搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

辐照导致硼硅酸盐玻璃机械性能变化

王铁山 张多飞 陈亮 律鹏 杜鑫 袁伟 杨迪

引用本文:
Citation:

辐照导致硼硅酸盐玻璃机械性能变化

王铁山, 张多飞, 陈亮, 律鹏, 杜鑫, 袁伟, 杨迪

Irradiation-induced modifications in the mechanical properties of borosilicate glass

Wang Tie-Shan, Zhang Duo-Fei, Chen Liang, Lü Peng, Du Xin, Yuan Wei, Yang Di
PDF
导出引用
  • 为了模拟研究高放废物玻璃固化体在处置过程中因辐照导致的机械性能变化,本文采用5 MeV Xe离子和1.2 MeV电子辐照硼硅酸盐玻璃,利用纳米压痕技术表征了辐照前后样品的硬度和模量,并利用傅里叶变换衰减全反射红外光谱测试,研究了辐照导致玻璃机械性能变化的微观机理.结果表明:当能量沉积达到6.61021 keV/cm3时,Xe离子辐照样品的硬度和模量下降都达到饱和,其中硬度下降约24%,模量下降约7.4%;电子辐照后样品的硬度和模量也有轻微下降,但在实验所用剂量范围内硬度和模量下降未出现饱和现象,当吸收剂量达到最大值(1109 Gy)时,硬度和模量分别下降约4.7%和2.9%.分析表明:Xe离子辐照后样品的恢复阻力增大,韧性提高,整体机械性能提升,而电子辐照后样品的机械性能无明显变化.研究结果证明了离子辐照导致玻璃机械性能变化的主要因素是离子在样品中的核能量沉积.
    Understanding the evolutions of the mechanical properties of borosilicate glasses under irradiation is crucial for evaluating their performances after long-term interaction with the irradiation environment in the disposal of high level nuclear waste.The variations of the mechanical properties of borosilicate glasses,induced by irradiation have been extensively studied.However,the mechanisms of variations in mechanical properties,induced by irradiation have not been clarified yet,especially when considering the effects of electronic and nuclear processes,respectively.To clarify this issue,a commercial borosilicate glass is investigated through an external irradiation of 5 MeV Xe ions and 1.2 MeV electrons in this paper.The nano-indentation test is used to study the changes of the hardness and modulus.The microstructure evolutions of Xe ion irradiated borosilicate glasses are characterized by Fourier transform infrared (FTIR) spectroscopy to discuss the mechanisms in the evolutions of mechanical properties.The nano-indentation results indicate that the hardness is reduced by 24%,and the modulus is lessened by 7.4% after the glass has been irradiated by Xe ions.Both the hardness and modulus variations reach their stable states when the total deposited energy is around 6.61021 keV/cm3.Although hardness and modulus are also observed to decrease by about 4.7% and 2.9%,resepectively, when the total deposited energy reaches approximately 1.41022 keV/cm3 after the glass has experienced the electron irradiation,the results still emphasize that the nuclear energy deposition is the major factor for the evolutions of the hardness and modulus of the borosilicate glass under ion irradiation.The decreases of hardness and modulus after the glass has experienced ion irradiation can be attributed to the deformation of glass network and volume expansion, which are induced by reducing the average ring size and transforming from[BO4] to[BO3] units.By considering the recovery resistance,it is found that the toughness of the borosilicate glass is significantly strengthened,and therefore the mechanical properties of the borosilicate glass are enhanced after the glass has been irradiated by Xe ions.Compared with the results after ion irradiation,the mechanical properties have negligible changes after electron irradiation.The present work is important for understanding both the irradiation effects on the hardness/modulus and the variations in the mechanical properties during the high level waste disposal.
      通信作者: 陈亮, chenl@lzu.edu.cn
    • 基金项目: 国家自然科学基金(批准号:11505084)和中央高校基本科研业务费(批准号:lzujbky-2016-37)资助的课题.
      Corresponding author: Chen Liang, chenl@lzu.edu.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 11505084) and the Fundamental Research Fund for the Central Universities, China (Grant No. lzujbky-2016-37).
    [1]

    Weber W J, Ewing R C, Angell C A, Arnold G W, Cormack A N, Delaye J M, Griscom D L, Hobbs L W, Navrotsky A, Price D L, Stoneham A M, Weinberg M C 1997 J. Mater. Res. 12 1946

    [2]

    Abbas A, Serruys Y, Ghaleb D, Delaye J M, Boizot B, Reynard B, Calas G 2000 Nucl. Instrum. Meth. B 166-167 445

    [3]

    Peuget S, Noel P Y, Loubet J L, Pavan S, Nivet P, Chenet A 2006 Nucl. Instrum. Meth. B 246 379

    [4]

    Peuget S, Cachia J N, Jégou C, Deschanels X, Roudil D, Broudic V, Delaye J M, Bart J M 2006 J. Nucl. Mater. 354 1

    [5]

    Peuget S, Delaye J M, Jégou C 2014 J. Nucl. Mater. 444 76

    [6]

    Deschanels X, Peuget S, Cachia J N, Charpentier T 2007 Prog. Nucl. Energy 49 623

    [7]

    Gedeon O, Lukeš J, Jurek K 2012 Nucl. Instrum. Meth. B 275 7

    [8]

    Chen L, Yuan W, Nan S, Du X, Zhang D F, Lv P, Peng H B, Wang T S 2016 Nucl. Instrum. Meth. B 370 42

    [9]

    Zhang T H, Yang Y M 2002 Adv. Mech. 32 349 (in Chinese)[张泰华, 杨业敏2002力学进展32 349]

    [10]

    Hu X J, Zheng B L, Yang B, Yu J G, He P F, Zhu Y F 2015 Acta Phys. Sin. 64 076201 (in Chinese)[胡兴健, 郑百林, 杨彪, 余金桂, 贺鹏飞, 岳珠峰2015物理学报64 076201]

    [11]

    Battaglin G, Arnold G, Mattei W, Mazzoldi G, Dran P, Dran J C 1999 J. Appl. Phys. 85 8040

    [12]

    Bao Y W, Wang W, Zhou Y C 2004 Acta Mater. 52 5397

    [13]

    Chen L, Wang T S, Zhang G F, Yang K J, Peng H B, Zhang L M 2013 Chin. Phys. B 22 126101

    [14]

    Sidorov T A 1967 J. Appl. Spectrosc. 7 258

    [15]

    Tenney A S, Wong J 1972 J. Chem. Phys. 56 5516

    [16]

    Steven A, Donald M, Schardt C R, Masiello D J, Simmons J H 2000 J. Non-Cryst. Solids 275 72

    [17]

    Cormier L, Meneses D D S, Neuville D R, Echegut P 2006 Phys. Chem. Glasses:Eur. J. Glass Sci. Technol. B 47 430

    [18]

    Yu J N 2007 Materal Radiation Effect (Beijing:Chemical Industry Press) p177(in Chinese)[郁金南2007材料辐照效应(北京:化学工业出版社)第177页]

    [19]

    Nan J, John S 2002 J. Appl. Phys. 92 2310

    [20]

    Yang T F, Gao Y, Huang X J, Zhang Y W, Toulemonde M, Xue J M, Yan S, Wang Y G 2011 J. Non-Cryst. Solids 357 3245

    [21]

    Kieu L H, Kilymis D, Delaye J M, Peuget S 2014 Procedia Mater. Sci. 7 262

    [22]

    Chen L, Wang T S, Yang K J, Peng H B, Zhang G F, Zhang L M, Jiang H, Wang Q 2013 Nucl. Instrum. Meth. B 307 566

    [23]

    Bonfils J D, Peuget S, Panczer G, Ligny D D, Henry S, Noël P Y, Chenet A, Champagnon B 2010 J. Non-Cryst. Solids 356 388

    [24]

    Kilymis D A, Delaye J M 2014 J. Non-Cryst. Solids 401 147

    [25]

    Chen L, Zhang D F, Lv P, Zhang J D, Du X, Yuan W, Nan S, Zhu Z H, Wang T S 2016 J. Non-Cryst. Solids 448 6

    [26]

    Arnold G W 1986 Radiat. Eff. Defects Solids 98 55

    [27]

    Ewing R C, Weber W J, Clinard Jr F W 1995 Prog. Nucl. Energy 29 63

  • [1]

    Weber W J, Ewing R C, Angell C A, Arnold G W, Cormack A N, Delaye J M, Griscom D L, Hobbs L W, Navrotsky A, Price D L, Stoneham A M, Weinberg M C 1997 J. Mater. Res. 12 1946

    [2]

    Abbas A, Serruys Y, Ghaleb D, Delaye J M, Boizot B, Reynard B, Calas G 2000 Nucl. Instrum. Meth. B 166-167 445

    [3]

    Peuget S, Noel P Y, Loubet J L, Pavan S, Nivet P, Chenet A 2006 Nucl. Instrum. Meth. B 246 379

    [4]

    Peuget S, Cachia J N, Jégou C, Deschanels X, Roudil D, Broudic V, Delaye J M, Bart J M 2006 J. Nucl. Mater. 354 1

    [5]

    Peuget S, Delaye J M, Jégou C 2014 J. Nucl. Mater. 444 76

    [6]

    Deschanels X, Peuget S, Cachia J N, Charpentier T 2007 Prog. Nucl. Energy 49 623

    [7]

    Gedeon O, Lukeš J, Jurek K 2012 Nucl. Instrum. Meth. B 275 7

    [8]

    Chen L, Yuan W, Nan S, Du X, Zhang D F, Lv P, Peng H B, Wang T S 2016 Nucl. Instrum. Meth. B 370 42

    [9]

    Zhang T H, Yang Y M 2002 Adv. Mech. 32 349 (in Chinese)[张泰华, 杨业敏2002力学进展32 349]

    [10]

    Hu X J, Zheng B L, Yang B, Yu J G, He P F, Zhu Y F 2015 Acta Phys. Sin. 64 076201 (in Chinese)[胡兴健, 郑百林, 杨彪, 余金桂, 贺鹏飞, 岳珠峰2015物理学报64 076201]

    [11]

    Battaglin G, Arnold G, Mattei W, Mazzoldi G, Dran P, Dran J C 1999 J. Appl. Phys. 85 8040

    [12]

    Bao Y W, Wang W, Zhou Y C 2004 Acta Mater. 52 5397

    [13]

    Chen L, Wang T S, Zhang G F, Yang K J, Peng H B, Zhang L M 2013 Chin. Phys. B 22 126101

    [14]

    Sidorov T A 1967 J. Appl. Spectrosc. 7 258

    [15]

    Tenney A S, Wong J 1972 J. Chem. Phys. 56 5516

    [16]

    Steven A, Donald M, Schardt C R, Masiello D J, Simmons J H 2000 J. Non-Cryst. Solids 275 72

    [17]

    Cormier L, Meneses D D S, Neuville D R, Echegut P 2006 Phys. Chem. Glasses:Eur. J. Glass Sci. Technol. B 47 430

    [18]

    Yu J N 2007 Materal Radiation Effect (Beijing:Chemical Industry Press) p177(in Chinese)[郁金南2007材料辐照效应(北京:化学工业出版社)第177页]

    [19]

    Nan J, John S 2002 J. Appl. Phys. 92 2310

    [20]

    Yang T F, Gao Y, Huang X J, Zhang Y W, Toulemonde M, Xue J M, Yan S, Wang Y G 2011 J. Non-Cryst. Solids 357 3245

    [21]

    Kieu L H, Kilymis D, Delaye J M, Peuget S 2014 Procedia Mater. Sci. 7 262

    [22]

    Chen L, Wang T S, Yang K J, Peng H B, Zhang G F, Zhang L M, Jiang H, Wang Q 2013 Nucl. Instrum. Meth. B 307 566

    [23]

    Bonfils J D, Peuget S, Panczer G, Ligny D D, Henry S, Noël P Y, Chenet A, Champagnon B 2010 J. Non-Cryst. Solids 356 388

    [24]

    Kilymis D A, Delaye J M 2014 J. Non-Cryst. Solids 401 147

    [25]

    Chen L, Zhang D F, Lv P, Zhang J D, Du X, Yuan W, Nan S, Zhu Z H, Wang T S 2016 J. Non-Cryst. Solids 448 6

    [26]

    Arnold G W 1986 Radiat. Eff. Defects Solids 98 55

    [27]

    Ewing R C, Weber W J, Clinard Jr F W 1995 Prog. Nucl. Energy 29 63

  • [1] 赵珀, 王建强, 陈梅清, 杨金学, 苏钲雄, 卢晨阳, 刘华军, 洪智勇, 高瑞. EuBa2Cu3O7-δ超导带材中掺杂相对He+离子辐照缺陷演化及超导电性的影响. 物理学报, 2024, 0(0): . doi: 10.7498/aps.73.20240124
    [2] 曹嵩, 殷雯, 周斌, 胡志良, 沈飞, 易天成, 王松林, 梁天骄. 中国散裂中子源二期靶站关键部件辐照损伤模拟计算. 物理学报, 2024, 0(0): 0-0. doi: 10.7498/aps.73.20240088
    [3] 魏雯静, 高旭东, 吕亮亮, 许楠楠, 李公平. 中子对碲锌镉辐照损伤模拟研究. 物理学报, 2022, 71(22): 226102. doi: 10.7498/aps.71.20221195
    [4] 梁晋洁, 高宁, 李玉红. 体心立方Fe中${ \langle 100 \rangle}$位错环对微裂纹扩展影响的分子动力学研究. 物理学报, 2020, 69(11): 116102. doi: 10.7498/aps.69.20200317
    [5] 何仁, 李英叶, 陈敬欣, 赵学玲, 汤欢, 张丽娜, 沈艳娇, 李锋, 杨琳, 韦德远. 三点、四点法机械性能测试建模及其在太阳电池中的应用. 物理学报, 2019, 68(20): 208801. doi: 10.7498/aps.68.20190597
    [6] 高云亮, 朱芫江, 李进平. Al辐照损伤初期的第一性原理研究. 物理学报, 2017, 66(5): 057104. doi: 10.7498/aps.66.057104
    [7] 马爽, 乌仁图雅, 特古斯, 武晓霞, 管鹏飞, 那日苏. FeMnP1-xTx(T=Si,Ga,Ge)系列化合物机械性能的第一性原理研究. 物理学报, 2017, 66(12): 126301. doi: 10.7498/aps.66.126301
    [8] 常晓阳, 尧舜, 张奇灵, 张杨, 吴波, 占荣, 杨翠柏, 王智勇. 基于分布式布拉格反射器结构的空间三结砷化镓太阳能电池抗辐照研究. 物理学报, 2016, 65(10): 108801. doi: 10.7498/aps.65.108801
    [9] 姚宝殿, 胡桂青, 于治水, 张慧芬, 施立群, 沈皓, 王月霞. H,He对Ti3SiC2材料力学性能影响的第一性原理研究. 物理学报, 2016, 65(2): 026202. doi: 10.7498/aps.65.026202
    [10] 齐佳红, 胡建民, 盛延辉, 吴宜勇, 徐建文, 王月媛, 杨晓明, 张子锐, 周扬. 电子辐照下GaAs/Ge太阳电池载流子输运机理研究. 物理学报, 2015, 64(10): 108802. doi: 10.7498/aps.64.108802
    [11] 徐嶺茂, 高超, 董鹏, 赵建江, 马向阳, 杨德仁. 单晶硅片中的位错在快速热处理过程中的滑移. 物理学报, 2013, 62(16): 168101. doi: 10.7498/aps.62.168101
    [12] 姜少宁, 万发荣, 龙毅, 刘传歆, 詹倩, 大貫惣明. 氦、氘对纯铁辐照缺陷的影响. 物理学报, 2013, 62(16): 166801. doi: 10.7498/aps.62.166801
    [13] 崔振国, 勾成俊, 侯氢, 毛莉, 周晓松. 低能中子在锆中产生的辐照损伤的计算机模拟研究. 物理学报, 2013, 62(15): 156105. doi: 10.7498/aps.62.156105
    [14] 朱勇, 李宝华, 谢国锋. 质子对BaTiO3薄膜辐照损伤的计算机模拟. 物理学报, 2012, 61(4): 046103. doi: 10.7498/aps.61.046103
    [15] 汪俊, 张宝玲, 周宇璐, 侯氢. 金属钨中氦行为的分子动力学模拟. 物理学报, 2011, 60(10): 106601. doi: 10.7498/aps.60.106601
    [16] 吴宜勇, 岳龙, 胡建民, 蓝慕杰, 肖景东, 杨德庄, 何世禹, 张忠卫, 王训春, 钱勇, 陈鸣波. 位移损伤剂量法评估空间GaAs/Ge太阳电池辐照损伤过程. 物理学报, 2011, 60(9): 098110. doi: 10.7498/aps.60.098110
    [17] 敖冰云, 汪小琳, 陈丕恒, 史鹏, 胡望宇, 杨剑瑜. 嵌入原子法计算金属钚中点缺陷的能量. 物理学报, 2010, 59(7): 4818-4825. doi: 10.7498/aps.59.4818
    [18] 贺新福, 杨文, 樊胜. 论FeCr合金辐照损伤的多尺度模拟. 物理学报, 2009, 58(12): 8657-8669. doi: 10.7498/aps.58.8657
    [19] 王海燕, 祝文军, 宋振飞, 刘绍军, 陈向荣, 贺红亮. 氦泡对铝的弹性性质的影响. 物理学报, 2008, 57(6): 3703-3708. doi: 10.7498/aps.57.3703
    [20] 范鲜红, 李 敏, 尼启良, 刘世界, 王晓光, 陈 波. Mo/Si多层膜在质子辐照下反射率的变化. 物理学报, 2008, 57(10): 6494-6499. doi: 10.7498/aps.57.6494
计量
  • 文章访问数:  5064
  • PDF下载量:  232
  • 被引次数: 0
出版历程
  • 收稿日期:  2016-06-19
  • 修回日期:  2016-10-14
  • 刊出日期:  2017-01-20

/

返回文章
返回