面向高温介电储能应用的聚合物基电介质材料研究进展

董久锋; 邓星磊; 牛玉娟; 潘子钊; 汪宏

doi:10.7498/aps.69.20201006

摘要

介电储能电容器以其充放电速度快、功率密度高等优点, 在现代电子和电力系统中得到了广泛应用. 目前, 与可再生能源相关的新兴产品, 如混合动力汽车、并网光伏发电和风力发电、井下油气勘探等, 对于介电储能电容器的高温储能性能提出了更高的要求. 本文总结了近年来关于聚合物及其纳米复合电介质材料的高温介电储能研究中的代表性研究进展, 为该领域科研工作者进一步研究提供参考. 首先介绍了电介质材料储能的物理机理, 并对电介质材料的几种电导机制进行了总结和分析; 接下来介绍了目前提高聚合物基电介质材料高温储能性能的几种方法, 包括纳米复合改性和相关的层状结构设计, 以及高分子聚合物的分子结构设计和化学交联处理等; 最后对聚合物基电介质材料在高温储能应用领域中尚待解决的科学技术问题进行了讨论, 并展望了未来可能的研究方向.

关键词:

电容器 /
介电材料 /
高温 /
能量密度

Abstract

Dielectric capacitors are widely used in modern electronic systems and power systems because of their advantages of fast charge discharge speed and high-power density. Nowadays, the new products related to renewable energy, such as hybrid electric vehicles, grid connected photovoltaic power generation and wind turbines, downhole oil, gas exploration, etc., put forward higher requirements for the energy storage capabilities of dielectric capacitors in elevated-temperature. In this review, the research progress of the polymer-based dielectrics for high-temperature capacitor energy storage in recent years is systematically reviewed to offer benefits for further study. Firstly, the physical mechanism of energy storage of dielectric materials is introduced, and several conduction mechanisms of dielectric materials are summarized and analyzed; then, several strategies to improve the high-temperature energy storage performance of polymer dielectrics are presented, including the nanocomposite modification and design of layer-structured polymer composites, and the molecular structure design and chemical crosslinking treatment of dielectric polymer. Finally the scientific and technological problems in the application of dielectric polymer and their nanocomposites for high-temperature capacitor energy storage are discussed, and a possible research direction in the future is prospected.

Keywords:

作者及机构信息

1.
南方科技大学材料科学与工程系, 深圳　518055

2.
西安交通大学电子与信息工程学院, 西安　710049

通信作者: 汪宏, wangh6@sustech.edu.cn

基金项目: 深圳市科技计划(批准号: KQTD20180411143514543, JCYJ20180504165831308)、广东省重点领域研发计划(批准号: 2020B010176001)和深圳市工程研究中心项目(批准号: [2018]1433)资助的课题

Authors and contacts

1.
Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, China

2.
School of Electronic and Information Engineering, Xi’an Jiaotong University, Xi’an 710049, China

Corresponding author: Wang Hong, wangh6@sustech.edu.cn

Funds: Project supported by the Science and Technology Program of Shenzhen, China (Grant Nos. KQTD20180411143514543, JCYJ20180504165831308), the Key Area R&D Program of Guangdong Province, China (Grant No. 2020B010176001), and the DRC Project of Shenzhen, China (Grant No. [2018]1433)

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参考文献

[1]	Pan H, Li F, Liu Y, Zhang Q H, Wang M, Lan S, Zheng Y P, Ma J, Gu L, Shen Y, Yu P, Zhang S J, Chen L Q, Lin Y H, Nan C W 2019 Science 365 578 Google Scholar
[2]	Lin X R, Salari M, Arava L M R, Ajayan P M, Grinstaff M W 2016 Chem. Soc. Rev. 45 5848 Google Scholar
[3]	Luo H, Zhou X F, Ellingford C, Zhang Y, Chen S, Zhou K C, Zhang D, Bowen C B, Wan C Y 2019 Chem. Soc. Rev. 48 4424 Google Scholar
[4]	Huang X Y, Sun B, Zhu Y K, Li S T, Jiang P K 2019 Prog. Mater. Sci. 100 187 Google Scholar
[5]	Yuan Q B, Yao F Z, Cheng S D, Wang L X, Wang Y F, Mi S B, Wang Q, Wang X H, Wang H 2020 Adv. Funct. Mater. 30 2000191 Google Scholar
[6]	Li Q, Zhang G Z, Liu F H, Han K, Gadiniski M R, Xiong C X, Wang Q 2015 Energy Environ. Sci. 8 922 Google Scholar
[7]	Li Q, Yao F Z, Liu Y, Zhang G Z, Wang H, Wang Q 2018 Ann. Rev. Mater. Res. 48 219 Google Scholar
[8]	Watson J, Castro G 2012 Analog Dialogue 46 1
[9]	Tan D, Zhang L, Chen Q, Irwin P 2014 J. Electron. Mater. 43 4569 Google Scholar
[10]	Johnson R W, Evans J L, Jacobsen P, Thompson J R, Christopher M 2004 IEEE Trans. Electron. Packag. Manuf. 27 164 Google Scholar
[11]	Barshaw E J, White J, Chait M J, Cornette J B, Bustamante J, Folli F, Biltchick D, Borelli G, Pocco G, Rabuffi M 2007 IEEE Trans. Magn. 43 223 Google Scholar
[12]	李吉超, 王春雷, 钟维烈, 薛旭艳, 王渊旭 2002 物理学报 51 776 Google Scholar Li J C, Wang C L, Zhong W L, Xue X Y, Wang Y X 2002 Acta Phys. Sin. 51 776 Google Scholar
[13]	Gadinski M R, Han K, Li Q, Zhang G, Reainthippayasakul W, Wang Q 2014 ACS Appl. Mater. Interfaces 6 18981 Google Scholar
[14]	Chu B, Zhou X, Ren K, Neese B, Lin M, Wang Q, Bauer F, Zhang Q M 2006 Science 313 334 Google Scholar
[15]	Zhou X, Zhao X, Suo Z, Zou C, Runt J, Liu S, Zhang S, Zhang Q M 2009 Appl. Phys. Lett. 94 143 Google Scholar
[16]	Li Q, Chen L, Gadinski M R, Zhang S H, Zhang G Z, Li H U, Iagodkine E, Haque A, Chen L Q, Jackson T N, Wang Q 2015 Nature 523 576 Google Scholar
[17]	Prajapati P, Thakui V K, Gupta R 2016 Chem. Rev. 116 4260 Google Scholar
[18]	Zhou L, Jiang Y F 2019 Mater. Sci. Technol. 36 1 Google Scholar
[19]	Yao Z H, Song Z, Hao H, Yu Z Y, Cao M H, Zhang S J, Lanagan M T, Liu H X 2017 Adv. Mater. 29 1601727 Google Scholar
[20]	Palneedi H, Peddigari M, Hwang G T, Jeong D Y, Ryu J 2018 Adv. Funct. Mater. 28 1803665 Google Scholar
[21]	Kojima K, Takai Y, Ieda M 1986 J. Appl. Phys. 59 2655 Google Scholar
[22]	Chiu F C 2014 Adv. Mater. Sci. Eng. 2014 1 Google Scholar
[23]	Akram S, Yang Y, Zhong X, Bhutta S, Wu G N, Castellon J, Zhou K 2017 IEEE Trans. Dielectr. Electr. Insul. 24 3505 Google Scholar
[24]	Liu A, Zhu H H, Sun H B, Xu Y, Noh Y Y 2018 Adv. Mater. 30 1706364 Google Scholar
[25]	Vecchio M A, Meddeb A B, Lanagan M T, Ounaies Z, Shallenberger J R 2018 J. Appl. Phys. 124 114102 Google Scholar
[26]	Sawa A 2008 Mater. Today 11 28 Google Scholar
[27]	Angle R L, Talley H E 1978 IEEE Trans. Electron Devices 25 1277 Google Scholar
[28]	Chiu F C, Lee C Y, Pan T M 2009 J. Appl. Phys. 105 074103 Google Scholar
[29]	Calvet L, Wheeler R, Reed M 2002 Appl. Phys. Lett. 80 1761 Google Scholar
[30]	Chiu F C 2006 J. Appl. Phys. 100 114102 Google Scholar
[31]	Shen Z H, Wang J J, Jiang J Y, Huang S X, Lin Y H, Nan C W, Chen L Q, Shen Y 2019 Nat. Commun. 10 1843 Google Scholar
[32]	Laghari J R, Sarjeant W J 1992 IEEE Trans. Power Electron. 7 251 Google Scholar
[33]	Shen Z H, Wang J J, Lin Y H, Nan C W, Chen L Q, Shen Y 2018 Adv. Mater. 30 1704380 Google Scholar
[34]	Chi Q G, Gao Z Y, Zhang T D, Zhang C H, Zhang Y, Chen Q G, Wang X, Lei Q Q 2019 ACS Sustainable Chem. Eng. 7 748 Google Scholar
[35]	Tong H, Fu J, Ahmad A, Fan T, Hou Y D, Xu J 2019 Macromol. Mater. Eng. 304 1800709 Google Scholar
[36]	James J C 1986 Polym. Compos. 7 158 Google Scholar
[37]	Ho J S, Greenbaum S G 2018 ACS Appl. Mater. Interfaces 10 29189 Google Scholar
[38]	Mannodi-Kanakkithodi A, Treich G M, Huan T D, Ma R, Tefferi M, Cao Y, Sotzing G A, Ramprasad R 2016 Adv. Mater. 28 6277 Google Scholar
[39]	Klein R J, Barber P, Chance W M, Loye H C Z 2012 IEEE Trans. Dielectr. Electr. Insul. 19 1234 Google Scholar
[40]	Diaham S, Saysouk F, Locatelli M L, Lebey T 2016 IEEE Trans. Dielectr. Electr. Insul. 23 2795 Google Scholar
[41]	Chi Q G, Dong J F, Zhang C H, Wong C P, Wang X, Lei Q Q 2016 J. Mater. Chem. C 4 8179 Google Scholar
[42]	Wang S, Huang X Y, Wang G Y, Wang Y, He J L, Jiang P K 2015 J. Phys. Chem. C 119 25307 Google Scholar
[43]	冯奇, 李梦凯, 唐海通, 王晓东, 高忠民, 孟繁玲 2016 物理学报 65 188101 Google Scholar Feng Q, Li M K, Tang H T, Wang X D, Gao Z M, Meng F L 2016 Acta Phys. Sin. 65 188101 Google Scholar
[44]	Pan Z B, Yao L M, Ge G L, Shen B, Zhai J W 2018 J. Mater. Chem. A 6 14614 Google Scholar
[45]	Zou K L, Dan Y, Yu Y X, Zhang Y, Zhang Q F, Lu Y M, Huang H T, Zhang X, He Y B 2019 J. Mater. Chem. A 7 13473 Google Scholar
[46]	Feng Y, Zhou Y H, Zhang T D, Zhang C H, Zhang Y Q, Zhang Y, Chen Q G, Chi Q G 2020 Energy Storage Mater. 25 180 Google Scholar
[47]	Yu K, Wang H, Zhou Y C, Bai Y Y, Niu Y J 2013 J. Appl. Phys. 113 034105 Google Scholar
[48]	Yu K, Niu Y J, Xiang F, Zhou Y C, Bai Y Y, Wang H 2013 J. Appl. Phys. 114 174107 Google Scholar
[49]	Wu Y H, Zha J W, Yao Z Q, Sun F, Li R K Y, Dang Z M 2015 RSC Adv. 9 44749 Google Scholar
[50]	Huang X Y, Jiang P K 2015 Adv. Mater. 27 546 Google Scholar
[51]	Hu P H, Sun W D, Fan M Z, et al. 2018 Appl. Surf. Sci. 458 743 Google Scholar
[52]	Sun W D, Lu X J, Jiang J Y, Zhang X, Hu P H, Li M, Lin Y H, Nan C W, Shen Y 2017 J. Appl. Phys. 121 244101 Google Scholar
[53]	Shen Z H, Wang J J, Jiang J Y, Lin Y H, Nan C W, Chen L Q, Shen Y 2018 Adv. Energy Mater. 8 1800509 Google Scholar
[54]	Zhu Y K, Zhu Y J, Huang X Y, Chen J, Li Q, He J L, Jiang P K 2019 Adv. Energy Mater. 9 1901826 Google Scholar
[55]	Li Y S, Zhou Y, Zhu Y J, Cheng S, Yuan C, Hu J, He J L, Li Q 2020 J. Mater. Chem. A 8 6576 Google Scholar
[56]	Wu L Y, Wu K, Liu D Y, Huang R, Huo J L, Chen F, Fu Q 2018 J. Mater. Chem. A 6 7573 Google Scholar
[57]	Wu L Y, Wu K, Lei C X, Liu D Y, Du R N, Chen F, Fu Q 2019 J. Mater. Chem. A 7 7664 Google Scholar
[58]	Liu F H, Li Q, Li Z Y, Liu Y, Dong L J, Xiong C X, Wang Q 2017 Compos. Sci. Technol. 142 139 Google Scholar
[59]	Ai D, Li H, Zhou Y, et al. 2020 Adv. Energy Mater. 10 1903881 Google Scholar
[60]	Li H, Ai D, Ren L L, Yao B, Han Z B, Shen Z H, Wang J J, Chen L Q, Wang Q 2019 Adv. Mater. 31 1900875 Google Scholar
[61]	Li H, Ren L L, Ai D, Han Z B, Liu Y, Yao B, Wang Q 2020 InfoMat. 2 389 Google Scholar
[62]	Thakur Y, Zhang T, Iacob C, Yang T N, Bernholc J, Chen L Q, Runt J, Zhang Q M 2017 Nanoscale 9 10992 Google Scholar
[63]	Chadband W G 1992 IEE Rev. 38 404 Google Scholar
[64]	Zhang T, Chen X, Thakur Y, Lu B, Zhang Q Y, Runt J, Zhang Q M 2020 Sci. Adv. 6 6622 Google Scholar
[65]	Thakur Y, Lean M H, Zhang Q M 2017 Appl. Phys. Lett. 110 122905 Google Scholar
[66]	Bouharrasa F E, Raihane M, Ameduri B 2020 Prog. Mater. Sci. 113 100670 Google Scholar
[67]	Niu Y J, Xiang F, Wang Y F, Chen J, Wang H 2018 Phys. Chem. Chem. Phys. 20 6598 Google Scholar
[68]	Niu Y J, Wang H 2019 ACS Appl. Nano Mater. 2 627 Google Scholar
[69]	Zhang X, Li B W, Dong L J, Liu H X, Chen W, Shen Y, Nan C W 2018 Adv. Mater. Interfaces 5 1800096 Google Scholar
[70]	Pan Z B, Yao L M, Zhai J W, Yao X, Chen H 2018 Adv. Mater. 30 1705662 Google Scholar
[71]	Rahimabady M, Mirshekarloo M S, Yao K, Lu L 2013 Phys. Chem. Chem. Phys. 15 16242 Google Scholar
[72]	Liu S, Xue S X, Shen B, Zhai J W 2015 Appl. Phys. Lett. 107 032907 Google Scholar
[73]	Choudhury A 2012 Polym. Int. 61 696 Google Scholar
[74]	Luo H, Zhang D, Jiang C, Yuan X, Chen C, Zhou K C 2015 ACS Appl. Mater. Interfaces 7 8061 Google Scholar
[75]	Liu J, Shen Z H, Xu W H, Zhang Y, Qian X S, Jiang Z H, Zhang Y H 2020 Small 2000714 Google Scholar
[76]	Xu W H, Liu J, Chen T W, Jiang X Y, Qian X S, Zhang Y, Jiang Z H, Zhang Y H 2019 Small 15 1901582 Google Scholar
[77]	Zhou Y, Yuan C, Wang S J, Zhu Y J, Cheng S, Yang X, Yang Y, Hu J, He J L, Li Q 2020 Energy Storage Mater. 28 255 Google Scholar
[78]	Wang Y F, Cui J, Yuan Q B, Niu Y J, Bai Y Y, Wang H 2015 Adv. Mater. 27 6658 Google Scholar
[79]	Wang Y F, Wang L X, Yuan Q B, et al. 2018 Nano Energy 44 364 Google Scholar
[80]	Chen J, Wang Y F, Yuan Q B, Xu X W, Niu Y J, Wang Q, Wang H 2018 Nano Energy 54 288 Google Scholar
[81]	Jiang J Y, Shen Z H, Qian J, Dan Z, Guo M, He Y, Lin Y H, Nan C W, Chen L Q, Shen Y 2019 Nano Energy 62 220 Google Scholar
[82]	Chen J, Wang Y F, Xu X W, Yuan Q B, Niu Y J, Wang Q, Wang H 2019 J. Mater. Chem. A 7 3729 Google Scholar
[83]	Wang Y F, Chen J. Li Y, Niu Y J, Wang Q, Wang H 2019 J. Mater. Chem. A 7 2965 Google Scholar
[84]	Chen X Y, Tseng J K, Treufeld I, Mackey M, Schuele D E, Li R P, Fukuto M, Baer E, Zhu L 2017 J. Mater. Chem. C 5 10417 Google Scholar
[85]	Li Z P, Chen X Y, Zhang C, Baer E, Langhe D, Ponting Ml, Brubaker M, Hosking T, Li R P, Fukuto M, Zhu L 2019 ACS Appl. Polym. Mater. 1 867 Google Scholar
[86]	Tewari P, Rajagopalan R, Furman E, Lanagan M T 2010 Langmuir 26 18817 Google Scholar
[87]	Hu P H, Shen Y, Guan Y H, Zhang X H, Lin Y H, Zhang Q M, Nan C W 2014 Adv. Funct. Mater. 24 3172 Google Scholar
[88]	Pan Z B, Liu B H, Zhai J W, Yao L M, Yang K, Shen B 2017 Nano Energy 40 587 Google Scholar
[89]	Tseng J K, Tang S, Zhou Z, Mackey M, Carr J M, Mu R, Flandin L, Schuele D E, Baer E, Zhu L 2014 Polymer 55 8 Google Scholar
[90]	Mackey M, Hiltner A, Baer E, Flandin L, Wolak M A, Shirk J S 2009 J. Phys. D: Appl. Phys. 42 175304 Google Scholar
[91]	Li Q, Liu F H, Yang T N, Gadinski M R, Zhang G Z, Chen L Q, Wang Q 2016 Proc. Natl. Acad. Sci. U.S.A. 113 9995 Google Scholar
[92]	Azizi A, Gadinski M R, Li Q, AlSaud M A, Wang J J, Wang Y, Wang B, Liu F H, Chen L Q, Alem N, Wang Q 2017 Adv. Mater. 29 1701864 Google Scholar
[93]	Zhou Y, Li Q, Dang B, Yang Y, Shao T, Li H, Hu J, Zeng R, He J L, Wang Q 2018 Adv. Mater. 30 1805672 Google Scholar
[94]	Bonardd S, Moreno-Serna V, Kortaberria G, Díaz D D, Leiva A, Saldías C 2019 Polymer 11 317 Google Scholar
[95]	Peng X W, Wu Q, Jiang S H, Hanif M, Chen S L, Hou H Q 2014 J. Appl. Polym. Sci. 131 40828 Google Scholar
[96]	Zhuang Y B, Seong J G, Lee Y M 2019 Prog. Polym. Sci. 92 35 Google Scholar
[97]	Kao K C 2004 Dielectric Phenomena in Solids (San Diego: Academic Press) p573
[98]	Wang Y, Zhou X, Lin M R, Zhang Q M 2009 Appl. Phys. Lett. 94 154 Google Scholar
[99]	Cheng Z X, Lin M R, Wu S, Thakur Y, Zhou Y, Jeong D Y, Shen Q D, Zhang Q M 2015 Appl. Phys. Lett. 106 202902 Google Scholar
[100]	Wu S, Li W P, Lin M R, Burlingame Q, Chen Q, Payzant A, Xiao K, Zhang Q M 2013 Adv. Mater. 25 1734 Google Scholar
[101]	Qiao Y L, Islam M S, Yin X D, Han K, Yan Y, Zhang J Y, Wang Q, Ploehn H J, Tang C B 2015 Polymer 72 428 Google Scholar
[102]	Yuan X P, Matsuyama Y, Chung T C M 2010 Macromolecules 43 4011 Google Scholar
[103]	Misra M, Agarwal M, Sinkovits D W, Kumar S K, Wang C C, Pilania G, Ramprasad R, Weiss R A, Yuan X P, Mike Chung T C 2014 Macromolecules 47 1122 Google Scholar
[104]	Zhang M, Zhang L, Zhu M, Wang Y G, Li N W, Zhang Z J, Chen Q, An L N, Lin Y H, Nan C W 2016 J. Mater. Chem. A 4 4797 Google Scholar
[105]	Chou Y H, Yen H J, Tsai C L, Lee W Y, Liou G S, Chen W C 2013 J. Mater. Chem. C 1 3235 Google Scholar
[106]	Treufeld I, Wang D H, Kurish B A, Tan L S 2014 J. Mater. Chem. A 2 20683 Google Scholar
[107]	Zhang Z B, Wang D H, Litt M H, Tan L S, Zhu L 2018 Angew. Chem. Int. Ed. 130 1547 Google Scholar
[108]	Zhang Z B, Zheng J F, Premasiri K, Kwok M H, Li Q, Li R P, Zhang S B, Litt M H, Gao X P A, Zhu L 2020 Mater. Horiz. 7 592 Google Scholar
[109]	Yang R Q, Wei R B, Li K, Tong L F, Jia K, Liu X B 2016 Sci. Rep. 6 36434 Google Scholar
[110]	Yang J, Yang X L, Zou Y K, Zhan Y Q, Zhao R, Liu X B 2012 J. Appl. Polym. Sci. 126 1129 Google Scholar
[111]	Hanley T L, Burford R P, Fleming R J, Barber K W 2003 IEEE Electr. Insul. Mag. 19 13 Google Scholar
[112]	Zhou Q, Ma J, Dong S, Li X, Cui G 2019 Adv. Mater. 31 1902029 Google Scholar
[113]	Khanchaitit P, Han K, Gadinski M R, Li Q, Wang Q 2013 Nat. Commun. 4 2845 Google Scholar
[114]	Meereboer N L, Terzić I, van der Steeg P, Portale G, Loos K 2019 J. Mater. Chem. A 7 2795 Google Scholar
[115]	Chen X Z, Li Z W, Cheng Z X, Zhang J Z, Shen Q D, Ge H X, Li H T 2011 Macromol. Rapid Commun. 32 94 Google Scholar
[116]	Tan S, Hu X, Ding S, Zhang Z, Li H, Yang L 2013 J. Mater. Chem. A 1 10353 Google Scholar
[117]	Li H, Gadinski M R, Huang Y Q, et al. 2020 Energy Environ. Sci. 13 1279 Google Scholar
[118]	Chen S Y, Meng G D, Kong B, Xiao B, Wang Z D, Jing Z, Gao Y S, Wu G L, Wang H, Cheng Y H 2020 Chem. Eng. J. 387 123662 Google Scholar
[119]	Wang Y X, Huang X Y, Li T, Wang Z W, Li L Q, Gu X J, Jiang P K 2017 J. Mater. Chem. A 5 20737 Google Scholar
[120]	Hung C C, Wu H C, Chiu Y C, Tung S H, Chen W C 2016 J. Polym. Sci. Polym. Chem. 54 3224 Google Scholar

施引文献

图 1 介电电容器、电化学电容器与电池的能量密度和功率密度的对比图

Fig. 1. Comparison of power density and energy density capabilities of dielectric capacitors, electrochemical capacitors, and batteries.

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图 2 (a) 两个金属电极之间的电介质电容器示意图; (b) 电介质材料的电位移-电场强度关系曲线

Fig. 2. (a) Schematic diagram of dielectric capacitor between two metal electrodes; (b) electric displacement-electric field (D-E) hysteresis loop of a dielectric material.

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图 3 各种电导机制的示意图

Fig. 3. Schematic diagrams of various conduction mechanisms.

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图 4 (a) PI-STO纳米复合膜制备的电容器示意图; 当电场强度为200 kV/mm, 400 K温度条件下工作时, 由(b) 纯PI, (c) 垂直纳米纤维, (d) 垂直纳米片, (e) 随机纳米颗粒, (f) 平行纳米纤维, (g) 平行纳米片填充的纳米复合薄膜制备的不同电容器的稳态温度分布; (h) 薄膜电容器内的最大温度T_max与热导率κ_z和电导率σ_z的函数关系图; (i) 6种情况下, 最大温度T_max(红色条)、击穿强度劣化因子β (蓝色条)和介电损耗tanδ (黑色条)的性能比较^[53]

Fig. 4. (a) Schematic illustration of a real capacitor made by winding the PI-STO nanocomposite film. When working under an applied electric field of 200 kV/mm and a surrounding temperature of 400 K, the steady-state temperature distributions in different capacitors made by film nanocomposites filled by (b) pure polymer, (c) vertical nanofibers, (d) vertical nanosheets, (e) random nanoparticles, (f) parallel nanofibers, and (g) parallel nanosheets. (h) Maximal temperature T_max inside the film capacitor as function of the thermal conductivity component κ_z and electrical conductivity component σ_z. (i) Comparisons of the maximal temperature T_max (red bar), breakdown strength deterioration factor β (blue bar), and dielectric loss tanδ (black bar) among six circumstances^[53].

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图 5 (a) 在25 ℃和1 kHz下, PI纳米复合材料的介电常数和损耗随填料含量的变化; PI和PI纳米复合材料在150 ℃下的(b) Weibull击穿强度和(c)储能性能; (d) 150 ℃下, 模拟电流密度分布随Al₂O₃, HfO₂和TiO₂填料含量和外加电场的变化^[59]

Fig. 5. (a) Dielectric constant and loss of the PI nanocomposites as a function of filler content at 25 ℃ and 1 kHz; (b) Weibull breakdown strength and (c) energy density performance of PI and the PI nanocomposites measured at 150 ℃; (d) simulated current density distribution as a function of Al₂O₃, HfO₂, and TiO₂ filler content and the applied electric field at 150 ℃^[59].

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图 6 (a) 蜘蛛丝和蜘蛛丝的显微结构; (b) BN-BCB@DPAES复合材料的工艺图^[76]

Fig. 6. (a) Spider silk and the hierarchical microscopic structure of the spider silk; (b) schematic of preparation process of BN-BCB@DPAES films^[76].

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图 7 (a) Roll-to-roll PECVD示意图; (b) 聚合物表层沉积SiO₂的断面扫描电子显微镜图; (c) 聚合物表层沉积SiO₂的断面能量色散X射线图谱; (d) 在120 ℃下, BOPP薄膜表层沉积180 nm 厚度的SiO₂前后的储能密度和储能效率对比; (e) 在150 ℃下, 储能效率大于90%时, 各种电介质聚合物薄膜表层沉积SiO₂前后的最大放电能量密度^[93]

Fig. 7. (a) Schematic of the roll-to-roll PECVD; (b) cross-sectional scanning electron microscope image of the coating layer on polymer film; (c) element concentration from energy dispersive X-ray spectroscopy scanned across the coating layer deposited on polymer film; (d) charge-discharge efficiency and discharged energy density of BOPP and BOPP-SiO₂ films with 180 nm coating layer on each side of the polymer measured at 120 ℃; (e) maximum discharged energy density of the various dielectric films before and after coating achieved at above 90% charge-discharge efficiency measured at 150 ℃^[93].

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图 8 (a) 芳香族聚脲、聚硫脲和聚芳醚脲的结构式; (b)砜基化聚苯醚和砜基化自具微孔聚合物的结构式

Fig. 8. (a) Chemical structures of ArPU, ArPTU and PEEU; (b) chemical structures of SO₂-PPO₂₅, and SO₂-PIM.

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[1]	Pan H, Li F, Liu Y, Zhang Q H, Wang M, Lan S, Zheng Y P, Ma J, Gu L, Shen Y, Yu P, Zhang S J, Chen L Q, Lin Y H, Nan C W 2019 Science 365 578 Google Scholar
[2]	Lin X R, Salari M, Arava L M R, Ajayan P M, Grinstaff M W 2016 Chem. Soc. Rev. 45 5848 Google Scholar
[3]	Luo H, Zhou X F, Ellingford C, Zhang Y, Chen S, Zhou K C, Zhang D, Bowen C B, Wan C Y 2019 Chem. Soc. Rev. 48 4424 Google Scholar
[4]	Huang X Y, Sun B, Zhu Y K, Li S T, Jiang P K 2019 Prog. Mater. Sci. 100 187 Google Scholar
[5]	Yuan Q B, Yao F Z, Cheng S D, Wang L X, Wang Y F, Mi S B, Wang Q, Wang X H, Wang H 2020 Adv. Funct. Mater. 30 2000191 Google Scholar
[6]	Li Q, Zhang G Z, Liu F H, Han K, Gadiniski M R, Xiong C X, Wang Q 2015 Energy Environ. Sci. 8 922 Google Scholar
[7]	Li Q, Yao F Z, Liu Y, Zhang G Z, Wang H, Wang Q 2018 Ann. Rev. Mater. Res. 48 219 Google Scholar
[8]	Watson J, Castro G 2012 Analog Dialogue 46 1
[9]	Tan D, Zhang L, Chen Q, Irwin P 2014 J. Electron. Mater. 43 4569 Google Scholar
[10]	Johnson R W, Evans J L, Jacobsen P, Thompson J R, Christopher M 2004 IEEE Trans. Electron. Packag. Manuf. 27 164 Google Scholar
[11]	Barshaw E J, White J, Chait M J, Cornette J B, Bustamante J, Folli F, Biltchick D, Borelli G, Pocco G, Rabuffi M 2007 IEEE Trans. Magn. 43 223 Google Scholar
[12]	李吉超, 王春雷, 钟维烈, 薛旭艳, 王渊旭 2002 物理学报 51 776 Google Scholar Li J C, Wang C L, Zhong W L, Xue X Y, Wang Y X 2002 Acta Phys. Sin. 51 776 Google Scholar
[13]	Gadinski M R, Han K, Li Q, Zhang G, Reainthippayasakul W, Wang Q 2014 ACS Appl. Mater. Interfaces 6 18981 Google Scholar
[14]	Chu B, Zhou X, Ren K, Neese B, Lin M, Wang Q, Bauer F, Zhang Q M 2006 Science 313 334 Google Scholar
[15]	Zhou X, Zhao X, Suo Z, Zou C, Runt J, Liu S, Zhang S, Zhang Q M 2009 Appl. Phys. Lett. 94 143 Google Scholar
[16]	Li Q, Chen L, Gadinski M R, Zhang S H, Zhang G Z, Li H U, Iagodkine E, Haque A, Chen L Q, Jackson T N, Wang Q 2015 Nature 523 576 Google Scholar
[17]	Prajapati P, Thakui V K, Gupta R 2016 Chem. Rev. 116 4260 Google Scholar
[18]	Zhou L, Jiang Y F 2019 Mater. Sci. Technol. 36 1 Google Scholar
[19]	Yao Z H, Song Z, Hao H, Yu Z Y, Cao M H, Zhang S J, Lanagan M T, Liu H X 2017 Adv. Mater. 29 1601727 Google Scholar
[20]	Palneedi H, Peddigari M, Hwang G T, Jeong D Y, Ryu J 2018 Adv. Funct. Mater. 28 1803665 Google Scholar
[21]	Kojima K, Takai Y, Ieda M 1986 J. Appl. Phys. 59 2655 Google Scholar
[22]	Chiu F C 2014 Adv. Mater. Sci. Eng. 2014 1 Google Scholar
[23]	Akram S, Yang Y, Zhong X, Bhutta S, Wu G N, Castellon J, Zhou K 2017 IEEE Trans. Dielectr. Electr. Insul. 24 3505 Google Scholar
[24]	Liu A, Zhu H H, Sun H B, Xu Y, Noh Y Y 2018 Adv. Mater. 30 1706364 Google Scholar
[25]	Vecchio M A, Meddeb A B, Lanagan M T, Ounaies Z, Shallenberger J R 2018 J. Appl. Phys. 124 114102 Google Scholar
[26]	Sawa A 2008 Mater. Today 11 28 Google Scholar
[27]	Angle R L, Talley H E 1978 IEEE Trans. Electron Devices 25 1277 Google Scholar
[28]	Chiu F C, Lee C Y, Pan T M 2009 J. Appl. Phys. 105 074103 Google Scholar
[29]	Calvet L, Wheeler R, Reed M 2002 Appl. Phys. Lett. 80 1761 Google Scholar
[30]	Chiu F C 2006 J. Appl. Phys. 100 114102 Google Scholar
[31]	Shen Z H, Wang J J, Jiang J Y, Huang S X, Lin Y H, Nan C W, Chen L Q, Shen Y 2019 Nat. Commun. 10 1843 Google Scholar
[32]	Laghari J R, Sarjeant W J 1992 IEEE Trans. Power Electron. 7 251 Google Scholar
[33]	Shen Z H, Wang J J, Lin Y H, Nan C W, Chen L Q, Shen Y 2018 Adv. Mater. 30 1704380 Google Scholar
[34]	Chi Q G, Gao Z Y, Zhang T D, Zhang C H, Zhang Y, Chen Q G, Wang X, Lei Q Q 2019 ACS Sustainable Chem. Eng. 7 748 Google Scholar
[35]	Tong H, Fu J, Ahmad A, Fan T, Hou Y D, Xu J 2019 Macromol. Mater. Eng. 304 1800709 Google Scholar
[36]	James J C 1986 Polym. Compos. 7 158 Google Scholar
[37]	Ho J S, Greenbaum S G 2018 ACS Appl. Mater. Interfaces 10 29189 Google Scholar
[38]	Mannodi-Kanakkithodi A, Treich G M, Huan T D, Ma R, Tefferi M, Cao Y, Sotzing G A, Ramprasad R 2016 Adv. Mater. 28 6277 Google Scholar
[39]	Klein R J, Barber P, Chance W M, Loye H C Z 2012 IEEE Trans. Dielectr. Electr. Insul. 19 1234 Google Scholar
[40]	Diaham S, Saysouk F, Locatelli M L, Lebey T 2016 IEEE Trans. Dielectr. Electr. Insul. 23 2795 Google Scholar
[41]	Chi Q G, Dong J F, Zhang C H, Wong C P, Wang X, Lei Q Q 2016 J. Mater. Chem. C 4 8179 Google Scholar
[42]	Wang S, Huang X Y, Wang G Y, Wang Y, He J L, Jiang P K 2015 J. Phys. Chem. C 119 25307 Google Scholar
[43]	冯奇, 李梦凯, 唐海通, 王晓东, 高忠民, 孟繁玲 2016 物理学报 65 188101 Google Scholar Feng Q, Li M K, Tang H T, Wang X D, Gao Z M, Meng F L 2016 Acta Phys. Sin. 65 188101 Google Scholar
[44]	Pan Z B, Yao L M, Ge G L, Shen B, Zhai J W 2018 J. Mater. Chem. A 6 14614 Google Scholar
[45]	Zou K L, Dan Y, Yu Y X, Zhang Y, Zhang Q F, Lu Y M, Huang H T, Zhang X, He Y B 2019 J. Mater. Chem. A 7 13473 Google Scholar
[46]	Feng Y, Zhou Y H, Zhang T D, Zhang C H, Zhang Y Q, Zhang Y, Chen Q G, Chi Q G 2020 Energy Storage Mater. 25 180 Google Scholar
[47]	Yu K, Wang H, Zhou Y C, Bai Y Y, Niu Y J 2013 J. Appl. Phys. 113 034105 Google Scholar
[48]	Yu K, Niu Y J, Xiang F, Zhou Y C, Bai Y Y, Wang H 2013 J. Appl. Phys. 114 174107 Google Scholar
[49]	Wu Y H, Zha J W, Yao Z Q, Sun F, Li R K Y, Dang Z M 2015 RSC Adv. 9 44749 Google Scholar
[50]	Huang X Y, Jiang P K 2015 Adv. Mater. 27 546 Google Scholar
[51]	Hu P H, Sun W D, Fan M Z, et al. 2018 Appl. Surf. Sci. 458 743 Google Scholar
[52]	Sun W D, Lu X J, Jiang J Y, Zhang X, Hu P H, Li M, Lin Y H, Nan C W, Shen Y 2017 J. Appl. Phys. 121 244101 Google Scholar
[53]	Shen Z H, Wang J J, Jiang J Y, Lin Y H, Nan C W, Chen L Q, Shen Y 2018 Adv. Energy Mater. 8 1800509 Google Scholar
[54]	Zhu Y K, Zhu Y J, Huang X Y, Chen J, Li Q, He J L, Jiang P K 2019 Adv. Energy Mater. 9 1901826 Google Scholar
[55]	Li Y S, Zhou Y, Zhu Y J, Cheng S, Yuan C, Hu J, He J L, Li Q 2020 J. Mater. Chem. A 8 6576 Google Scholar
[56]	Wu L Y, Wu K, Liu D Y, Huang R, Huo J L, Chen F, Fu Q 2018 J. Mater. Chem. A 6 7573 Google Scholar
[57]	Wu L Y, Wu K, Lei C X, Liu D Y, Du R N, Chen F, Fu Q 2019 J. Mater. Chem. A 7 7664 Google Scholar
[58]	Liu F H, Li Q, Li Z Y, Liu Y, Dong L J, Xiong C X, Wang Q 2017 Compos. Sci. Technol. 142 139 Google Scholar
[59]	Ai D, Li H, Zhou Y, et al. 2020 Adv. Energy Mater. 10 1903881 Google Scholar
[60]	Li H, Ai D, Ren L L, Yao B, Han Z B, Shen Z H, Wang J J, Chen L Q, Wang Q 2019 Adv. Mater. 31 1900875 Google Scholar
[61]	Li H, Ren L L, Ai D, Han Z B, Liu Y, Yao B, Wang Q 2020 InfoMat. 2 389 Google Scholar
[62]	Thakur Y, Zhang T, Iacob C, Yang T N, Bernholc J, Chen L Q, Runt J, Zhang Q M 2017 Nanoscale 9 10992 Google Scholar
[63]	Chadband W G 1992 IEE Rev. 38 404 Google Scholar
[64]	Zhang T, Chen X, Thakur Y, Lu B, Zhang Q Y, Runt J, Zhang Q M 2020 Sci. Adv. 6 6622 Google Scholar
[65]	Thakur Y, Lean M H, Zhang Q M 2017 Appl. Phys. Lett. 110 122905 Google Scholar
[66]	Bouharrasa F E, Raihane M, Ameduri B 2020 Prog. Mater. Sci. 113 100670 Google Scholar
[67]	Niu Y J, Xiang F, Wang Y F, Chen J, Wang H 2018 Phys. Chem. Chem. Phys. 20 6598 Google Scholar
[68]	Niu Y J, Wang H 2019 ACS Appl. Nano Mater. 2 627 Google Scholar
[69]	Zhang X, Li B W, Dong L J, Liu H X, Chen W, Shen Y, Nan C W 2018 Adv. Mater. Interfaces 5 1800096 Google Scholar
[70]	Pan Z B, Yao L M, Zhai J W, Yao X, Chen H 2018 Adv. Mater. 30 1705662 Google Scholar
[71]	Rahimabady M, Mirshekarloo M S, Yao K, Lu L 2013 Phys. Chem. Chem. Phys. 15 16242 Google Scholar
[72]	Liu S, Xue S X, Shen B, Zhai J W 2015 Appl. Phys. Lett. 107 032907 Google Scholar
[73]	Choudhury A 2012 Polym. Int. 61 696 Google Scholar
[74]	Luo H, Zhang D, Jiang C, Yuan X, Chen C, Zhou K C 2015 ACS Appl. Mater. Interfaces 7 8061 Google Scholar
[75]	Liu J, Shen Z H, Xu W H, Zhang Y, Qian X S, Jiang Z H, Zhang Y H 2020 Small 2000714 Google Scholar
[76]	Xu W H, Liu J, Chen T W, Jiang X Y, Qian X S, Zhang Y, Jiang Z H, Zhang Y H 2019 Small 15 1901582 Google Scholar
[77]	Zhou Y, Yuan C, Wang S J, Zhu Y J, Cheng S, Yang X, Yang Y, Hu J, He J L, Li Q 2020 Energy Storage Mater. 28 255 Google Scholar
[78]	Wang Y F, Cui J, Yuan Q B, Niu Y J, Bai Y Y, Wang H 2015 Adv. Mater. 27 6658 Google Scholar
[79]	Wang Y F, Wang L X, Yuan Q B, et al. 2018 Nano Energy 44 364 Google Scholar
[80]	Chen J, Wang Y F, Yuan Q B, Xu X W, Niu Y J, Wang Q, Wang H 2018 Nano Energy 54 288 Google Scholar
[81]	Jiang J Y, Shen Z H, Qian J, Dan Z, Guo M, He Y, Lin Y H, Nan C W, Chen L Q, Shen Y 2019 Nano Energy 62 220 Google Scholar
[82]	Chen J, Wang Y F, Xu X W, Yuan Q B, Niu Y J, Wang Q, Wang H 2019 J. Mater. Chem. A 7 3729 Google Scholar
[83]	Wang Y F, Chen J. Li Y, Niu Y J, Wang Q, Wang H 2019 J. Mater. Chem. A 7 2965 Google Scholar
[84]	Chen X Y, Tseng J K, Treufeld I, Mackey M, Schuele D E, Li R P, Fukuto M, Baer E, Zhu L 2017 J. Mater. Chem. C 5 10417 Google Scholar
[85]	Li Z P, Chen X Y, Zhang C, Baer E, Langhe D, Ponting Ml, Brubaker M, Hosking T, Li R P, Fukuto M, Zhu L 2019 ACS Appl. Polym. Mater. 1 867 Google Scholar
[86]	Tewari P, Rajagopalan R, Furman E, Lanagan M T 2010 Langmuir 26 18817 Google Scholar
[87]	Hu P H, Shen Y, Guan Y H, Zhang X H, Lin Y H, Zhang Q M, Nan C W 2014 Adv. Funct. Mater. 24 3172 Google Scholar
[88]	Pan Z B, Liu B H, Zhai J W, Yao L M, Yang K, Shen B 2017 Nano Energy 40 587 Google Scholar
[89]	Tseng J K, Tang S, Zhou Z, Mackey M, Carr J M, Mu R, Flandin L, Schuele D E, Baer E, Zhu L 2014 Polymer 55 8 Google Scholar
[90]	Mackey M, Hiltner A, Baer E, Flandin L, Wolak M A, Shirk J S 2009 J. Phys. D: Appl. Phys. 42 175304 Google Scholar
[91]	Li Q, Liu F H, Yang T N, Gadinski M R, Zhang G Z, Chen L Q, Wang Q 2016 Proc. Natl. Acad. Sci. U.S.A. 113 9995 Google Scholar
[92]	Azizi A, Gadinski M R, Li Q, AlSaud M A, Wang J J, Wang Y, Wang B, Liu F H, Chen L Q, Alem N, Wang Q 2017 Adv. Mater. 29 1701864 Google Scholar
[93]	Zhou Y, Li Q, Dang B, Yang Y, Shao T, Li H, Hu J, Zeng R, He J L, Wang Q 2018 Adv. Mater. 30 1805672 Google Scholar
[94]	Bonardd S, Moreno-Serna V, Kortaberria G, Díaz D D, Leiva A, Saldías C 2019 Polymer 11 317 Google Scholar
[95]	Peng X W, Wu Q, Jiang S H, Hanif M, Chen S L, Hou H Q 2014 J. Appl. Polym. Sci. 131 40828 Google Scholar
[96]	Zhuang Y B, Seong J G, Lee Y M 2019 Prog. Polym. Sci. 92 35 Google Scholar
[97]	Kao K C 2004 Dielectric Phenomena in Solids (San Diego: Academic Press) p573
[98]	Wang Y, Zhou X, Lin M R, Zhang Q M 2009 Appl. Phys. Lett. 94 154 Google Scholar
[99]	Cheng Z X, Lin M R, Wu S, Thakur Y, Zhou Y, Jeong D Y, Shen Q D, Zhang Q M 2015 Appl. Phys. Lett. 106 202902 Google Scholar
[100]	Wu S, Li W P, Lin M R, Burlingame Q, Chen Q, Payzant A, Xiao K, Zhang Q M 2013 Adv. Mater. 25 1734 Google Scholar
[101]	Qiao Y L, Islam M S, Yin X D, Han K, Yan Y, Zhang J Y, Wang Q, Ploehn H J, Tang C B 2015 Polymer 72 428 Google Scholar
[102]	Yuan X P, Matsuyama Y, Chung T C M 2010 Macromolecules 43 4011 Google Scholar
[103]	Misra M, Agarwal M, Sinkovits D W, Kumar S K, Wang C C, Pilania G, Ramprasad R, Weiss R A, Yuan X P, Mike Chung T C 2014 Macromolecules 47 1122 Google Scholar
[104]	Zhang M, Zhang L, Zhu M, Wang Y G, Li N W, Zhang Z J, Chen Q, An L N, Lin Y H, Nan C W 2016 J. Mater. Chem. A 4 4797 Google Scholar
[105]	Chou Y H, Yen H J, Tsai C L, Lee W Y, Liou G S, Chen W C 2013 J. Mater. Chem. C 1 3235 Google Scholar
[106]	Treufeld I, Wang D H, Kurish B A, Tan L S 2014 J. Mater. Chem. A 2 20683 Google Scholar
[107]	Zhang Z B, Wang D H, Litt M H, Tan L S, Zhu L 2018 Angew. Chem. Int. Ed. 130 1547 Google Scholar
[108]	Zhang Z B, Zheng J F, Premasiri K, Kwok M H, Li Q, Li R P, Zhang S B, Litt M H, Gao X P A, Zhu L 2020 Mater. Horiz. 7 592 Google Scholar
[109]	Yang R Q, Wei R B, Li K, Tong L F, Jia K, Liu X B 2016 Sci. Rep. 6 36434 Google Scholar
[110]	Yang J, Yang X L, Zou Y K, Zhan Y Q, Zhao R, Liu X B 2012 J. Appl. Polym. Sci. 126 1129 Google Scholar
[111]	Hanley T L, Burford R P, Fleming R J, Barber K W 2003 IEEE Electr. Insul. Mag. 19 13 Google Scholar
[112]	Zhou Q, Ma J, Dong S, Li X, Cui G 2019 Adv. Mater. 31 1902029 Google Scholar
[113]	Khanchaitit P, Han K, Gadinski M R, Li Q, Wang Q 2013 Nat. Commun. 4 2845 Google Scholar
[114]	Meereboer N L, Terzić I, van der Steeg P, Portale G, Loos K 2019 J. Mater. Chem. A 7 2795 Google Scholar
[115]	Chen X Z, Li Z W, Cheng Z X, Zhang J Z, Shen Q D, Ge H X, Li H T 2011 Macromol. Rapid Commun. 32 94 Google Scholar
[116]	Tan S, Hu X, Ding S, Zhang Z, Li H, Yang L 2013 J. Mater. Chem. A 1 10353 Google Scholar
[117]	Li H, Gadinski M R, Huang Y Q, et al. 2020 Energy Environ. Sci. 13 1279 Google Scholar
[118]	Chen S Y, Meng G D, Kong B, Xiao B, Wang Z D, Jing Z, Gao Y S, Wu G L, Wang H, Cheng Y H 2020 Chem. Eng. J. 387 123662 Google Scholar
[119]	Wang Y X, Huang X Y, Li T, Wang Z W, Li L Q, Gu X J, Jiang P K 2017 J. Mater. Chem. A 5 20737 Google Scholar
[120]	Hung C C, Wu H C, Chiu Y C, Tung S H, Chen W C 2016 J. Polym. Sci. Polym. Chem. 54 3224 Google Scholar

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