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伸缩-剪切模式自偏置铌酸锂基复合材料的磁电性能和高频谐振响应

辛成舟 马健男 马静 南策文

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伸缩-剪切模式自偏置铌酸锂基复合材料的磁电性能和高频谐振响应

辛成舟, 马健男, 马静, 南策文

Magnetoelectric effect in stretch-shear mode self-biased LiNbO3 based composite with high-frequency resonant response

Xin Cheng-Zhou, Ma Jian-Nan, Ma Jing, Nan Ce-Wen
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  • 选用多种切型铌酸锂(LiNbO3)单晶,研究了铁基非晶合金(Metglas)/LiNbO3叠层复合材料基于伸缩-剪切模式的磁电耦合性能,揭示了铌酸锂单晶压电系数与复合材料剪切磁电耦合系数的对应关系,在使用铌酸锂xzt/30切型时得到了最优化剪切磁电系数.通过SrFe12O19薄磁带提供偏置磁场,Metglas/LiNbO3磁电复合材料可在没有外加直流磁场时实现剪切磁电响应,并在0.991 MHz和3.51 MHz频率时分别测出了谐振磁电系数,有望将铌酸锂基剪切磁电复合材料用于高频磁场探测.
    Magnetoelectric (ME) composites have received attention abidingly due to the promising potential applications in magnetic field sensor and energy harvester. In recent years, shear mode ME composite was frequently discussed with promising applications in high-frequency magnetic field with large signal-to-noise ratio. Single-crystal LiNbO3, as a lead-free piezoelectric phase with high mechanical quality factor and small dielectric constant, is suitable for achieving a large shear ME effect with large shear piezoelectric coefficient d15 or d24, and different piezoelectric coefficients can be obtained by crystal-cut transformation. The transformation rule of shear ME coefficient with transformation of LiNbO3 crystal orientation and the MHz high-frequency magnetic detection is still lacking. Furthermore, self-biased ME composite can be obtained with SrFe12O19 ribbon, which is useful for the integration and miniaturization of ME sensor. In the present work, we use a series of X-cut LiNbO3 to obtain different d15 or d16 in a stretch-shear ME composite. Piezoelectric coefficient d15 and ME coefficient E15 of Metglas/LiNbO3 composite are obtained in experiment, respectively. The results show that LiNbO3 xzt/30 has the largest d15 and E15, and the transformation rule of E15 is consistent with the coordinate transformation of d15. The structure of stretch-shear ME composite is optimized to improve the ME coefficient. Then the stretch-shear mode self-biased SrFe12O19/Metglas/LiNbO3 composite is fabricated, and shear ME response is observed under zero external direct current magnetic bias. Moreover, E15 at electromechanical resonance frequency is gained at shear-mode high frequency (0.991 MHz and 3.51 MHz). The largest ME coefficient E15 is acquired in the stretch-shear 5-foil Metglas/LiNbO3 (xzt/30) composite of 134.16 mV/(cmOe) at 1 kHz and 9.17 V/(cm Oe) at 3.51 MHz. This work is beneficial to the confirming of the corresponding rules of shear ME coefficient and LiNbO3 piezoelectric coefficient, showing that the composite possesses the potential applications in integration, miniaturization and high-frequency resonant sensor.
      通信作者: 马静, ma-jing@mail.tsinghua.edu.cn
    • 基金项目: 国家自然科学基金(批准号:51402164)资助的课题.
      Corresponding author: Ma Jing, ma-jing@mail.tsinghua.edu.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 51402164).
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    Ma J, Shi Z, Nan C W 2007 Adv. Mater. 19 2571

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    [6]

    Zeng L Y, Zhou M H, Bi K, Lei M 2016 J. Appl. Phys. 119 034102

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    Bichurin M I, Petrov R V, Petrov V M 2013 Appl. Phys. Lett. 103 092902

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    Zhang J T, Li P, Wen Y M, He W, Yang A C, Lu C J 2014 Sens. Actuator A: Phys. 214 149

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    Lu M C, Mei L, Jeong D Y, Xiang J, Xie H Q, Zhang Q M 2015 Appl. Phys. Lett. 106 112905

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    Weis R S, Gaylord T K 1985 Appl. Phys. A 37 191

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    Wang Y, Jiang Y J 2003 Opt. Mater. 23 403

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    Kuo H Y, Slinger A, Bhattacharya K 2010 Smart Mater. Struct. 19 125010

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    Timopheev A A, Vidal J V, Kholkin A L, Sobolev N A 2013 J. Appl. Phys. 114 044102

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    Vidal J V, Timopheev A A, Kholkin A L, Sobolev N A 2015 Vacuum 122 286

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    Xin C Z, Ma J N, Ma J, Nan C W 2017 Sci. Bull. 62 388

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    Xin C Z, Ma J N, Ma J, Nan C W 2017 Acta Phys. Sin. 66 067502 (in Chinese) [辛成舟, 马健男, 马静, 南策文 2017 物理学报 66 067502]

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    Ma J N, Xin C Z, Ma J, Lin Y H, Nan C W 2016 J. Phys. D: Appl. Phys. 49 405002

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    Ma J N, Xin C Z, Ma J, Zhang Q M, Nan C W 2016 Sci. Bull. 61 378

  • [1]

    Nan C W, Bichurin M I, Dong S X, Viehland D, Srinivasan G 2008 J. Appl. Phys. 103 031101

    [2]

    Ma J, Hu J M, Li Z, Nan C W 2011 Adv. Mater. 23 1062

    [3]

    Chu Z Q, Shi H D, Shi W L, Liu G X, Wu J G, Yang J K, Dong S X 2017 Adv. Mater. 29 1606022

    [4]

    Ma J, Shi Z, Nan C W 2007 Adv. Mater. 19 2571

    [5]

    Shi Z, Ma J, Lin Y H, Nan C W 2007 J. Appl. Phys. 101 043902

    [6]

    Zeng L Y, Zhou M H, Bi K, Lei M 2016 J. Appl. Phys. 119 034102

    [7]

    Bichurin M I, Petrov R V, Petrov V M 2013 Appl. Phys. Lett. 103 092902

    [8]

    Wang Y J, Hasanyan D, Li J F, Viehland D, Luo H S 2012 Appl. Phys. Lett. 100 202903

    [9]

    Zhang J T, Li P, Wen Y M, He W, Yang A C, Lu C J 2014 Sens. Actuator A: Phys. 214 149

    [10]

    Liu G X, Zhang C L, Dong S X 2014 J. Appl. Phys. 116 074104

    [11]

    Lu M C, Mei L, Jeong D Y, Xiang J, Xie H Q, Zhang Q M 2015 Appl. Phys. Lett. 106 112905

    [12]

    Fang Z, Mokhariwale N, Li F, Datta S, Zhang Q M 2011 IEEE Sens. J. 11 2260

    [13]

    Weis R S, Gaylord T K 1985 Appl. Phys. A 37 191

    [14]

    Wang Y, Jiang Y J 2003 Opt. Mater. 23 403

    [15]

    Kuo H Y, Slinger A, Bhattacharya K 2010 Smart Mater. Struct. 19 125010

    [16]

    Timopheev A A, Vidal J V, Kholkin A L, Sobolev N A 2013 J. Appl. Phys. 114 044102

    [17]

    Vidal J V, Timopheev A A, Kholkin A L, Sobolev N A 2015 Vacuum 122 286

    [18]

    Xin C Z, Ma J N, Ma J, Nan C W 2017 Sci. Bull. 62 388

    [19]

    Xin C Z, Ma J N, Ma J, Nan C W 2017 Acta Phys. Sin. 66 067502 (in Chinese) [辛成舟, 马健男, 马静, 南策文 2017 物理学报 66 067502]

    [20]

    Ma J N, Xin C Z, Ma J, Lin Y H, Nan C W 2016 J. Phys. D: Appl. Phys. 49 405002

    [21]

    Ma J N, Xin C Z, Ma J, Zhang Q M, Nan C W 2016 Sci. Bull. 61 378

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出版历程
  • 收稿日期:  2018-04-25
  • 修回日期:  2018-05-18
  • 刊出日期:  2018-08-05

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