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中国物理学会期刊

水系镁离子电池正极材料钠锰氧化物的制备及电化学性能

CSTR: 32037.14.aps.70.20202130

Preparation and electrochemical performance of sodium manganese oxides as cathode materials for aqueous Mg-ion batteries

CSTR: 32037.14.aps.70.20202130
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  • 近年来镁离子电池正极材料的研发成为研究热点, 提高电池的高倍率性能和循环稳定性成为主要研究目标. 本文采用水热法制备了纳米线和纳米片共混结构的钠锰氧化物(Na0.55Mn2O4·1.5H2O)纳米材料, 并用X−射线衍射和扫描电子显微镜进行表征, 通过充放电测试仪和电化学工作站进行变倍率充放电循环和变扫速循环伏安测试. 结果表明水热反应时间对材料的相结构和形貌组成影响显著, 其中水热反应72 h样品(NMO-72)中纳米片和纳米线形成紧密共混, 纳米片有效填充到纳米线交叉空隙中, 提高了材料的振实密度. 并且NMO-72材料具有更高的放电比容量和倍率循环性能. 在50 mA·g–1电流密度下, NMO-72的放电比容量达到229.1 mAh·g–1; 在1000 mA·g–1电流密度下, NMO-72材料的放电比容量稳定在81 mAh·g–1; 而电流密度再次回到50 mA·g–1时, 其放电比容量稳定保持在164.7 mAh·g–1. 同时, 循环伏安测试表明NMO-72材料与其他材料相比, 具有最佳的镁离子扩散动力学性能, 由此NMO-72材料具有更为优异的可逆比容量、高倍率性能和循环稳定性.

     

    In recent years, the cathode materials of magnesium ion batteries have become a hot point of research, and the improvement of high-rate performance and cycle stability has become the main research goal. In this paper, sodium manganese oxide (Na0.55Mn2O4·1.5H2O) nanomaterial with a blended structure of nanowires and nanosheets is prepared by the hydrothermal method. The structure and morphology of the material are analyzed by X-ray diffraction and scanning electron microscopy. The variable rate charge-discharge curves and variable scan rate cyclic voltammetry curves are obtained by a battery tester and electrochemical workstation, respectively. The results show that the hydrothermal reaction time has significant effects on phase structure and morphology composition of the material. The nanosheets and nanowires in the sample form a closely blend by 72-h hydrothermal reaction (NMO-72), and the nanosheets effectively fill into the intersecting space of the nanowires. In this way, the tap density of the material is improved. More importantly, NMO-72 has higher discharge specific capacity and rate cycling performance. At a current density of 50 mA·g–1, the discharge specific capacity of NMO-72 reaches 229.1 mAh·g–1. At a current density of 1000 mA·g–1, the discharge specific capacity of the NMO-72 stabilizes at 81 mAh·g–1. When the current density returns to 50 mA·g–1 again, the discharge specific capacity remains stable at 164.7 mAh·g–1. Besides, the cyclic voltammetry test shows that the NMO-72 material has more excellent magnesium ion diffusion kinetic performance than other materials. Therefore, the NMO-72 material has more excellent reversible specific capacity, high rate performance and cycling stability.

     

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