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高压下富氢高温超导体的研究进展

孙莹 刘寒雨 马琰铭

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高压下富氢高温超导体的研究进展

孙莹, 刘寒雨, 马琰铭

Progress on hydrogen-rich superconductors under high pressure

Sun Ying, Liu Han-Yu, Ma Yan-Ming
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  • 近年来, 高压强极端条件下的富氢化合物成为高温超导体研究的热点目标材料体系. 该领域目前取得了两个标志性重要进展, 先后发现了共价型H3S富氢超导体(Tc = 200 K)和以LaH10(Tc = 260 K, –13 ℃), YH6, YH9等为代表的一类氢笼合物结构的离子型富氢超导体, 先后刷新了超导温度的新纪录. 这些研究工作燃发了人们在高压下富氢化合物中发现室温超导体的希望. 本文重点介绍高压下富氢高温超导体的相关研究进展, 讨论富氢化合物产生高温超导电性的物理机理, 展望未来在富氢化合物中发现室温超导体的可能性并提出多元富氢化合物候选体系.
    In recent years, hydrogen-rich compounds under extremely high pressure have become the hot target materials for high-temperature superconductors. At present, two landmark progresses have been made in this field. Covalent H3S hydrogen-rich superconductors (Tc = 200 K) and ionic hydrogen-rich superconductors with hydrogen-cage structure, such as LaH10 (Tc = 260 K, –13 ℃), YH6 and YH9, have been successively synthesized, setting a new record of superconducting temperature. These studies have given rise to the hope of discovering room-temperature superconductors in hydrogen-rich compounds under high pressure. This paper focuses on the progress of hydrogen-rich superconductors with high critical temperature under high pressure, discusses the physical mechanism of high-temperature superconductivity in hydrogen-rich compounds, provide an outlook on the possibility of discovering room-temperature superconductors in hydrogen-rich compounds in the future, and offer the candidate system for high superconductivity in multiple hydrogen-rich compounds.
      通信作者: 刘寒雨, lhy@calypso.cn ; 马琰铭, mym@jlu.edu.cn
    • 基金项目: 国家自然科学基金重大项目(批准号: 52090024)、中国科学院战略性先导科技专项(批准号: XDB33000000)、国家自然科学基金(批准号: 12074138)和中国博士后科学基金(批准号: 2020M681032)资助的课题
      Corresponding author: Liu Han-Yu, lhy@calypso.cn ; Ma Yan-Ming, mym@jlu.edu.cn
    • Funds: Project supported by the Major Program of the National Natural Science Foundation of China (Grant No. 52090024), the Strategic Priority Research Program of Chinese Academy of Sciences (Grant No. XDB33000000), the National Natural Science Foundation of China (Grant No. 12074138), and the China Postdoctoral Science Foundation (Grant No. 2020M681032)
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  • 图 1  超导体年表. 方形、圆形和菱形色块分别表示BCS超导体、铜氧化物超导体和铁基超导体. 黑色和蓝色标签分别标注常压超导材料和高压超导材料及合成压强

    Fig. 1.  Timeline of superconductors. The square, circle, and rhombus color blocks respectively represent BCS superconductors, cuprate superconductors, and iron-based superconductors. Black and blue labels represent superconducting materials at atmospheric pressure and high pressure as well as the pressure value required to synthesize these superconductors.

  • [1]

    赵忠贤, 陈立泉, 崔长庚, 黄玉珍, 刘锦湘, 陈赓华, 李山林, 郭树权, 何业冶 1987 科学通报 32 177Google Scholar

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    [2]

    赵忠贤, 陈立泉, 杨乾声, 黄玉珍, 陈赓华, 唐汝明, 刘贵荣, 崔长庚, 陈烈, 王连忠 1987 科学通报 32 412Google Scholar

    Zhao Z X, Chen L Q, Yang Q S, Huang Y Z, Chen G H, Tang R M, Liu G R, Cui C G, Chen L, Wang L Z 1987 Chin. Sci. Bull. 32 412Google Scholar

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    Wang Q Y, Li Z, Zhang W H, Zhang Z C, Zhang J S, Li W, Ding H, Ou Y B, Deng P, Chang K, Wen J, Song C L, He K, Jia J F, Ji S H, Wang Y Y, Wang L L, Chen X, Ma X C, Xue Q K 2012 Chin. Phys. Lett. 29 037402Google Scholar

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    Pickard C J, Needs R J 2007 Nat. Phys. 3 473Google Scholar

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    Zhang L J, Niu Y L, Li Q, Cui T, Wang Y, Ma Y M, He Z, Zou G T 2007 Solid State Commun. 141 610Google Scholar

    [31]

    Cudazzo P, Profeta G, Sanna A, Floris A, Continenza A, Massidda S, Gross E K 2008 Phys. Rev. Lett. 100 257001Google Scholar

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    Liu H, Zhu L, Cui W, Ma Y M 2012 J. Chem. Phys. 137 074501Google Scholar

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    McMahon J M, Ceperley D M 2011 Phys. Rev. B 84 144515Google Scholar

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    Dias R P, Silvera I F 2017 Science 355 715Google Scholar

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    Eremets M I, Drozdov A P, Kong P P, Wang H 2019 Nat. Phys. 15 1246Google Scholar

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    Loubeyre P, Occelli F, Dumas P 2020 Nature 577 631Google Scholar

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    Monacelli L, Errea I, Calandra M, Mauri F 2020 Nat. Phys.

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    Ginzburg V L 1999 Physics Uspekhi 42 353Google Scholar

    [40]

    Wang H, Li X, Gao G Y, Li Y W, Ma Y M 2018 Wires. Comput. Mol. Sci. 8 e1330

    [41]

    Flores-Livas J A, Boeri L, Sanna A, Profeta G, Arita R, Eremets M 2020 Phys. Rep. 856 1Google Scholar

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    Ashcroft N W 2004 Phys. Rev. Lett. 92 187002Google Scholar

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    Eremets M I, Trojan I A, Medvedev S A, Tse J S, Yao Y 2008 Science 319 1506Google Scholar

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    Kim D Y, Scheicher R H, Lebegue S, Prasongkit J, Arnaud B, Alouani M, Ahuja R 2008 Proc. Natl. Acad. Sci. U.S.A. 105 16454Google Scholar

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    Martinez-Canales M, Oganov A R, Ma Y, Yan Y, Lyakhov A O, Bergara A 2009 Phys. Rev. Lett. 102 087005Google Scholar

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    Degtyareva O, Proctor J E, Guillaume C L, Gregoryanz E, Hanfland M 2009 Solid State Commun. 149 1583Google Scholar

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  • 收稿日期:  2020-12-22
  • 修回日期:  2020-12-30
  • 上网日期:  2021-01-03
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