Electromagnetic scattering characteristics change significantly from breaking waves, which is considered to be one reason for sea spike phenomenon（HH polarization scattering intensity close to or even greater than VV polarization scattering intensity). Spiky sea clutter is often treated falsely as targets, which affects radar performance in target detection in the sea surface background. Thus the investigation on the physical mechanism of the sea spike phenomenon can help mitigate false alarms. In this paper, the authors investigate the microwave backscattering from the wedge-shaped breaking waves, which is simulated with the dihedral impedance wedge of finite length. The physical optical field of the breaking waves is calculated with the Kirchhoff approximation. Based on the Maliuzhinets method with using the precise impedance boundary condition, the impedance wedge scattering solution in spectral integral representation is presented. The spectral function is derived by the perturbation method with respect to the oblique incident angle based on the incidence normal to or grazing to the edge. After obtaining the spectral function, the asymptotic theory is used to determine the diffraction field of impedance wedge at an arbitrary skew incidence. The equivalent edge currents are derived from the uniform diffraction of impedance wedge by combining the physical optical coefficients and diffracted coefficients. Backscattering radar cross-sections（RCSs) of the diffracted field from 120 impedance wedge are calculated in both HH and VV polarizations, and the effects of frequency and permittivity on the wedge diffraction are discussed as well. The physical optical field backscattering from 135 impedance wedge is compared with the total field with considering the diffraction effects. Further calculations and analyses for backscattering from the three-dimensional extension breaking waves are presented by using the contribution of edge diffraction field to correct the physical optics field. Numerical results show that the backscattering RCS of impedance diffracted field in HH polarization is greater than that in VV polarization in the Keller cone. Therefore, the diffraction effects will make the backscattering RCS of the total field in HH polarization greater than that in VV polarization when the breaking wave grows to near-collapse stage at a small grazing angle with upwind observation. This indicates that the wedge diffraction is one of the causes of sea spike phenomenon.