Lu S, Huang H, Su D, Sun X 2020 Nano Energy 78 105107 Google Scholar
[82]	Zhu Y, He X, Mo Y 2015 ACS Appl. Mater. Interfaces 7 23685 Google Scholar
[83]	Zhu Y, He X, Mo Y 2016 J. Mater. Chem. A 4 3253 Google Scholar
[84]	Meng X, Liu J, Li X, Banis M N, Yang J, Li R, Sun X 2013 RSC Adv. 3 7285 Google Scholar
[85]	Liu J, Banis M N, Li X, Lushington A, Cai M, Li R, Sham T K, Sun X 2013 J. Phys. Chem. C 117 20260 Google Scholar
[86]	Wang B, Zhao Y, Banis M N, Sun Q, Adair K R, Li R, Sham T K, Sun X 2018 ACS Appl. Mater. Interfaces 10 1654 Google Scholar
[87]	Wang B, Liu J, Norouzi Banis M, Sun Q, Zhao Y, Li R, Sham T K, Sun X 2017 ACS Appl. Mater. Interfaces 9 31786 Google Scholar
[88]	Wang B, Liu J, Sun Q, Li R, Sham T K, Sun X 2014 Nanotechnology 25 504007
[89]	Liu Z, Hu P, Ma J, Qin B, Zhang Z, Mou C, Yao Y, Cui G 2017 Electrochim. Acta 236 221 Google Scholar
[90]	Xia Y, Fujieda T, Tatsumi K, Prosini P P, Sakai T 2001 J. Power Sources 92 234 Google Scholar
[91]	Qiu J, Yang L, Sun G, Yu X, Li H, Chen L 2020 Chem. Commun. 56 5633 Google Scholar
[92]	Lu J, Zhou J, Chen R, Fang F, Nie K, Qi W, Zhang J N, Yang R, Yu X, Li H, Chen L, Huang X 2020 Energy Storage Mater. 32 191 Google Scholar
[93]	Zhou W, Wang Z, Pu Y, Li Y, Xin S, Li X, Chen J, Goodenough J B 2019 Advanced Materials 31 1805574
[94]	Li W, Lucht B L 2007 J. Power Sources 168 258 Google Scholar
[95]	Smart M C, Lucht B L, Ratnakumar B V 2008 J. Electrochem. Soc. 155 A557 Google Scholar
[96]	Qiu J, Liu X, Chen R, Li Q, Wang Y, Chen P, Gan L, Lee S J, Nordlund D, Liu Y, Yu X, Bai X, Li H, Chen L 2020 Adv. Funct. Mater. 30 1909392 Google Scholar
[97]	Aurbach D, Pollak E, Elazari R, Salitra G, Kelley C S, Affinito J 2009 J. Electrochem. Soc. 156 A694 Google Scholar
[98]	Li W, Yao H, Yan K, Zheng G, Liang Z, Chiang Y M, Cui Y 2015 Nat. Commun. 6 7436 Google Scholar
[99]	Zhuang G V, Xu K, Jow T R, Ross P N 2004 Electrochem. Solid-State Lett. 7 A224 Google Scholar
[100]	Zheng J, Engelhard M H, Mei D, Jiao S, Polzin B J, Zhang J G, Xu W 2017 Nat. Energy 2 17012 Google Scholar
[101]	Yang L, Furczon M M, Xiao A, Lucht B L, Zhang Z, Abraham D P 2010 J. Power Sources 195 1698 Google Scholar
[102]	Li J, Li W, You Y, Manthiram A 2018 Adv. Energy Mater. 8 1801957 Google Scholar
[103]	Choudhury S, Stalin S, Deng Y, Archer L A 2018 Chem. Mater. 30 5996 Google Scholar
[104]	Zhao Q, Chen P, Li S, Liu X, Archer L A 2019 J. Mater. Chem. A 7 7823 Google Scholar
[105]	Wang C, Wang T, Wang L, Hu Z, Cui Z, Li J, Dong S, Zhou X, Cui G 2019 Adv. Sci. 6 1901036 Google Scholar
[106]	Besli M M, Xia S, Kuppan S, Huang Y, Metzger M, Shukla A K, Schneider G, Hellstrom S, Christensen J, Doeff M M 2019 Chem. Mater. 31 491 Google Scholar

施引文献

图 1 PEO基聚合物电解质固态电池发展概况.

Fig. 1. Overview of the PEO polymer based solid-state battery.

下载: 全尺寸图片幻灯片

图 2 PEO基固态电解质与负极的反应　(a) 锂的不均匀沉积形成的锂枝晶^[29]; (b)锂金属沉积的原位电镜扫描图片^[32]; (c) 锂金属沉积的循环伏安曲线^[34]

Fig. 2. Anode side reaction in PEO based solid state battery: (a) Lithium dendrite formation during deposition^[29]; (b) in-situ SEM images of lithium deposition^[32]; (c) C-V curves of lithium deposition/dissolution^[34].

下载: 全尺寸图片幻灯片

图 3 负极界面改善策略　(a) 锂金属表面修饰^[47]; (b) 有机-无机复合电解质^[49]; (c)嵌段聚合物^[54]

Fig. 3. Strategies to improve the anode stability^[47]: (a) Surface modification of Li metal; (b) organic-inorganic composite electrolyte^[49]; (c) triblock co-polymer^[54].

下载: 全尺寸图片幻灯片

图 4 负极界面表征　(a)常规XPS^[56]; (b)原位SEM^[35]; (c)同步辐射CT^[61]

Fig. 4. Advanced characterization of anode interface: (a)Lab-XPS^[56]; (b)in-situ SEM^[35]; (c) synchrotron X-ray microtomography^[61].

下载: 全尺寸图片幻灯片

图 5 传统电池及全固态锂电池体系质量能量密度和体积能量密度预测与比较图^[67]

Fig. 5. Prediction of volumetric and gravimetric energy density for traditional battery and all solid-state battery.

下载: 全尺寸图片幻灯片

图 6 正极表面改性　(a) 固相法制备的5 wt.% c-LATP包覆的LiCoO₂的SEM图片^[76]; (b) 前驱体包覆方法获得的Li_1.3Al_0.3Ti_1.7(PO₄)₃改性LiCoO₂的SEM图片^[77]; (c) 溶液方法制备的0.5 wt% LATP均匀包覆的LiCoO₂的SEM图片^[75]; (d)在2.8−4.5 V截止电压下, LATP包覆及未包覆改性的NCM622在1 C倍率下的循环曲线 (1 C = 190 mA/g)^[79]; (e) 高温煅烧过程中LATP包覆改性及未包覆NCM622的表面演化示意图^[79]; (f) 定量分析LATP包覆改性及未包覆改性NCM622的XPS 的O1s和P2p^[79]

Fig. 6. Cathode interface engineering: (a) SEM image of 5 wt.% c-LATP coated LiCoO₂^[76]; (b) SEM image of LATP precursor coated LiCoO₂^[77]; (c) SEM image of 0.5 wt.% LATP coated LiCoO₂ by solution method^[75]; (d) charge discharge curve of NMC622 at 1 C rate between 2.8−4.5 V (1 C = 190 mA/g)^[79]; (e) schematic diagram of LATP coated and un-coated NMC during high temperature sintering^[79]; (f) XPS O1s and P2p of LATP coated and un-coated NMC^[79].

下载: 全尺寸图片幻灯片

图 7 (a) 示意图说明ALD/MLD技术解决固态电池界面问题^[80]; (b) ALD技术制备的LNO包覆NCM811的TEM图^[81]; (c) 示意图说明包覆改性前后的NCM811正极在长循环后层状结构降解及晶格氧的损失情况^[81]; (d) 对比改性前后NCM811在60 ℃, 0.2 C倍率下循环性能曲线^[81]; (e) LTO包覆LiCoO₂颗粒和LTO包覆LiCoO₂正极(极片包括活性材料, 导电碳和粘结剂)的示意图^[71]; (f) 示意图说明电沉积方法制备PAN包覆NCM523^[91]

Fig. 7. (a) Schematic diagram of ALD/MLD in stabilizing cathode interface^[80]; (b) TEM image of ALD LNO coated NCM811^[81]; (c) illustration of structure degradation and oxygen release of coated and uncoated NCM811^[81]; (d) cycling performance of coated and uncoated NCM811 NCM811 at 60 ℃, 0.2 C rate^[81]; (e) illustration of ALD LTO coated LiCoO₂particle and LTO coated LiCoO₂electrode^[71]; (f) illustration of PAN coated NCM 523 by electrodeposition^[91].

下载: 全尺寸图片幻灯片

下载: 全尺寸图片幻灯片

图 8 (a) DSM-SPE电解质膜的结构示意图^[105]; (b) DSM-SPE电解质膜循环10次后, XPS测试LiCoO₂正极表面F1s和B1s谱图^[105]; (c) SPE, DSM-SPE, 和PEO-LiTFSI电解质组装的LiCoO₂/Li固态电池在2.8−4.3 V电压范围, 60 ℃, 0.1 C倍率下循环性能曲线^[105]; (d) 原位聚合形成CEI膜及组装固态电池的示意图^[92]; (e) LiCoO₂|PEO-SPE|Li和CEI膜改性的LiCoO₂|PEO-SPE|Li在不同循环圈数放电态的EIS曲线, 及等效电路图和相应的拟合结果对比图^[92]; (f) LiCoO₂|PEO-SPE|Li和CEI膜改性的LiCoO₂|PEO-SPE|Li在3.0−4.2 V电压范围, 0.5 C倍率下的循环性能曲线^[92]

Fig. 8. (a) Demonstration of DSM-SPE solid electrolyte based solid battery^[105];(b) F1s and B1s XPS spectra of LiCoO₂ electrode after 10 cycles^[105]; (c) cycling performance of LiCoO₂/Li cell with SPE, DSM-SPE, and PEO-LiTFSI electrolyte at 60 ℃, 0.1 C rate between 2.8−4.3 V^[105]; (d) illustration of in- situ CEI film formation and solid state battery assembly^[92]; (e) EIS spectra of LiCoO₂|PEO-SPE|Li and CEI modified LiCoO₂|PEO-SPE|Li at different cycles^[92]; (f) cycling performance of LiCoO₂|PEO-SPE|Li and CEI modified LiCoO₂|PEO-SPE|Li at 0.5 C rate between 3.0−4.2 V^[92].

下载: 全尺寸图片幻灯片

图 9 (a) LATP包覆层的TEM和SAED图^[77]; (b) LATP包覆层的STEM和EDS图^[77]; (c) Mg掺杂的LiCoO₂的放大STEM和EELS图^[77]; (d) Mg掺杂的LATP- LiCoO₂ 和LATP- LiCoO₂的C-AFM图^[77]; (e) 完全充电态的NCA颗粒在21周循环后的2D-FF-TXM^[106]; (f) 完全电态的NCA颗粒在21周循环后的3D-FF-TXM^[106]; (g) 未进行循环及循环后的NCA电极在高分辨率下的BIB-SEM图^[106]

Fig. 9. (a) TEM and SAED of LATP coating layer^[77]; (b) STEM and EDS of LATP coating layer^[77]; (c) STEM and EELS of Mg doped LiCoO₂^[77]; (d) C-AFM of LATP coated Mg-LiCoO₂ and LATP- LiCoO₂^[77]; (e) 2D-FF-TXM of NCA particle after 21 cycle^[106]; (f) 3D-FF-TXM of NCA particle after 21 cycle^[106]; (g) BIB-SEM of NCA electrode before and after cycling^[106].

下载: 全尺寸图片幻灯片

[1]	Berthier C, Gorecki W, Minier M, Armand M B, Chabagno J M, Rigaud P 1983 Solid State Ionics 11 91 Google Scholar
[2]	Gauthier M, Fauteux D, Vassort G, Bélanger A, Duval M, Ricoux P, Chabagno J M, Muller D, Rigaud P, Armand M B, Deroo D 1985 J. Electrochem. Soc. 132 1333 Google Scholar
[3]	Armand M 1994 Solid State Ionics 69 309 Google Scholar
[4]	Koksbang R, Olsen I I, Shackle D 1994 Solid State Ionics 69 320 Google Scholar
[5]	Zhou D, Shanmukaraj D, Tkacheva A, Armand M, Wang G 2019 Chem 5 2326 Google Scholar
[6]	Shi J, Vincent C A 1993 Solid State Ionics 60 11 Google Scholar
[7]	Teran A A, Tang M H, Mullin S A, Balsara N P 2011 Solid State Ionics 203 18
[8]	Marchiori C F N, Carvalho R P, Ebadi M, Brandell D, Araujo C M 2020 Chem. Mater. 32 7237 Google Scholar
[9]	Xue Z, He D, Xie X 2015 J. Mater. Chem. A 3 19218 Google Scholar
[10]	Tan S J, Zeng X X, Ma Q, Wu X W, Guo Y G 2018 Electrochem. Energ. Rev. 1 113 Google Scholar
[11]	Niitani T, Shimada M, Kawamura K, Kanamura K 2005 J. Power Sources 146 386 Google Scholar
[12]	Tan J, Ao X, Dai A, Yuan Y, Zhuo H, Lu H, Zhuang L, Ke Y, Su C, Peng X, Tian B, Lu J 2020 Energy Storage Mater. 33 173 Google Scholar
[13]	Liu L, Mo J, Li J, Liu J, Yan H, Lyu J, Jiang B, Chu L, Li M 2020 J. Energy Chem. 48 334 Google Scholar
[14]	Bouchet R, Maria S, Meziane R, Aboulaich A, Lienafa L, Bonnet J-P, Phan T N T, Bertin D, Gigmes D, Devaux D, Denoyel R, Armand M 2013 Nat. Mater. 12 452 Google Scholar
[15]	Yue L, Ma J, Zhang J, Zhao J, Dong S, Liu Z, Cui G, Chen L 2016 Energy Storage Mater. 5 157
[16]	Zhou W, Wang Z, Pu Y, Li Y, Xin S, Li X, Chen J, Goodenough J B 2019 Adv. Mater. 31 1805574 Google Scholar
[17]	Liang W, Shao Y, Chen Y-M, Zhu Y 2018 ACS Appl. Energy Mater. 1 6064 Google Scholar
[18]	Zaghib K, Charest P, Guerfi A, Shim J, Perrier M, Striebel K 2005 J. Power Sources 146 380 Google Scholar
[19]	Zaghib K, Charest P, Guerfi A, Shim J, Perrier M, Striebel K 2004 J. Power Sources 134 124 Google Scholar
[20]	Fiory F S, Croce F, D'Epifanio A, Licoccia S, Scrosati B, Traversa E 2004 J. Eur. Ceram. Soc. 24 1385 Google Scholar
[21]	Chen R, Qu W, Guo X, Li L, Wu F 2016 Mater. Horiz. 3 487 Google Scholar
[22]	Croce F, Scrosati B 1993 J. Power Sources 43 9 Google Scholar
[23]	Baudry P, Lascaud S, Majastre H, Bloch D 1997 J. Power Sources 68 432 Google Scholar
[24]	Persi L, Croce F, Scrosati B, Plichta E, Hendrickson M A 2002 J. Electrochem. Soc. 149 A212 Google Scholar
[25]	Li Q, Itoh T, Imanishi N, Hirano A, Takeda Y, Yamamoto O 2003 Solid State Ionics 159 97 Google Scholar
[26]	Hallinan D T, Mullin S A, Stone G M, Balsara N P 2013 J. Electrochem. Soc. 160 A464 Google Scholar
[27]	Le Granvalet-Mancini M, Hanrath T, Teeters D 2000 Solid State Ionics 135 283 Google Scholar
[28]	Brissot C, Rosso M, Chazalviel J N, Lascaud S 1999 J. Electrochem. Soc. 146 4393 Google Scholar
[29]	Harry K J, Liao X, Parkinson D Y, Minor A M, Balsara N P 2015 J. Electrochem. Soc. 162 A2699 Google Scholar
[30]	Maslyn J A, Loo W S, McEntush K D, Oh H J, Harry K J, Parkinson D Y, Balsara N P 2018 J. Phys. Chem. C 122 26797 Google Scholar
[31]	Maslyn J A, Frenck L, Loo W S, Parkinson D Y, Balsara N P 2019 ACS Appl. Energy Mater. 2 8197 Google Scholar
[32]	Dollé M l, Sannier L, Beaudoin B, Trentin M, Tarascon J M 2002 Electrochem. Solid-State Lett. 5 A286 Google Scholar
[33]	Frenck L, Maslyn J A, Loo W S, Parkinson D Y, Balsara N P 2019 ACS Appl. Mater. Interfaces 11 47878 Google Scholar
[34]	Zhang J, Zhao N, Zhang M, Li Y, Chu P K, Guo X, Di Z, Wang X, Li H 2016 Nano Energy 28 447 Google Scholar
[35]	Golozar M, Hovington P, Paolella A, Bessette S, Lagacé M, Bouchard P, Demers H, Gauvin R, Zaghib K 2018 Nano Lett. 18 7583 Google Scholar
[36]	Barai P, Higa K, Srinivasan V 2017 Phys. Chem. Chem. Phys. 19 20493 Google Scholar
[37]	Galluzzo M D, Halat D M, Loo W S, Mullin S A, Reimer J A, Balsara N P 2019 ACS Energy Lett. 4 903 Google Scholar
[38]	Zaghib K 1998 J. Electrochem. Soc. 145 3135 Google Scholar
[39]	Imanishi N, Ono Y, Hanai K, Uchiyama R, Liu Y, Hirano A, Takeda Y, Yamamoto O 2008 J. Power Sources 178 744
[40]	Kobayashi Y, Seki S, Mita Y, Ohno Y, Miyashiro H, Charest P, Guerfi A, Zaghib K 2008 J. Power Sources 185 542 Google Scholar
[41]	Si Q, Kakubo M, Matsui M, Horiba T, Yamamoto O, Takeda Y, Seki N, Imanishi N 2014 J. Power Sources 248 1275 Google Scholar
[42]	Xu X, Li Y, Cheng J, Hou G, Nie X, Ai Q, Dai L, Feng J, Ci L 2020 J. Energy Chem. 41 73 Google Scholar
[43]	Appetecchi G B, Croce F, Dautzenberg G, Mastragostino M, Ronci F, Scrosati B, Soavi F, Zanelli A, Alessandrini F, Prosini P P 1998 J. Electrochem. Soc. 145 4126 Google Scholar
[44]	Appetecchi G B, Croce F, Mastragostino M, Scrosati B, Soavi F, Zanelli A 1998 J. Electrochem. Soc. 145 4133 Google Scholar
[45]	Bac A, Ciosek M, Bukat M, Siekierski M, Wieczorek W 2006 J. Power Sources 159 438 Google Scholar
[46]	Delaporte N, Guerfi A, Demers H, Lorrmann H, Paolella A, Zaghib K 2019 ChemistryOpen 8 192 Google Scholar
[47]	Zeng X X, Yin Y X, Li N W, Du W C, Guo Y G, Wan L J 2016 JACS 138 15825 Google Scholar
[48]	Zhao C Z, Zhang X Q, Cheng X B, Zhang R, Xu R, Chen P Y, Peng H J, Huang J Q, Zhang Q 2017 PNAS 114 11069 Google Scholar
[49]	Huo H, Chen Y, Luo J, Yang X, Guo X, Sun X 2019 Adv. Energy Mater. 9 1804004 Google Scholar
[50]	Pawłowska M, Żukowska G Z, Kalita M, Sołgała A, Parzuchowski P, Siekierski M 2007 J. Power Sources 173 755 Google Scholar
[51]	Chintapalli M, Chen X C, Thelen J L, Teran A A, Wang X, Garetz B A, Balsara N P 2014 Macromolecules 47 5424 Google Scholar
[52]	Yuan R, Teran A A, Gurevitch I, Mullin S A, Wanakule N S, Balsara N P 2013 Macromolecules 46 914 Google Scholar
[53]	Fu C, Venturi V, Kim J, Ahmad Z, Ells A W, Viswanathan V, Helms B A 2020 Nat. Mater. 19 758 Google Scholar
[54]	Niitani T, Shimada M, Kawamura K, Dokko K, Rho Y H, Kanamura K 2005 Electrochem. Solid-State Lett. 8 A385 Google Scholar
[55]	Ismail I, Noda A, Nishimoto A, Watanabe M 2001 Electrochim. Acta 46 1595 Google Scholar
[56]	Sun B, Xu C, Mindemark J, Gustafsson T, Edström K, Brandell D 2015 J. Mater. Chem. A 3 13994 Google Scholar
[57]	Xu C, Sun B, Gustafsson T, Edström K, Brandell D, Hahlin M 2014 J. Mater. Chem. A 2 7256 Google Scholar
[58]	Rosso M, Gobron T, Brissot C, Chazalviel J N, Lascaud S 2001 J. Power Sources 97 804
[59]	Dolle M, Sannier L, Beaudoin B, Trentin M, Tarascon J M 2002 Electrochemical and Solid State Letters 5 A286
[60]	Hovington P, Lagace M, Guerfi A, Bouchard P, Mauger A, Julien C M, Armand M, Zaghib K 2015 Nano Lett. 15 2671 Google Scholar
[61]	Harry K J, Hallinan D T, Parkinson D Y, MacDowell A A, Balsara N P 2014 Nat. Mater. 13 69 Google Scholar
[62]	Choi J W, Aurbach D 2016 Nat. Rev. Mater. 1 16013
[63]	Boaretto N, Meabe L, Martinez-Ibañez M, Armand M, Zhang H 2020 J. Electrochem. Soc. 167 070524 Google Scholar
[64]	Myung S, Maglia F, Park K J, Yoon C S, Lamp P, Kim S, Sun Y 2017 ACS Energy Lett. 2 196 Google Scholar
[65]	Ding Y, Mu D, Wu B, Wang R, Zhao Z, Wu F 2017 Appl. Energy 195 586 Google Scholar
[66]	Manthiram A, Knight J C, Myung S, Oh S M, Sun Y 2016 Adv. Energy Mater. 6 1501010 Google Scholar
[67]	Judez X, Eshetu G G, Li C, Rodriguezmartinez L M, Zhang H, Armand M 2018 Joule 2 2208 Google Scholar
[68]	Zhang H, Zhang J, Ma J, Xu G, Dong T, Cui G 2019 Electrochem. Energy Rev. 2 128 Google Scholar
[69]	Nie K, Wang X, Qiu J, Wang Y, Yang Q, Xu J, Yu X, Li H, Huang X, Chen L 2020 ACS Energy Lett. 5 826 Google Scholar
[70]	Li Z, Li A, Zhang H, Lin R, Jin T, Cheng Q, Xiao X, Lee W, Ge M, Zhang H 2020 Nano Energy 72 104655 Google Scholar
[71]	Liang J, Sun Y, Zhao Y, Sun Q, Luo J, Zhao F, Lin X, Li X, Li R, Zhang L, Lu S, Huang H, Sun X 2020 J. Mater. Chem. A 8 2769 Google Scholar
[72]	Ma J, Liu Z, Chen B, Wang L, Yue L, Liu H, Zhang J, Liu Z, Cui G 2017 J. Electrochem. Soc. 164 A3454 Google Scholar
[73]	Miyashiro H, Kobayashi Y, Seki S, Mita Y, Usami A, Nakayama M, Wakihara M 2005 Chem. Mater. 17 5603 Google Scholar
[74]	Seki S, Kobayashi Y, Miyashiro H, Mita Y, Iwahori T 2005 Chem. Mater. 17 2041 Google Scholar
[75]	Yang Q, Huang J, Li Y, Wang Y, Qiu J, Zhang J, Yu H, Yu X, Li H, Chen L 2018 J. Power Sources 388 65 Google Scholar
[76]	Morimoto H, Awano H, Terashima J, Shindo Y, Nakanishi S, Ito N, Ishikawa K, Tobishima S I 2013 J. Power Sources 240 636 Google Scholar
[77]	Shim J, Han J, Lee J, Lee S 2016 ACS Appl. Mater. Interfaces 8 12205 Google Scholar
[78]	Fu C, Lou S, Xu X, Cui C, Li C, Zuo P, Ma Y, Yin G, Gao Y 2020 Chem. Eng. J. 392 123665 Google Scholar
[79]	Wang Y, Liu B, Zhou G, Nie K, Zhang J, Yu X, Li H 2019 Chin. Phys. B 28 068202 Google Scholar
[80]	Zhao Y, Zheng K, Sun X 2018 Joule 2 2583 Google Scholar
[81]	Liang J, Hwang S, Li S, Luo J, Sun Y, Zhao Y, Sun Q, Li W, Li M, Banis M N, Li X, Li R, Zhang L, Zhao S, Lu S, Huang H, Su D, Sun X 2020 Nano Energy 78 105107 Google Scholar
[82]	Zhu Y, He X, Mo Y 2015 ACS Appl. Mater. Interfaces 7 23685 Google Scholar
[83]	Zhu Y, He X, Mo Y 2016 J. Mater. Chem. A 4 3253 Google Scholar
[84]	Meng X, Liu J, Li X, Banis M N, Yang J, Li R, Sun X 2013 RSC Adv. 3 7285 Google Scholar
[85]	Liu J, Banis M N, Li X, Lushington A, Cai M, Li R, Sham T K, Sun X 2013 J. Phys. Chem. C 117 20260 Google Scholar
[86]	Wang B, Zhao Y, Banis M N, Sun Q, Adair K R, Li R, Sham T K, Sun X 2018 ACS Appl. Mater. Interfaces 10 1654 Google Scholar
[87]	Wang B, Liu J, Norouzi Banis M, Sun Q, Zhao Y, Li R, Sham T K, Sun X 2017 ACS Appl. Mater. Interfaces 9 31786 Google Scholar
[88]	Wang B, Liu J, Sun Q, Li R, Sham T K, Sun X 2014 Nanotechnology 25 504007
[89]	Liu Z, Hu P, Ma J, Qin B, Zhang Z, Mou C, Yao Y, Cui G 2017 Electrochim. Acta 236 221 Google Scholar
[90]	Xia Y, Fujieda T, Tatsumi K, Prosini P P, Sakai T 2001 J. Power Sources 92 234 Google Scholar
[91]	Qiu J, Yang L, Sun G, Yu X, Li H, Chen L 2020 Chem. Commun. 56 5633 Google Scholar
[92]	Lu J, Zhou J, Chen R, Fang F, Nie K, Qi W, Zhang J N, Yang R, Yu X, Li H, Chen L, Huang X 2020 Energy Storage Mater. 32 191 Google Scholar
[93]	Zhou W, Wang Z, Pu Y, Li Y, Xin S, Li X, Chen J, Goodenough J B 2019 Advanced Materials 31 1805574
[94]	Li W, Lucht B L 2007 J. Power Sources 168 258 Google Scholar
[95]	Smart M C, Lucht B L, Ratnakumar B V 2008 J. Electrochem. Soc. 155 A557 Google Scholar
[96]	Qiu J, Liu X, Chen R, Li Q, Wang Y, Chen P, Gan L, Lee S J, Nordlund D, Liu Y, Yu X, Bai X, Li H, Chen L 2020 Adv. Funct. Mater. 30 1909392 Google Scholar
[97]	Aurbach D, Pollak E, Elazari R, Salitra G, Kelley C S, Affinito J 2009 J. Electrochem. Soc. 156 A694 Google Scholar
[98]	Li W, Yao H, Yan K, Zheng G, Liang Z, Chiang Y M, Cui Y 2015 Nat. Commun. 6 7436 Google Scholar
[99]	Zhuang G V, Xu K, Jow T R, Ross P N 2004 Electrochem. Solid-State Lett. 7 A224 Google Scholar
[100]	Zheng J, Engelhard M H, Mei D, Jiao S, Polzin B J, Zhang J G, Xu W 2017 Nat. Energy 2 17012 Google Scholar
[101]	Yang L, Furczon M M, Xiao A, Lucht B L, Zhang Z, Abraham D P 2010 J. Power Sources 195 1698 Google Scholar
[102]	Li J, Li W, You Y, Manthiram A 2018 Adv. Energy Mater. 8 1801957 Google Scholar
[103]	Choudhury S, Stalin S, Deng Y, Archer L A 2018 Chem. Mater. 30 5996 Google Scholar
[104]	Zhao Q, Chen P, Li S, Liu X, Archer L A 2019 J. Mater. Chem. A 7 7823 Google Scholar
[105]	Wang C, Wang T, Wang L, Hu Z, Cui Z, Li J, Dong S, Zhou X, Cui G 2019 Adv. Sci. 6 1901036 Google Scholar
[106]	Besli M M, Xia S, Kuppan S, Huang Y, Metzger M, Shukla A K, Schneider G, Hellstrom S, Christensen J, Doeff M M 2019 Chem. Mater. 31 491 Google Scholar

[1]	羊美丽, 邹丽, 程佳杰, 王佳明, 江钰帆, 郝会颖, 邢杰, 刘昊, 樊振军, 董敬敬. 聚偏氟乙烯添加剂提高CsPbBr₃钙钛矿太阳能电池性能. 物理学报, 2023, 72(16): 168101. doi: 10.7498/aps.72.20230636
[2]	耿晓彬, 李顶根, 徐波. 固态电解质电池锂枝晶生长机械应力-热力学相场模拟研究. 物理学报, 2023, 72(22): 220201. doi: 10.7498/aps.72.20230824
[3]	徐晗, 张璐. 空间电荷层效应对固体氧化物燃料电池三相界面附近氧空位传输的影响. 物理学报, 2021, 70(12): 128801. doi: 10.7498/aps.70.20210012
[4]	游逸玮, 崔建文, 张小锋, 郑锋, 吴顺情, 朱梓忠. 锂磷氧氮(LiPON)固态电解质与Li负极界面特性. 物理学报, 2021, 70(13): 136801. doi: 10.7498/aps.70.20202214
[5]	周逸凡, 杨慕紫, 佘峰权, 龚力, 张晓琪, 陈建, 宋树芹, 谢方艳. X射线光电子能谱在固态锂离子电池界面研究中的应用. 物理学报, 2021, 70(17): 178801. doi: 10.7498/aps.70.20210180
[6]	陆敬予, 柯承志, 龚正良, 李德平, 慈立杰, 张力, 张桥保. 原位表征技术在全固态锂电池中的应用. 物理学报, 2021, 70(19): 198102. doi: 10.7498/aps.70.20210531
[7]	. 固态电池中的物理问题专题编者按. 物理学报, 2020, 69(22): 220101. doi: 10.7498/aps.69.220101
[8]	王娇, 刘少辉, 陈长青, 郝好山, 翟继卫. 钛酸钡基/聚偏氟乙烯复合介质材料的界面改性与储能性能. 物理学报, 2020, 69(21): 217702. doi: 10.7498/aps.69.20201031
[9]	拱越, 谷林. 全固态电池中界面的结构演化和物质输运. 物理学报, 2020, 69(22): 226801. doi: 10.7498/aps.69.20201160
[10]	冯吴亮, 王飞, 周星, 吉晓, 韩福东, 王春生. 固态电解质与电极界面的稳定性. 物理学报, 2020, 69(22): 228206. doi: 10.7498/aps.69.20201554
[11]	彭林峰, 曾子琪, 孙玉龙, 贾欢欢, 谢佳. 富钠反钙钛矿型固态电解质的简易合成与电化学性能. 物理学报, 2020, 69(22): 228201. doi: 10.7498/aps.69.20201227
[12]	赵宁, 穆爽, 郭向欣. 石榴石型固态锂电池中的物理问题. 物理学报, 2020, 69(22): 228804. doi: 10.7498/aps.69.20201191
[13]	余启鹏, 刘琦, 王自强, 李宝华. 全固态金属锂电池负极界面问题及解决策略. 物理学报, 2020, 69(22): 228805. doi: 10.7498/aps.69.20201218
[14]	曹文卓, 李泉, 王胜彬, 李文俊, 李泓. 金属锂在固态电池中的沉积机理、策略及表征. 物理学报, 2020, 69(22): 228204. doi: 10.7498/aps.69.20201293
[15]	张桥保, 龚正良, 杨勇. 硫化物固态电解质材料界面及其表征的研究进展. 物理学报, 2020, 69(22): 228803. doi: 10.7498/aps.69.20201581
[16]	陶颖, 祁宁, 王波, 陈志权, 唐新峰. 氧化铟/聚(3,4-乙烯二氧噻吩)复合材料的微结构及其热电性能研究. 物理学报, 2018, 67(19): 197201. doi: 10.7498/aps.67.20180382
[17]	刘相, 谢凯, 郑春满, 王军. 不同气氛下裂解含苯环聚硅氧烷制备锂离子电池Si-O-C复合负极材料的电池性能研究. 物理学报, 2011, 60(11): 118202. doi: 10.7498/aps.60.118202
[18]	阚鹏志, 赵谡玲, 徐征, 孔超, 王大伟, 闫悦. ZnO纳米棒在聚［2-甲氧基-5-（2-乙基-己氧基）-1，4-苯撑乙烯撑］固态阴极射线发光器件中的应用研究. 物理学报, 2010, 59(1): 616-619. doi: 10.7498/aps.59.616
[19]	孔超, 徐征, 赵谡玲, 张福俊, 黄金英, 闫光, 厉军明. Si3N4做电子加速层的聚［2-甲氧基-5-(2-乙基-己氧基)-1，4-苯撑乙烯撑］固态阴极射线发光. 物理学报, 2008, 57(12): 7891-7895. doi: 10.7498/aps.57.7891
[20]	吴伟才, 周印华, 温善鹏, 韩靓, 田文晶. 溶剂效应对聚苯撑乙烯掺杂苝二酰亚胺太阳电池性能的影响. 物理学报, 2007, 56(8): 5003-5008. doi: 10.7498/aps.56.5003

计量

文章访问数: 12466
PDF下载量: 543
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板

聚氧乙烯基聚合物固态电池的界面研究进展