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杂化非本征铁电性是指在具有钙钛矿结构单元的金属氧化物中由氧八面体面内旋转和面外倾侧耦合诱导出的二阶铁电序,其有望在室温强磁电耦合多铁性材料中获得重要应用,并将极大地拓展铁电体物理学的内涵和外延.本文在阐述杂化非本征铁电性物理起源及其内禀电控磁性的基础上,总结了有关Ruddlesden-Popper结构杂化非本征铁电体及多铁性的主要研究进展与面临的挑战,并展望了发展方向.
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关键词:
- 多铁性 /
- 杂化非本征铁电性 /
- 氧八面体倾转 /
- Ruddlesden-Popper结构
Hybrid improper ferroelectricity (HIF) is a secondary ferroelectric ordering induced by the coupling between oxygen octahedral in-plane rotation and out-of-plane tilt in a metal-oxide containing the perovskite structure units. Investigation of HIF will greatly extend the connotation and denotation of ferroelectric physics and material science, and it is expected to develop the room temperature single phase multiferroic material with large polarization and strong magnetoelectric coupling, owing to its intrinsic characteristic of the electric-field control of magnetism through HIF in magnet. In the present paper, the recent primary progress of HIFs and the multiferroics with Ruddlesden-Popper structures is reviewed, and the perspective of the future development is also presented.-
Keywords:
- multiferroic /
- hybrid improper ferroelectricity /
- oxygen octahedron tilt /
- Ruddlesden-Popper structure
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[34] Kamba S, Adamo C, Goian V, Zhang H, Beamland R, Gupta A S, Gopalan V, Drahokoupil J, Vanek P, Svatuska M, Seiner H, Palatnius L, Klementova M, Benedek N A, Reaney I, Maca K, Fennie C J, Schlom D G 2014 Abstract Book of Electroceramics XIV Bucharest, Romania, June 16-20, 2014 p269
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[1] Scott J F 2007 Science 315 954
[2] Yang S Y, Seidel J, Byrnes S J, Shafer P, Yang C H, Rossell M D, Yu P, Chu Y H, Scott J F, Ager Ⅲ J W, Martin L W, Ramesh R 2010 Nat. Nanotech. 5 143
[3] Ma J, Hu J, Li Z, Nan C W 2011 Adv. Mater. 9 1062
[4] Dong S, Liu J M, Cheong S W, Ren Z 2015 Adv. Phys. 64 519
[5] Liu J M, Nan C W 2014 Physics 43 88 (in Chinese) [刘俊明, 南策文 2014 物理 43 88]
[6] Hill N A 2000 J. Phys. Chem. B 104 6694
[7] Wang J, Neaton J B, Zheng H, Nagarajan V, Ogale S B, Liu B, Viehland D, Vaithyanathan V, Schlom D G, Waghmare U V, Spaldin N A, Rabe K M, Wuttig M, Ramesh R 2003 Science 299 1719
[8] Kimura T, Goto T, Shintani H, Ishizaka K, Arima T, Tokura Y 2003 Nature 426 55
[9] Shi X X, Liu X Q, Chen X M 2017 Adv. Funct. Mater. 27 1604037
[10] Liu J, Sun T L, Liu X Q, Tian H, Gao T T, Chen X M 2018 Adv. Funct. Mater. 28 1706062
[11] Liu J, Liu X Q, Chen X M 2017 J. Am. Ceram. Soc. 100 4045
[12] Shi X X, Liu X Q, Chen X M 2016 J. Appl. Phys. 119 064104
[13] Liu J, Liu X Q, Chen X M 2016 J. Appl. Phys. 119 204102
[14] Shi X X, Qin Y, Chen X M 2014 Appl. Phys. Lett. 105 192902
[15] Liu J, Liu X Q, Chen X M 2015 J. Appl. Phys. 117 174101
[16] Young Y, Stroppa A, Picozzi S, Rodinelli J M 2015 J. Phys.: Condens. Matter. 27 283202
[17] Benedek N A, Fennie C J 2011 Phys. Rev. Lett. 106 107204
[18] Mulder A T, Benedek N A, Rondinelli J M, Fennie C J 2013 Adv. Funct. Mater. 23 4810
[19] Zhao H J, Iniguez J, Ren W, Chen X M, Bellaiche L 2014 Phys. Rev. B 89 174101
[20] Zhao H J, Ren W, Yang Y R, Iniguez J, Chen X M, Bellaiche L 2014 Nat. Commun. 5 4021
[21] Fukushima T, Stroppa A, Picozzi S, Perez-Mato J M 2011 Phys. Chem. Chem. Phys. 13 12186
[22] Schaak R E, Mallouk T E 2002 Chem. Mater. 14 1455
[23] Chen C, Ning H, Lepadatu S, Cain M, Yan H, Reece M J 2015 J. Mater. Chem. C 3 19
[24] Oh Y S, Luo X, Huang F T, Wang Y, Cheong S W 2015 Nat. Mater. 14 407
[25] Liu X Q, Wu J W, Shi X X, Zhao H J, Zhou H Y, Qiu R H, Zhang W Q, Chen X M 2015 Appl. Phys. Lett. 106 202903
[26] Li X, Yang L, Li C F, Liu M F, Fan Z, Xie Y L, Lu C L, Lin L, Yan Z B, Zhang Z, Dai J Y, Liu J M, Cheong S W 2017 Appl. Phys. Lett. 110 042901
[27] Gao B, Huang F T, Wang Y, Kim J W, Wang L, Lim S J, Cheong S W 2017 Appl. Phys. Lett. 110 222906
[28] Huang F T, Gao B, Kim J W, Luo X, Wang Y, Chu M W, Chang C K, Sheu H S, Cheong S W 2016 NPJ Quantum Mater. 1 16017
[29] Li G J, Liu X Q, Zhu H Y, Chen X M 2018 J. Appl. Phys. 123 014101
[30] Wang Y, Huang F T, Luo X, Gao B, Cheong S W 2017 Adv. Mater. 29 1601288
[31] Pitcher M J, Mandal P, Dyer M S, Alaria J, Borisov P, Niu H, Claridge J B, Rosseinsky M J 2015 Science 347 420
[32] Xu B, Wang D, Zhao H J, Iniguez J, Chen X M, Bellaiche L 2015 Adv. Funct. Mater. 25 3626
[33] Bousquet E, Dawber M, Stucki N, Lichtensteiger C, Hermet P, Gariglio S, Triscone J, Ghosez P 2008 Nature 452 732
[34] Kamba S, Adamo C, Goian V, Zhang H, Beamland R, Gupta A S, Gopalan V, Drahokoupil J, Vanek P, Svatuska M, Seiner H, Palatnius L, Klementova M, Benedek N A, Reaney I, Maca K, Fennie C J, Schlom D G 2014 Abstract Book of Electroceramics XIV Bucharest, Romania, June 16-20, 2014 p269
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