Controllable synthesis and performance of magnetic nanocomposites with core/shell structure

He Xue-Min; Zhong Wei; Du You-Wei

doi:10.7498/aps.67.20181027

Abstract

Magnetic nanocomposites with core/shell structure are an important class of functional materials, and their comprehensive properties are affected by the microstructures of materials: they are largely dependent on the controlled sysnthesis of the composite systems. In this paper, we review the research advances in the preparation, characterization and performance of core/shell-structured magnetic nanocomposites, focusing on the following systems: 1) ferrite-based permanent-magnet/soft-magnetic (or antiferromagnetic) composite nanomaterials; 2) nanocomposites comprised of the magnetic core particles and the nonmagnetic coating layers; 3) carbon-based nanocomposites obtained by the catalytic synthesis of magnetic particles; 4) nanocomposites with exchange bias effect; 5) one-dimensional nanocomposites with coaxial core/shell structure; 6) core/shell/shell structured magnetic ternary nanocomposites. The components of these composite systems include M-type permanent-magnet ferrites, 3d transition metals (and their alloys, oxides and carbides), multiferroics, nonmagnetic (such as insulator, semiconductor and organic molecule), and carbon materials. And the emphasis is placed on the analysis of thermal stability, photoluminescence performance, photoelectrocatalytic capacity, electrochemical characteristics, microwave absorption properties, magnetoresistance effect, permanent magnetic property, high-frequency soft-magnetic properties, exchange bias effect and related phenomenology for the core/shell-structured nanocomposites. Finally, the future developing trend of the magnetic nanocomposites with core/shell structure is presented, and some fundamental researches and modified applications are also proposed.

Keywords:

Authors and contacts

1.
Research Center of Information Physics, School of Science, Nanjing University of Posts and Telecommunications, Nanjing 210023, China;
2.
National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: Zhong Wei, wzhong@nju.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 11604160, 11774156, 11474151), the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20160876), the National Laboratory of Solid State Microstructures, Nanjing University, China (Grant No. M30007), and the Nanjing University of Posts and Telecommunications Foundation, China (Grant No. NY215063).

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Cited By

[1]	Beek W J E, Wienk M M, Jansen R A J 2004 Adv. Mater. 16 1009
[2]	Sajjad M, Morell G, Feng P 2013 ACS Appl. Mater. Interfaces 5 5051
[3]	Zhang H T, Wu G, Chen X H, Qiu X G 2006 Mater. Res. Bull. 41 495
[4]	He X M, Zhong W, Au C T, Du Y W 2013 Nanoscale Res. Lett. 8 446
[5]	Kodama R H, Makhlouf S A, Berkowitz A E 1997 Phys. Rev. Lett. 79 1393
[6]	Martínez-Boubeta C, Simeonidis K, Angelakeris M, Pazos-Pérez N, Giersig M, Delimitis A, Nalbandian L, Alexandrakis V, Niarchos D 2006 Phys. Rev. B 74 054430
[7]	Tracy J B, Bawendi M G 2006 Phys. Rev. B 74 184434
[8]	Johnston-Peck A C, Wang J W, Tracy J B 2009 ACS Nano 3 1077
[9]	Djerdj I, Arčon D, Jaglčić Z, Niederberger M 2007 J. Phys. Chem. C 111 3614
[10]	He X M, Zhong W, Yan S M, Au C T, L L Y, Du Y W 2014 J. Phys. D: Appl. Phys. 47 235002
[11]	Hou Y L, Xu Z C, Sun S H 2007 Angew. Chem. 119 6445
[12]	Zhang H T, Chen X H 2005 Nanotechnology 16 2288
[13]	Makhlouf S A, Al-Attar H, Kodama R H 2008 Solid State Commun. 145 1
[14]	Lu A H, Salabas E L, Schth F 2007 Angew. Chem. Int. Ed. 46 1222
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[24]	Zhou H P, Xu S X, Zhang D K, Chen S J, Deng J K 2017 Nanoscale 9 3196
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[26]	Choi E B, Lee J H 2015 J. Alloys Compd. 643 S231
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