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中国物理学会期刊

非磁性发光材料的磁场效应: 从有机半导体到卤化物钙钛矿

CSTR: 32037.14.aps.71.20211872

Magnetic field effects in non-magnetic luminescent materials: from organic semiconductors to halide perovskites

CSTR: 32037.14.aps.71.20211872
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  • 磁场效应(magnetic field effects, MFEs)指的是材料或器件的光电物理特性(包括光致发光、电致发光、注入电流、光电流等)在外加磁场下发生的变化. 本文所述的是非磁性发光材料的MFEs, 其首先在有机半导体光电器件中被发现. 近十几年来, MFEs作为一种新兴的物理现象引起了广泛的研究; 同时它也成为一种独特的实验手段, 用以探讨有机半导体中电荷的输运、复合以及自旋极化等过程. 近期的研究发现, MFEs不仅存在于有机半导体中, 而且在拥有强自旋-轨道耦合作用的金属卤化物钙钛矿材料中被观测到, 这既拓展了MFEs的研究方向, 也为通过研究MFEs来探索金属卤化物钙钛矿器件的物理机制, 进而为提升其器件性能提供了契机. 本文重点关注有机半导体和卤化物钙钛矿在磁场下的电致发光和光致发光变化, 即发光的磁场效应. 回顾了到目前为止主流的理论模型和代表性实验现象, 对比分析了磁场下有机半导体和卤化物钙钛矿的发光物理行为. 以期为有机及钙钛矿磁场效应领域的研究提供一些思路, 同时为有机及钙钛矿发光领域的发展贡献些许想法.

     

    Magnetic field effects (MFEs) are used to describe the changes of the photophysical properties (including photoluminescence, electroluminescence, injectedcurrent, photocurrent, etc.) when materials and devices are subjected to the external magnetic field. The MFEs in non-magnetic luminescent materials and devices were first observed in organic semiconductor. In the past two decades, the effects have been studied extensively as an emerging physical phenomenon, and also used as a unique experimental method to explore the processes such as charge transport, carrier recombination, and spin polarization in organic semiconductors. Recent studies have found that the MFEs can also be observed in metal halide perovskites with strong spin-orbital coupling. Besides, for expanding the research domain of MFEs, these findings can also be utilized to study the physical mechanism in metal halide perovskites, and then provide an insight into the improving of the performance of perovskite devices. In this review, we focus on the magnetic field effects on the electroluminescence and photoluminescence changes of organic semiconductors and halide perovskites. We review the mainstream of theoretical models and representative experimental phenomena which have been found to date, and comparatively analyze the luminescence behaviors of organic semiconductors and halide perovskites under magnetic fields. It is expected that this review can provide some ideas for the research on the MFEs of organic semiconductors and halideperovskites, and contribute to the research of luminescence in organic materials and halideperovskites.

     

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