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本文研究了热致变色微胶囊环氧绝缘材料的介电松弛特性及机理. 结果表明, 热致变色微胶囊环氧绝缘材料表现出非单调介电松弛特性, 即在58—66 ℃温度范围内, 介电松弛时间随温度升高而逐渐延长, 无法通过传统的Arrhenius或Vogel-Fulcher-Tammann方程进行描述. 分析认为, 该非单调介电松弛特性主要源于微胶囊内限域相变引发的自由体积变化. 随着温度的升高, 微胶囊有限空间内发生固-液相变, 使得微胶囊内的自由体积逐渐减小, 限制了偶极子随外电场的定向过程, 导致介电松弛时间逐渐延长. 采用限域介电松弛模型拟合了热致变色环氧试样的非单调介电松弛特性, 并得到了介电松弛活化能. 不同微胶囊含量的热致变色试样的介电松弛活化能均处于相同的数量级, 表明其非单调介电松弛过程均发生于热致变色微胶囊内, 验证了限域相变对非单调介电松弛特性的作用.The dielectric relaxation characteristic and mechanism of thermochromic microcapsule-epoxy insulating material are investigated. The results show that thermochromic microcapsule-epoxy insulating material exhibits non-monotonic dielectric relaxation characteristic, namely the dielectric relaxation time gradually increases with the temperature rising in a range of about 58–66 ℃, which cannot be depicted by the conventional Arrhenius equation or Vogel-Fulcher-Tammann equation. It is proposed that the non-monotonic dielectric relaxation characteristic is derived from the free volume variation induced by the confined phase transition in microcapsule. With the increase of temperature, the solid-liquid phase transition occurs in the limited space of microcapsule, reducing the free volume inside the microcapsule, which could restrict the reorientation of dipole with the external electric field and lead to the increase of dielectric relaxation time. The non-monotonic dielectric relaxation characteristic of thermochromic epoxy specimen is fitted based on the confined dielectric relaxation model, obtaining the activation energy of dielectric relaxation. The relaxation activation energy values of thermochromic epoxy insulating materials with different microcapsule content are of the same order of magnitude, indicating that the non-monotonic dielectric relaxations occur inside the thermochromic microcapsule, verifying the role of confined phase transition in the non-monotonic dielectric relaxation characteristic.
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Keywords:
- thermochromism /
- confined phase transition /
- dielectric relaxation /
- free volume
[1] 盛戈皞, 钱勇, 罗林根, 宋辉, 刘亚东, 江秀臣 2021 高电压技术 47 3072
Google Scholar
Sheng G H, Qian Y, Luo L G, Song H, Liu Y D, Jiang X C 2021 High Volt. Eng. 47 3072
Google Scholar
[2] Huang X, Han L, Yang X, Huang Z, Hu J, Li Q, He J 2022 iEnergy 1 19
Google Scholar
[3] Li S T, Yu S H, Feng Y 2016 High Volt. 1 122
Google Scholar
[4] Zhang Y, Li S T, Gao J, Wang S, Wu K N, Li J Y 2020 IEEE Trans. Dielectr. Electr. Insul. 27 1795
Google Scholar
[5] 高建, 严智民, 李建英, 任志刚, 郭卫, 潘泽华 2022 西安交通大学学报 56 155
Google Scholar
Gao J, Yan Z M, Li J Y, Ren Z G, Guo W, Pan Z H 2022 J. Xi’an Jiaotong Univ. 56 155
Google Scholar
[6] 林生军, 黄印, 谢东日, 闵道敏, 王威望, 杨柳青, 李盛涛 2016 物理学报 65 077701
Google Scholar
Lin S J, Huang Y, Xie D R, Min D M, Wang W W, Yang L Q, Li S T 2016 Acta. Phys. Sin. 65 077701
Google Scholar
[7] Tian F Q, Ohki Y 2014 J. Phys. D:Appl. Phys. 47 045311
Google Scholar
[8] Cheng L, Liu W F, Liu H B, Li S T 2020 J. Phys. D: Appl. Phys. 53 445502
Google Scholar
[9] Li Z, Min D M, Niu H, Li S J, Zhang Y Y, Huang Y, Li S T 2021 J. Appl. Phys. 130 065101
Google Scholar
[10] 高铭泽, 张沛红 2016 物理学报 65 247802
Google Scholar
Gao M Z, Zhang P H 2016 Acta. Phys. Sin. 65 247802
Google Scholar
[11] Lian Z, Min D M, Li S T, Han Y S 2019 IEEE Trans. Terahertz Sci. Technol. 9 383
Google Scholar
[12] Seeboth A, Lotzsch D, Ruhmann R and Muehling O 2014 Chem. Rev. 114 3037
Google Scholar
[13] Gao J, Wu K N, Li J Y, Yin G L, Li S T 2023 Smart Mater. Struct. 32 015019
Google Scholar
[14] Panák O, Držková M, Kaplanová M 2015 Dyes Pigm. 120 279
Google Scholar
[15] Hajzeri M, Baˇsnec K, Bele M and Gunde M K 2015 Dyes Pigm. 113 754
Google Scholar
[16] Ryabov Y E, Puzenko A, Feldman Y 2004 Phys. Rev. B 69 014204
Google Scholar
[17] Frunza L, Schönhals A, Frunza S, Parvulescu V I, Cojocaru B, Carriazo D, Martín C, Rives V 2007 J. Phys. Chem. A 111 5166
Google Scholar
[18] Feldman Y, Gusev Y A, Vasilyeva M A 2012 Dielectric Relaxation Phenomena in Complex Systems (Kazan: Kazan University) pp100–108
[19] Ryabov Y, Gutina A, Arkhipov V, Feldman Y 2001 J. Phys. Chem. B 105 1845
Google Scholar
[20] Bitton G, Feldman Y, Agranat A J 2002 J. Non-Cryst. Solids 305 362
Google Scholar
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图 2 热致变色过程中微胶囊内固-液相变的DSC结果.
Fig. 2. DSC result of the solid-liquid phase transition in microcapsules during thermochromsim.
图 3 不同试样的介电松弛特性 (a) 0 phr; (b) 0.2 phr; (c) 0.5 phr; (d) 1.0 phr
Fig. 3. Dielectric relaxation characteristics of different specimens: (a) 0 phr; (b) 0.2 phr; (c) 0.5 phr; (d) 1.0 phr.
图 4 不同热致变色环氧试样的非单调介电松弛时间温度特性及拟合结果
Fig. 4. Nonmonotonic temperature dependences of dielectric relaxation times of different thermochromic epoxy specimens and the fitting results.
表 1 介电松弛时间温度特性的拟合参数
Table 1. Fitting parameters of temperature dependences of dielectric relaxation times.
微胶囊含量/phr Ea/eV Eb/eV C 0.2 154.39 0.064 22570 0.5 119.28 0.044 9933 1.0 139.90 0.054 17250 
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[1] 盛戈皞, 钱勇, 罗林根, 宋辉, 刘亚东, 江秀臣 2021 高电压技术 47 3072
Google Scholar
Sheng G H, Qian Y, Luo L G, Song H, Liu Y D, Jiang X C 2021 High Volt. Eng. 47 3072
Google Scholar
[2] Huang X, Han L, Yang X, Huang Z, Hu J, Li Q, He J 2022 iEnergy 1 19
Google Scholar
[3] Li S T, Yu S H, Feng Y 2016 High Volt. 1 122
Google Scholar
[4] Zhang Y, Li S T, Gao J, Wang S, Wu K N, Li J Y 2020 IEEE Trans. Dielectr. Electr. Insul. 27 1795
Google Scholar
[5] 高建, 严智民, 李建英, 任志刚, 郭卫, 潘泽华 2022 西安交通大学学报 56 155
Google Scholar
Gao J, Yan Z M, Li J Y, Ren Z G, Guo W, Pan Z H 2022 J. Xi’an Jiaotong Univ. 56 155
Google Scholar
[6] 林生军, 黄印, 谢东日, 闵道敏, 王威望, 杨柳青, 李盛涛 2016 物理学报 65 077701
Google Scholar
Lin S J, Huang Y, Xie D R, Min D M, Wang W W, Yang L Q, Li S T 2016 Acta. Phys. Sin. 65 077701
Google Scholar
[7] Tian F Q, Ohki Y 2014 J. Phys. D:Appl. Phys. 47 045311
Google Scholar
[8] Cheng L, Liu W F, Liu H B, Li S T 2020 J. Phys. D: Appl. Phys. 53 445502
Google Scholar
[9] Li Z, Min D M, Niu H, Li S J, Zhang Y Y, Huang Y, Li S T 2021 J. Appl. Phys. 130 065101
Google Scholar
[10] 高铭泽, 张沛红 2016 物理学报 65 247802
Google Scholar
Gao M Z, Zhang P H 2016 Acta. Phys. Sin. 65 247802
Google Scholar
[11] Lian Z, Min D M, Li S T, Han Y S 2019 IEEE Trans. Terahertz Sci. Technol. 9 383
Google Scholar
[12] Seeboth A, Lotzsch D, Ruhmann R and Muehling O 2014 Chem. Rev. 114 3037
Google Scholar
[13] Gao J, Wu K N, Li J Y, Yin G L, Li S T 2023 Smart Mater. Struct. 32 015019
Google Scholar
[14] Panák O, Držková M, Kaplanová M 2015 Dyes Pigm. 120 279
Google Scholar
[15] Hajzeri M, Baˇsnec K, Bele M and Gunde M K 2015 Dyes Pigm. 113 754
Google Scholar
[16] Ryabov Y E, Puzenko A, Feldman Y 2004 Phys. Rev. B 69 014204
Google Scholar
[17] Frunza L, Schönhals A, Frunza S, Parvulescu V I, Cojocaru B, Carriazo D, Martín C, Rives V 2007 J. Phys. Chem. A 111 5166
Google Scholar
[18] Feldman Y, Gusev Y A, Vasilyeva M A 2012 Dielectric Relaxation Phenomena in Complex Systems (Kazan: Kazan University) pp100–108
[19] Ryabov Y, Gutina A, Arkhipov V, Feldman Y 2001 J. Phys. Chem. B 105 1845
Google Scholar
[20] Bitton G, Feldman Y, Agranat A J 2002 J. Non-Cryst. Solids 305 362
Google Scholar
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