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小分子掺杂高分子半导体薄膜中异质结结构光谱学特性研究

刘宁 张新平 窦菲

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小分子掺杂高分子半导体薄膜中异质结结构光谱学特性研究

刘宁, 张新平, 窦菲

Heterojunction structure forming in the polymer film doped with small-molecule organic semiconductors

Liu Ning, Zhang Xin-Ping, Dou Fei
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  • 利用稳态吸收和荧光光谱学、瞬态荧光光谱学(时间相关单光子计数技术)系统研究了EPPTC掺杂的F8BT薄膜异质结结构中激发复合体的形成机理和荧光发射特性,并表征了其特征光谱和荧光发射寿命. 其特征主要体现在显著延长的荧光发射寿命和红移的荧光发射光谱.这对于理解有机半导体材料异质结结构形成的机理和光物理学特性研究提供了多方面的实验依据.同时,由于这两种材料混合后的吸收光谱较宽范围地覆盖了可见光谱区,这样的有机半导体掺杂工艺对于有机光伏器件和太阳能电池器件的应用研究具有重要意义.
    Blends and doping of organic semiconductors are generally employed to improve effectively the charge transfer and dissociation performance. The absorption spectrum may be optimized making use of the different energy states of the components in the blends, which may favor the development of the photovoltaic or solar cell devices. Excellent type-II heterojunction structures can be produced by mixing the small-molecule perylene (EPPTC) and a copolymer of polyfluorene (F8BT). Actually, F8BT and EPPTC exhibit absorptions in the blue region and in the green region, respectively. Thus, the blend will have a much broadened absorption spectrum. In the experiment, the blend solution of these two materials in chloroform is spin-coated onto a piece of glass substrate, so that EPPTC is doped into the polymer of F8BT and the heterojunction structure forms in the final solid film. Then, steady-state absorption and fluorescence spectroscopy, as well as the transient photoluminesence spectroscopy (time-correlated single-photon counting), is used to investigate the formation and the photoluminescence properties of exciplex in the heterojunction film of F8BT doped with EPPTC. The photoluminscence (PL) spectrum and the life-time are measured to characterize the exciplex in the blend film, where the longer life-time of the red-shifted PL spectrum confirms the formation of the exciplex. This provides various experimental data for understanding the formation and the photophysical properties of the heterojunction structures in organic semiconductor blends. Futhermore, the absorption of the blend film covers a large range of the visible spectrum. Therefore, this kind of doping of organic semiconductor is important for the development of photovoltaic and solar cell devices.
    • 基金项目: 国家自然科学基金(批准号:111074018), 新世纪优秀人才支持计划, 高等学校博士学科点专项(批准号:20091103110012)和教育部留学回国人员科研启动基金资助的课题.
    • Funds: Project supported by the Natural Natural Science Foundation of China (Grant No. 111074018), the Program for New Century Excellent Talents in University, the Specialized Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20091103110012), and the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars, Ministry of Education of China.
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  • [1]

    Friend R H, Gymer R W, Holmes A B, Burroughes J H, Marks R N, Taliani C, Bradaley D D C, Dos Santos D A, Brédas J L, Lögdlund M, Salaneck W R 1999 Nature 397 121

    [2]

    Crone B K, Davids P S, Campbell I H, Smith D L 2000 J. Appl. Phys. 87 1974

    [3]

    Chappell J, Lidzey D G, Jukes P C, Higgins A M, Thompson R L, O0Connor S, Grizzi I, Fletcher R, O’Brien J, Geoghegan M, Jones R A L 2003 Nat. Mater. 2 616

    [4]

    Westenhoff S, Howard I A, Hodgkiss J M, Kirov K R, Bronstein H A, Williams C K, Greenham N C, Friend R H 2008 J. Am. Chem. Soc. 130 13653

    [5]

    Wilkinson F, Helman W P, Ross A B 1995 J. Phys. Chem. Refe. Data 24 663

    [6]

    Morteani A C, Sreearunothai P, Laura, Herz M, Friend R H, Silv C 2004 Phys. Rev. Lett. 92 247402.

    [7]

    Morteani A C, Friend R H, Silva C 2004 Chem. Phys. Lett. 391 81

    [8]

    Huang Y S, Westenhoff S, Avilov I, Sreearunothai P, Hodgkiss J M, Deleener C, Friend R H, Beljonne D D 2008 Nat. Mater. 7 483

    [9]

    Morteani A C, Dhoot A S, Kim J-S, Silva C, Greenham N C, Murphy C, Moons E, Cina S, Burroughes J H, Friend R H 2003 Adv. Mater. 15 1708

    [10]

    Peng C Z, Zhang X P, Liu H M, Feng S F 2010 Acta Phys. Sin. 59 5791 (in Chinese) [彭春增,张新平,刘红梅,冯胜飞 2010 物理学报 59 5791]

    [11]

    Shepherd W E B, Platt A F, Kendrich M J 2011 J. Phys. Chen. Lett. 2 362

    [12]

    Zhang W, Yu J S, Yuan K 2010 Proceedings of SPIE-The International Society for Optical Engineering 7658

    [13]

    Lai S L, ChanMY, Tong Q X 2010 J. Nonlinear Opt. Phys. Mater. 19 603

    [14]

    Park YW, Kim Y M, Choi J H 2011 J. Nanoscience Nanotechnology 11 1381

    [15]

    Zhang X P, Sun B Q 2007 J. Phys. Chem. B 111 10881

    [16]

    Kang J, Kaczmarek O, Liebscher J, Dähne1 L 2010 Int. J. Polym. Sci. 2010 264781

    [17]

    Chaudhuri D, Li D, Che Y, Shafran E, Gerton J M, Zang L, Lupton J M 2011 Nano Lett. 11 488

    [18]

    Provencher F, Laprade J F, C?oté M, Silva C 2009 Phys. Stat. Sol. (c) 6 93

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出版历程
  • 收稿日期:  2011-02-08
  • 修回日期:  2011-05-09
  • 刊出日期:  2012-01-05

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