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By modeling and analyzing porous alumina (PA), a method to modulate the colors of PA templates is proposed, which is based on the preparation of PA templates and the atomic layer deposition (ALD) technique. Referring to the experimentally prepared PA samples, theoretical simulations are carried out for a series of PA templates with the same hole-diameter and hole-interval, but with different hole-depths. The relationship between the modulated colors and the hole-depths are thus disclosed. By controlling the time of anodization in oxalic acidsolution, two PA samples with different hole-depths (296 nm and 373 nm) were prepared, both with an average hole-diameter of 40 nm and an average hole-interval of 100 nm, respectively. ALD processing is then applied to deposit a layer of Fe2O3 film with total thickness of 16.8 nm on these samples. It was experimentally observed that the processed PA samples show different colors which change with hole-depths. The experimental results are in good agreement with the theoretical simulations, which proves the feasibility of color modulation with this method.
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Keywords:
- porous alumina /
- color modulation /
- atomic layer deposition
[1] Hideki Masuda, Kenji Fukuda 1995 Science 268 1466
[2] Hideki Masuda, Haruki Yamada, Masahiro Satoh, Hidetaka Asoh 1997 Applied Physics Letter 71 2770
[3] Choi J, Schilling J, Nielsch K, Hillebrand R, Reiche M, Wehrspohn R B, Gosele U 2002 Materials Research Society 722 L5.2.1
[4] Zheng W J, Fei G T , Wang B, Zhang L D 2009 Nanoscale Research Letters 4 665
[5] Wang B, Fei G T, Wang M, Kong M G, Zhang L D 2007 Nanotechnology 18 365601
[6] Zheng W J, Fei G T, Wang B, Jin Z, Zhang L D 2009 Materials Letters 63 706
[7] Huang J Y, Wang X D, Wang Z L 2006 Nano letters 6 2325
[8] Chen H M, Hsin C F, Liu R S, Hu S F, Huang C Y 2006 Journal of The Electrochemical Society 154 11
[9] Ma C L 2004 Acta Phys. Sin. 53 1952(in Chinese)[马春兰 2004 物理学报 53 1952]
[10] Wang C W, Wang J, Li Y 2005 Acta Phys. Sin. 54 439(in Chinese)[王成伟、王 建、李燕等 2005 物理学报 54 439]
[11] Li Q, Wang K G, Dang W J 2010 Acta Phys. Sin. 59 5851 (in Chinese) [李 强、王凯歌、党维军 2010 物理学报 59 5851]
[12] Hornyak G L, Patrissi C J, Oberhauser E B, Martin C R, Valmalette J C, Lemaire L, Dutta J, Hofmann H 1997 Nanostructured Materials 9 571
[13] Zhang D X, Zhang H J, He Y L 2006 Microscopy Research & Technique 69 267
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[1] Hideki Masuda, Kenji Fukuda 1995 Science 268 1466
[2] Hideki Masuda, Haruki Yamada, Masahiro Satoh, Hidetaka Asoh 1997 Applied Physics Letter 71 2770
[3] Choi J, Schilling J, Nielsch K, Hillebrand R, Reiche M, Wehrspohn R B, Gosele U 2002 Materials Research Society 722 L5.2.1
[4] Zheng W J, Fei G T , Wang B, Zhang L D 2009 Nanoscale Research Letters 4 665
[5] Wang B, Fei G T, Wang M, Kong M G, Zhang L D 2007 Nanotechnology 18 365601
[6] Zheng W J, Fei G T, Wang B, Jin Z, Zhang L D 2009 Materials Letters 63 706
[7] Huang J Y, Wang X D, Wang Z L 2006 Nano letters 6 2325
[8] Chen H M, Hsin C F, Liu R S, Hu S F, Huang C Y 2006 Journal of The Electrochemical Society 154 11
[9] Ma C L 2004 Acta Phys. Sin. 53 1952(in Chinese)[马春兰 2004 物理学报 53 1952]
[10] Wang C W, Wang J, Li Y 2005 Acta Phys. Sin. 54 439(in Chinese)[王成伟、王 建、李燕等 2005 物理学报 54 439]
[11] Li Q, Wang K G, Dang W J 2010 Acta Phys. Sin. 59 5851 (in Chinese) [李 强、王凯歌、党维军 2010 物理学报 59 5851]
[12] Hornyak G L, Patrissi C J, Oberhauser E B, Martin C R, Valmalette J C, Lemaire L, Dutta J, Hofmann H 1997 Nanostructured Materials 9 571
[13] Zhang D X, Zhang H J, He Y L 2006 Microscopy Research & Technique 69 267
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