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Spinel structure ZnFe2O4 were prepared by solid state reaction and hydrothermal method. Investigations on X-ray diffraction (XRD), scanning electron microscopy (SEM) and specific area measuements indicate that the samples are well-crystallized cubic spinel structre with average particle sizes of 500 nm and 200 nm and specific areas of 136.7 m2 g-1 and 382.5 m2 g-1 for solid state reaction and hydrothermal method, respectively. The ZnFe2O4 samples show high lithium-storage capacity and good reversibility. Compared with the sample prepared by solid state reaction, ZnFe2O4 prepared by hydrothermal method demonstrate better electrochemical performances. Its specific charge capacity decays from 750 mAh g-1 to 702 mAh g-1 after 30 cycles, with capacity retention of 93.6 %. ZnFe2O4 is a very promising anode material for lithium ion battery for its easy preparation, low coat and good electrochemical performances.
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Keywords:
- ZnFe2O4 /
- spinel structure /
- electrochemical performances /
- lithium ion battery
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[2] Kang K, Meng Y S, Breger J, Grey C P, Ceder G 2006 Science 311 977
[3] Lee J H, Lee H Y, Ohb S M, Lee S J, Lee K Y, Lee S M 2007 J. Power Sources 166 250
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[6] Qiu W H, Zhang G, Lu S G, Liu Q G 1999 Solid State Ionics 121 73
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[10] Hou X H, Yu H W, Hu S J 2010 Acta Phys. Sin. 59 8226 (in Chinese) [侯贤华、余洪文、胡社军 2010 物理学报 59 8226]
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[13] Chen J, Xu L, Li W, Gou X 2005 Adv. Mater. 17 582
[14] Taberna P L, Mitra S, Poizot P, Simon P, Tarascon J M 2006 Nat. Mater. 5 567
[15] Son D, Kim E, Kim T G, Kim M G, Cho J, Park B 2004 Appl. Phys. Lett. 85 5875
[16] NuLi Y N, Chu Y Q, Qin Q Z 2004 J. Electrochem. Soc. 151 A1077
[17] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R 2008 Electrochim. Acta 53 2380
[18] Chu Y Q, Fu Z W, Qin Q Z 2004 Electrochim. Acta 49 4915
[19] Alcántara R, Jaraba M, Lavela P, Tirado J L, Jumas J C, Fourcade J O 2003 Electrochem. Commun. 5 16
[20] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R 2007 Adv. Funct. Mater. 17 2855
[21] Reddy M V, Yu T, Sow C H, Shen Z X, Lim C T, Subba Rao G V, Chowdari B V R 2007 Adv. Funct. Mater. 17 2792
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[1] Sato K, Noguchi M, Demachi A, Oki N, Endo M 1994 Science 264 556
[2] Kang K, Meng Y S, Breger J, Grey C P, Ceder G 2006 Science 311 977
[3] Lee J H, Lee H Y, Ohb S M, Lee S J, Lee K Y, Lee S M 2007 J. Power Sources 166 250
[4] Tollefson J 2008 Nature 456 436
[5] Armand M, Tarascon J M 2008 Nature 451 652
[6] Qiu W H, Zhang G, Lu S G, Liu Q G 1999 Solid State Ionics 121 73
[7] Zhou Y K, Cao L, Zhang F B, He B L, Li H L 2003 J. Electrochem. Soc. 150 A1246
[8] Hou X H, Du S J, Li W S, Zhao L Z, Yu H W, Tan C L 2008 Acta Phys. Sin. 57 2374 (in Chinese) [侯贤华、杜社军、李伟 善、赵灵智、余洪文、谭春林 2008 物理学报 57 2374] [9] Hou Z F, Liu H Y, Zhu Z Z, Huang M C, Yang Y 2003 Acta Phys. Sin. 52 2209 (in Chinese) [候柱锋、刘慧英、朱梓忠、黄美纯、杨 勇 2003物理学报 52 2209]
[9] Chen L B, Yu H C, Xu C M, Wang T H 2009 Acta Phys. Sin. 58 5029 (in Chinese) [陈立宝、虞红春、许春梅、王太宏 2009物理学报 58 5029]
[10] Hou X H, Yu H W, Hu S J 2010 Acta Phys. Sin. 59 8226 (in Chinese) [侯贤华、余洪文、胡社军 2010 物理学报 59 8226]
[11] Liu H Y, Zhu Z Z, Yang Y 2008 Acta Phys. Sin. 57 5182 (in Chinese) [刘慧英、朱梓忠、杨 勇 2008 物理学报 57 5182]
[12] Larcher D, Masquelier C, Bonnin D, Chabre Y, Masson V, Leriche J B, Tarascon J M 2003 J. Electrochem. Soc. 150 A133
[13] Chen J, Xu L, Li W, Gou X 2005 Adv. Mater. 17 582
[14] Taberna P L, Mitra S, Poizot P, Simon P, Tarascon J M 2006 Nat. Mater. 5 567
[15] Son D, Kim E, Kim T G, Kim M G, Cho J, Park B 2004 Appl. Phys. Lett. 85 5875
[16] NuLi Y N, Chu Y Q, Qin Q Z 2004 J. Electrochem. Soc. 151 A1077
[17] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R 2008 Electrochim. Acta 53 2380
[18] Chu Y Q, Fu Z W, Qin Q Z 2004 Electrochim. Acta 49 4915
[19] Alcántara R, Jaraba M, Lavela P, Tirado J L, Jumas J C, Fourcade J O 2003 Electrochem. Commun. 5 16
[20] Sharma Y, Sharma N, Subba Rao G V, Chowdari B V R 2007 Adv. Funct. Mater. 17 2855
[21] Reddy M V, Yu T, Sow C H, Shen Z X, Lim C T, Subba Rao G V, Chowdari B V R 2007 Adv. Funct. Mater. 17 2792
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