二维共价键子结构Zintl相热电材料研究及进展

袁珉慧; 乐文凯; 谈小建; 帅晶

doi:10.7498/aps.70.20211010

摘要

热电材料可以实现热能和电能间的直接相互转换, 在半导体制冷和热能回收方面有着重要应用. Zintl相热电材料由电负性差异较大的阴阳离子组成, 其输运特征符合“声子玻璃, 电子晶体”的概念, 因此受到了广泛的研究, 特别是具有二维共价键子结构Zintl相热电材料凭借优异的电性能更是被寄予厚望. 本文综述了具有二维共价键子结构的典型Zintl相热电材料, 梳理了研究最广且性能突出的CaAl₂Si₂结构1-2-2型、原胞内原子较多本征低热导率的9–4+x–9型、具有天然空位而本征热导率极低的2-1-2型、以及电性能相对较好的ZrBeSi结构1-1-1型Zintl相的研究进展; 其中还特别总结了性能优异的Mg₃Sb₂基n型Zintl材料的研究发展. 本文概括总结了每种体系近年来的研究进展及性能调控方法, 讨论了进一步优化其热电性能的可能策略, 并对其未来发展进行了展望.

关键词:

Abstract

Thermoelectric materials can realize the direct conversion between thermal energy and electrical energy, and thus having important applications in semiconductor refrigeration and heat recovery. Zintl phase is composed of highly electronegative cations and anions, which accords with the concept of “phonon glass, electron crystal” (PGEC). Thermoelectric properties of Zintl phase have attracted extensive interest, among which the two-dimensional (2D) covalent bond structure featured Zintl phases have received more attention for their outstanding electrical properties. In this review, Zintl phase materials with two-dimensional covalent bond substructures are reviewed, including 1-2-2-type, 9–4+x–9-type, 2-1-2-type and 1-1-1-type Zintl phase. The 1-2-2-type Zintl phase is currently the most widely studied and best-performing Zintl material. It is worth mentioning that the maximum ZT value for the Mg₃Sb₂-based n-type Zintl material with the CaAl₂Si₂ structure has been reported to reach 1.85, and the average ZT value near room temperature area also reaches 1.4. The 9–4+x–9-type Zintl material with a mass of atoms in unit cell contributes to lower thermal conductivity thus relatively high ZT value. The 2-1-2-type Zintl material has extremely low thermal conductivity due to the intrinsic vacancies, which has been developing in recent years. The 1-1-1-type Zintl material with the same ZrBeSi structure as the 2-1-2-type Zintl material, shows better electrical transport performance. In sum, this review summarizes the recent progress and optimization methods of those typical Zintl phases above. Meanwhile, the future optimization and development of Zintl phase with two-dimensional covalent bond substructures are also prospected.

Keywords:

thermoelectric materials /
Zintl phase /
2-dimensional covalent bond substructure

作者及机构信息

1.
中山大学材料学院, 深圳　518107

2.
中国科学院宁波材料技术与工程研究所, 宁波　315201

通信作者: 谈小建, tanxiaojian@nimte.ac.cn ; 帅晶, shuaij3@mail.sysu.edu.cn

基金项目: 国家自然科学基金 (批准号: 52002413, 21875273)、广东省自然科学基金(批准号: 2021A1515010612)、浙江省自然科学基金杰出青年项目(批准号: LR21E020002)和中国科学院青年创新促进会(批准号: 2019298)资助的课题.

Authors and contacts

1.
School of Materials, Sun Yat-sen University, Shenzhen 518107, China

2.
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China

Corresponding author: Tan Xiao-Jian, tanxiaojian@nimte.ac.cn ; Shuai Jing, shuaij3@mail.sysu.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 52002413, 21875273), the Natural Science Foundation of Guangdong Province, China (Grant No. 2021A1515010612), the Natural Science Foundation of Zhejiang Province, China (Grant No. LR21E020002), and Youth Innovation Promotion Association CAS (Grant No. 2019298).

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参考文献

[1]	Rowe D M 2006 Thermoelectrics Handbook: Macro to Nano (Boca Raton: CRC/Taylor & Francis)
[2]	Goldsmid H J 2010 Introduction to Thermoelectricity (Vol. 121) (Berlin, Heidelberg: Springer Berlin Heidelberg)
[3]	Snyder G J, Toberer E S 2008 Nat. Mater. 7 105 Google Scholar
[4]	Pei Y Z, Wang H, Snyder G J 2012 Adv. Mater. 24 6125 Google Scholar
[5]	Ren Z F, Lan Y C, Zhang Q Y 2017 Advanced Thermoelectrics: Materials, Contacts, Devices, and Systems (Boca Raton, FL: CRC Press)
[6]	Zintl E 1939 Angew. Chem. 52 1 Google Scholar
[7]	Laves F 1941 Naturwissenschaften 29 244 Google Scholar
[8]	Shuai J, Geng H Y, Lan Y C, Zhu Z, Wang C, Liu Z, Bao J M, Chu C W, Sui J H, Ren Z F 2016 Proc. Natl. Acad. Sci. U. S. A. 113 E4125 Google Scholar
[9]	Shuai J, Mao J, Song S W, Zhu Q, Sun J F, Wang Y M, He R, Zhou J W, Chen G, Singh D J, Ren Z F 2017 Energy Environ. Sci. 10 799 Google Scholar
[10]	Chen X X, Wu H J, Cui J, Xiao Y, Zhang Y, He J Q, Chen Y, Cao J, Cai W, Pennycook S J, Liu Z H, Zhao L D, Sui J H 2018 Nano Energy 52 246 Google Scholar
[11]	Song S W, Mao J, Bordelon M, He R, Wang Y M, Shuai J, Sun J Y, Lei X B, Ren Z S, Chen S, Wilson S, Nielsch K, Zhang Q Y, Ren Z F 2019 Mater. Today Phys. 8 25 Google Scholar
[12]	Chen X X, Zhu J B, Qin D D, Qu N, Xue W H, Wang Y M, Zhang Q, Cai W, Guo F K, Sui J H 2021 Science China-Materials 64 1761
[13]	Song S W, Mao J, Shuai J, Zhu H T, Ren Z, Saparamadu U, Tang Z J, Wang B, Ren Z F 2018 Appl. Phys. Lett. 112 092103 Google Scholar
[14]	Brown S R, Kauzlarich S M, Gascoin F, Snyder G J 2006 Chem. Mater. 18 1873 Google Scholar
[15]	Hu Y, Bux S K, Grebenkemper J H, Kauzlarich S M 2015 J. Mater. Chem. C 3 10566 Google Scholar
[16]	Tan W, Liu Y, Zhu M, Zhu T, Zhao X, Tao X, Xia S 2017 Inorg. Chem. 56 1646 Google Scholar
[17]	Baranets S, Bobev S 2020 Mater. Today Adv. 7 100094 Google Scholar
[18]	Zevalkink A, Toberer E S, Zeier W G, Flage-Larsen E, Snyder G J 2011 Energy Environ. Sci. 4 510 Google Scholar
[19]	Xia S Q, Bobev S 2008 J. Comput. Chem. 29 2125 Google Scholar
[20]	Toberer E S, Zevalkink A, Crisosto N, Snyder G J 2010 Adv. Funct. Mater. 20 4375 Google Scholar
[21]	Zhang Z W, Yan Y R, Li X F, Wang X Y, Li J, Chen C, Cao F, Sui J H, Lin X, Liu X J, Xie G Q, Zhang Q 2020 Adv. Energy Mater. 10 2001229 Google Scholar
[22]	Song L R, Zhang J W, Iversen B B 2017 J. Mater. Chem. A 5 4932 Google Scholar
[23]	Lin Y, Wood M, Imasato K, Kuo J J, Lam D, Mortazavi A N, Slade T J, Hodge S A, Xi K, Kanatzidis M G, Clarke D R, Hersam M C, Snyder G J 2020 Energy Environ. Sci. 13 4114 Google Scholar
[24]	Chen C, Li X F, Xue W H, Bai F X, Huang Y, Yao H H, Li S, Zhang Z W, Wang X Y, Sui J H, Liu X J, Cao F, Wang Y M, Zhang Q 2020 Nano Energy 73 104771 Google Scholar
[25]	Chen C, Xue W H, Li S, Zhang Z W, Li X F, Wang X Y, Liu Y J, Sui J H, Liu X J, Cao F, Ren Z F, Chu C W, Wang Y M, Zhang Q 2019 Proc. Natl. Acad. Sci. U.S.A. 116 2831 Google Scholar
[26]	Zhang W M, Chen C, Yao H H, Xue W H, Li S, Bai F X, Huang Y F, Li X F, Lin X, Cao F, Sui J H, Wang S F, Yu B, Wang Y M, Liu X J, Zhang Q 2020 Chem. Mater. 32 6983 Google Scholar
[27]	Ohno S, Aydemir U, Amsler M, Pöhls J H, Chanakian S, Zevalkink A, White M A, Bux S K, Wolverton C, Snyder G J 2017 Adv. Funct. Mater. 27 1606361 Google Scholar
[28]	Chen C, Xue W H, Li X F, Lan Y C, Zhang Z W, Wang X Y, Zhang F, Yao H H, Li S, Sui J H, Han P D, Liu X J, Cao F, Wang Y M, Zhang Q 2019 ACS Appl. Mater. Interfaces 11 37741 Google Scholar
[29]	Aydemir U, Zevalkink A, Ormeci A, Gibbs Z M, Bux S, Snyder G J 2015 Chem. Mater. 27 1622 Google Scholar
[30]	Aydemir U, Zevalkink A, Ormeci A, Bux S, Snyder G J 2016 J. Mater. Chem. A 4 1867 Google Scholar
[31]	Sales B C, Mandrus D, Williams R K 1996 Science 272 1325 Google Scholar
[32]	Brown S R, Toberer E S, Ikeda T, Cox C A, Gascoin F, Kauzlarich S M, Snyder G J 2008 Chem. Mater. 20 3412 Google Scholar
[33]	Toberer E S, Cox C A, Brown S R, Ikeda T, May A F, Kauzlarich S M, Snyder G J 2008 Adv. Funct. Mater. 18 2795 Google Scholar
[34]	Wang X, Li J, Wang C, Zhou B Q, Zheng L T, Gao B, Chen Y, Pei Y Z 2018 Chem. Mater. 30 5339 Google Scholar
[35]	Ohno S, Zevalkink A, Takagiwa Y, Bux S K, Snyder G J 2014 J. Mater. Chem. A 2 7478 Google Scholar
[36]	Gascoin F, Ottensmann S, Stark D, Haïle S M, Snyder G J 2005 Adv. Funct. Mater. 15 1860 Google Scholar
[37]	Cao Q G, Zhang H, Tang M B, Chen H H, Yang X X, Grin Y, Zhao J T 2010 J. Appl. Phys. 107 053714 Google Scholar
[38]	Wang X J, Tang M B, Zhao J T, Chen H H, Yang X X 2007 Appl. Phys. Lett. 90 232107 Google Scholar
[39]	May A F, McGuire M A, Singh D J, Ma J, Delaire O, Huq A, Cai W, Wang H 2012 Phys. Rev. B 85 035202 Google Scholar
[40]	Cao Q, Zheng J, Zhang K, Ma G 2016 J. Alloys Compd. 680 278 Google Scholar
[41]	Wang X, Li W, Zhou B, Sun C, Zheng L, Tang J, Shi X, Pei Y 2019 Mater. Today Phys. 8 123 Google Scholar
[42]	Zheng L T, Li W, Wang X, Pei Y Z 2019 J. Mater. Chem. A 7 12773 Google Scholar
[43]	Guo M C, Zhu J B, Guo F K, Zhang Q, Cai W, Sui J H 2020 Mater. Today Phys. 15 100270 Google Scholar
[44]	Wang J, Guo M C, Zhu J B, Qin D D, Guo F kai, Zhang Q, Cai W, Sui J H 2020 J. Mater. Sci. Technol. 59 189 Google Scholar
[45]	Saparamadu U, Tan X J, Sun J F, Ren Z S, Song S W, Singh D J, Shuai J, Jiang J, Ren Z F 2020 J. Mater. Chem. A 8 15760 Google Scholar
[46]	Wang X J, Tang M B, Chen H H, Yang X X, Zhao J T, Burkhardt U, Grin Y 2009 Appl. Phys. Lett. 94 092106 Google Scholar
[47]	Zhang H, Baitinger M, Tang M B, Man Z Y, Chen H H, Yang X X, Liu Y, Chen L, Grin Y, Zhao J T 2010 Dalton Trans. 39 1101 Google Scholar
[48]	Bhardwaj A, Misra D K 2014 RSC Adv. 4 34552 Google Scholar
[49]	Shuai J, Liu Z H, Kim H S, Wang Y, Mao J, He R, Sui J H, Ren Z F 2016 J. Mater. Chem. A 4 4312 Google Scholar
[50]	Zhu M, Wu Z, Liu Q, Zhu T J, Zhao X B, Huang B, Tao X, Xia S Q 2018 J. Mater. Chem. A 6 11773 Google Scholar
[51]	Yang C H, Guo K, Yang X X, Xing J J, Wang K, Luo J, Zhao J T 2019 ACS Appl. Energy Mater. 2 889 Google Scholar
[52]	Zhang X, Gu H S, Zhang Y, Guo L J, Yang J T, Luo S J, Lu X, Chen K S, Chai H X, Wang G Y, Zhang X, Zhou X Y 2019 Chem. Eng. J. 374 589 Google Scholar
[53]	Zhang J W, Song L R, Madsen G K H, Fischer K F F, Zhang W Q, Shi X, Iversen B B 2016 Nat. Commun. 7 10892 Google Scholar
[54]	Shuai J, Kim H S, Liu Z H, He R, Sui J H, Ren Z F 2016 Appl. Phys. Lett. 108 183901 Google Scholar
[55]	Gong J J, Hong A J, Shuai J, Li L, Yan Z B, Ren Z F, Liu J M 2016 Phys. Chem. Chem. Phys. 18 16566 Google Scholar
[56]	Pomrehn G S, Zevalkink A, Zeier W G, van de Walle A, Snyder G J 2014 Angew. Chem. Int. Ed. 53 3422 Google Scholar
[57]	Yu C, Zhu T J, Zhang S N, Zhao X B, He J, Su Z, Tritt T M 2008 J. Appl. Phys. 104 013705 Google Scholar
[58]	Zhang H, Zhao J T, Grin Y, Wang X J, Tang M B, Man Z Y, Chen H H, Yang X X 2008 J. Chem. Phys. 129 164713 Google Scholar
[59]	Zhang H, Fang L, Tang M B, Man Z Y, Chen H H, Yang X X, Baitinger M, Grin Y, Zhao J T 2010 J. Chem. Phys. 133 194701 Google Scholar
[60]	Guo K, Cao Q G, Feng X J, Tang M B, Chen H H, Guo X, Chen L, Grin Y, Zhao J T 2011 Eur. J. Inorg. Chem. 2011 4043 Google Scholar
[61]	Zevalkink A, Zeier W G, Cheng E, Snyder J, Fleurial J P, Bux S 2014 Chem. Mater. 26 5710 Google Scholar
[62]	Zhang J, Song L, Iversen B B 2019 npj Comput. Mater. 5 76 Google Scholar
[63]	Shuai J, Mao J, Song S W, Zhang Q Y, Chen G, Ren Z F 2017 Mater. Today Phys. 1 74 Google Scholar
[64]	Bhardwaj A, Chauhan N S, Misra D K 2015 J. Mater. Chem. A 3 10777 Google Scholar
[65]	Meng F C, Sun S S, Ma J L, Chronister C, He J, Li W 2020 Mater. Today Phys. 13 100217 Google Scholar
[66]	Shuai J, Wang Y M, Kim H S, Liu Z H, Sun J Y, Chen S, Sui J H, Ren Z F 2015 Acta Mater. 93 187 Google Scholar
[67]	Tamaki H, Sato H K, Kanno T 2016 Adv. Mater. 28 10182 Google Scholar
[68]	Kanno T, Tamaki H, Yoshiya M, Uchiyama H, Maki S, Takata M, Miyazaki Y 2021 Adv. Funct. Mater. 31 2008469 Google Scholar
[69]	Mao J, Shuai J, Song S W, Wu Y X, Dally R, Zhou J W, Liu Z H, Sun J F, Zhang Q Y, dela Cruz C, Wilson S, Pei Y Z, Singh D J, Chen G, Chu C W, Ren Z F 2017 Proc. Natl. Acad. Sci. U.S.A. 114 10548 Google Scholar
[70]	Imasato K, Fu C G, Pan Y, Wood M, Kuo J J, Felser C, Snyder G J 2020 Adv. Mater. 32 1908218 Google Scholar
[71]	Kuo J J, Kang S D, Imasato K, Tamaki H, Ohno S, Kanno T, Snyder G J 2018 Energy Environ. Sci. 11 429 Google Scholar
[72]	Ohno S, Imasato K, Anand S, Tamaki H, Kang S D, Gorai P, Sato H K, Toberer E S, Kanno T, Snyder G J 2018 Joule 2 141 Google Scholar
[73]	Kanno T, Tamaki H, Sato H K, Kang S D, Ohno S, Imasato K, Kuo J J, Snyder G J, Miyazaki Y 2018 Appl. Phys. Lett. 112 033903 Google Scholar
[74]	Shi X M, Sun C, Bu Z L, Zhang X Y, Wu Y X, Lin S Q, Li W, Faghaninia A, Jain A, Pei Y Z 2019 Adv. Sci. 6 1802286 Google Scholar
[75]	Shi X M, Zhao T T, Zhang X Y, Sun C, Chen Z W, Lin S Q, Li W, Gu H, Pei Y Z 2019 Adv. Mater. 31 1903387 Google Scholar
[76]	Bhardwaj A, Rajput A, Shukla A K, Pulikkotil J J, Srivastava A K, Dhar A, Gupta G, Auluck S, Misra D K, Budhani R C 2013 RSC Adv. 3 8504 Google Scholar
[77]	Shi X M, Wang X, Li W, Pei Y Z 2018 Small Methods 2 1800022 Google Scholar
[78]	Shu R, Zhou Y C, Wang Q, Han Z J, Zhu Y B, Liu Y, Chen Y X, Gu M, Xu W, Wang Y, Zhang W Q, Huang L, Liu W S 2019 Adv. Funct. Mater. 29 1807235 Google Scholar
[79]	Hu L P, Zhu T J, Liu X H, Zhao X B 2014 Adv. Funct. Mater. 24 5211 Google Scholar
[80]	Hu L, Wu H, Zhu T, Fu C, He J, Ying P, Zhao X 2015 Adv. Energy Mater. 5 1500411 Google Scholar
[81]	Fu T, Yue X, Wu H, Fu C, Zhu T, Liu X, Hu L, Ying P, He J, Zhao X 2016 J. Materiomics 2 141 Google Scholar
[82]	Imasato K, Kang S D, Snyder G J 2019 Energy Environ. Sci. 12 965 Google Scholar
[83]	Condron C L, Kauzlarich S M, Gascoin F, Snyder G J 2006 J. Solid State Chem. 179 2252 Google Scholar
[84]	Brechtel E, Cordier G, Schafer H 1979 Z. Naturforsch. , B:Chem. Sci. 34 1229 Google Scholar
[85]	Kim S J, Salvador J, Bilc D, Mahanti S D, Kanatzidis M G 2001 J. Am. Chem. Soc. 123 12704 Google Scholar
[86]	Bobev S, Thompson J D, Sarrao J L, Olmstead M M, Hope H, Kauzlarich S M 2004 Inorg. Chem. 43 5044 Google Scholar
[87]	Bux S K, Zevalkink A, Janka O, Uhl D, Kauzlarich S, Snyder J G, Fleurial J P 2014 J. Mater. Chem. A 2 215 Google Scholar
[88]	Kazem N, Zaikina J V, Ohno S, Snyder G J, Kauzlarich S M 2015 Chem. Mater. 27 7508 Google Scholar
[89]	Wu Z, Li J, Li X, Zhu M, Wu K C, Tao X T, Huang B B, Xia S Q 2016 Chem. Mater. 28 6917 Google Scholar
[90]	Zhang J, Liu Q, Liu K F, Tan W J, Liu X C, Xia S Q 2021 Inorg. Chem. 60 4026 Google Scholar
[91]	Liu X C, Wu Z, Xia S Q, Tao X T, Bobev S 2015 Inorg. Chem. 54 947 Google Scholar
[92]	Cooley J A, Promkhan P, Gangopadhyay S, Donadio D, Pickett W E, Ortiz B R, Toberer E S, Kauzlarich S M 2018 Chem. Mater. 30 484 Google Scholar
[93]	Xia S Q, Bobev S 2007 J. Am. Chem. Soc. 129 4049 Google Scholar
[94]	Wilson D K, Saparov B, Bobev S 2011 Z. Anorg. Allg. Chem. 637 2018 Google Scholar
[95]	Wang J, Xia S Q, Tao X T, Schäfer M C, Bobev S 2013 J. Solid State Chem. 205 116 Google Scholar
[96]	Yan J, Gorai P, Ortiz B, Miller S, Barnett S A, Mason T, Stevanović V, Toberer E S 2015 Energy Environ. Sci. 8 983 Google Scholar
[97]	Ovchinnikov A, Saparov B, Xia S Q, Bobev S 2017 Inorg. Chem. 56 12369 Google Scholar
[98]	Sun J F, Singh D J 2017 J. Mater. Chem. A 5 8499 Google Scholar
[99]	Ma H Q, Li G D, Zhang X L, Huang H J, Duan B, Zhai P C 2020 J. Alloys Compd. 843 155981 Google Scholar
[100]	Li Y, Chen J X, Cai P W, Wen Z H 2018 J. Mater. Chem. A 6 4948 Google Scholar
[101]	Yao H H, Chen C, Xue W H, Bai F X, Cao F, Lan Y C, Liu X J, Wang Y M, Singh D J, Lin X, Zhang Q 2021 Sci. Adv. 7 eabd6162 Google Scholar
[102]	Merlo F, Pani M, Fornasini M L 1990 J. Less-Common Met. 166 319 Google Scholar
[103]	Romaka V V, Falmbigl M, Grytsiv A, Rogl P 2014 J. Alloys Compd. 585 287 Google Scholar
[104]	Altayeb A, Sondezi B M, Tchoula Tchokonté M B, Strydom A M, Doyle T B, Kaczorowski D 2017 AIP Adv. 7 055714 Google Scholar
[105]	Chen S C, Lee J R, Syu K J, Lee W H 2014 Solid State Commun. 195 6 Google Scholar
[106]	Guo J, Zhu M, Li X, Tao X T, Xia S Q 2018 Inorg. Chem. Front. 5 1902 Google Scholar
[107]	May A F, Toberer E S, Snyder G J 2009 J. Appl. Phys. 106 013706 Google Scholar
[108]	Pan Y, Fan F R, Hong X, He B, Le C, Schnelle W, He Y, Imasato K, Borrmann H, Hess C, Buechner B, Sun Y, Fu C, Snyder G J, Felser C 2020 Adv. Mater. 33 2003168 Google Scholar
[109]	Liu Q, Liu X C, Liu K F, Zhang J, Xia S Q 2020 J. Alloys Compd. 847 156551 Google Scholar
[110]	Balvanz A, Qu J X, Baranets S, Ertekin E, Gorai P, Bobev S 2020 Chem. Mater. 32 10697 Google Scholar

施引文献

图 1 (a) 各类型结构中典型Zintl相ZT值对比图^{[8,10-12,14,18,21,24,25,28,32-35]}; (b) 2D典型Zintl相最大ZT值随时间变化总结图

Fig. 1. (a) ZT values of typical Zintl phases with 2D covalent bond substructures ^{[8,10-12,14,18,21,24,25,28,32-35]}; (b) summary diagram of the maximum ZT value of some representative 2D Zintl phase over time.

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图 2 AB₂X₂型Zintl材料　(a) 晶体结构; (b) 单胞扩展键; (c) 单胞不扩展键晶体结构示意图; (d) Sb基AB₂X₂型Zintl相ZT值对比图; (e) Bi基AB₂X₂型Zintl相ZT值对比图^{[8,21,34,36-45]}

Fig. 2. (a) Crystal structure of AB₂X₂-type Zintl material; (b), (c) unit cell. Temperature-dependent ZT values of (d) Sb-based AB₂X₂-type Zintl phases; (e) Bi-based AB₂X₂-type Zintl phases^{[8,21,34,36-45]}.

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图 3 Mg₃Sb₂ Zintl材料　(a) 晶体结构; (b) c轴方向晶体结构; (c) a轴方向晶体结构示意图; (d) Mg₃Sb₂结构由传统认为的层状结构到三维结构示意图; (e) 近年Mg₃Sb₂基Zintl相主要工作ZT值随温度变化图^{[9,10,22,23,48,66,69,76-78]}; (f) 突出Mg₃Sb₂相300—500 K及300—773 K温区下平均ZT值对比图^{[9-12,69,73,75,78-82]}

Fig. 3. (a) Crystal structure of Mg₃Sb₂; (b) crystal structure along the c axis; (c) crystal structure along the a axis; (d) Mg₃Sb₂ structure with traditional layered covalent bonds compared to the 3D covalent bonds; (e) temperature-dependent ZT values of Mg₃Sb₂-based Zintl phases^{[9,10,22,23,48,66,69,76-78]}; (f) average ZT values of Mg₃Sb₂-based Zintl phases at 300−500 K and 300−773 K^{[9-12,69,73,75,78-82]}.

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图 4 Ca₉Zn₄Sb₉相　(a) 晶体结构图; (b) a轴晶体结构图; 9–4+x–9型Zintl相近年来典型结构(c)ZT值随温度变化图; (d) 泽贝克系数随温度变化图; (e) 电阻率随温度变化图; (f) 热导率及晶格热导率随温度变化图^{[27,28,87-90]}

Fig. 4. (a) Crystal structure of Ca₉Zn₄Sb₉; (b) crystal structure of Ca₉Zn₄Sb₉ along a axis. Temperature-dependent (c) ZT values; (d) Seebeck coefficient; (e) electrical resistivity; (f) thermal conductivity of 9–4+x–9 type Zintl phases ^{[27,28,87-90]}.

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图 5 (a) EuZn₂Sb₂单胞晶体结构图; (b) Eu₂ZnSb₂相与EuZn₂Sb₂相结构对比图^[25]; (c) Eu₂ZnSb₂相a轴方向晶体结构图; (d) Eu₂ZnSb₂相c轴方向晶体结构示意图; (e) Eu₂ZnSb₂相扩胞后晶体结构示意图; (f) Eu₂ZnSb₂相扩胞后a轴方向晶体结构示意图; (g) 2-1-2型Zintl相近年来典型结构ZT值随温度变化图; (h) S随温度变化图; (i) 电阻率随温度变化图; (j) 2-1-2型Zintl相与9–4+x–9, 1-2-2型典型Zintl相晶格热导率随温度变化对比图^{[8,24,25,27,90,92]}

Fig. 5. (a) Unit cell of EuZn₂Sb₂; (b) unit cell of Eu₂ZnSb₂ ; (c) unit cell of Eu₂ZnSb₂ along the a axis;(d) crystal structure along the c axis; (e) crystal structure of Eu₂ZnSb₂; (f) in the a axis direction after cell expansion. Temperature-dependent (g) ZT values; (h) Seebeck coefficient; (i) electrical resistivity of 2-1-2 type Zintl phases; (j) lattice thermal conductivity of 2-1-2, 9–4+x–9 and 1-2-2type Zintl phases ^{[8,24,25,27,90,92]}.

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图 6 SrAgSbZintl相　(a) 晶体结构示意图; (b)延c轴方向晶体结构示意图. 1-1-1型Zintl相近年来典型结构 (c) ZT值随温度变化图; (d) 电阻率随温度变化图; (e) 热导率随温度变化图; (f) 1-1-1型Zintl相功率因子较同结构1-2-2型Zintl相随温度变化对比图^[24-26,106]

Fig. 6. (a) Crystal structure of SrAgSb; (b) crystal structure of SrAgSb along the c axis. Temperature-dependent (c) ZT values; (d) power factors (compared with 2-1-2 Zintl phases); (e) electric resistivity; (f) thermal conductivity of typical 1-1-1 Zintl phases^[24-26,106].

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表 1 1-2-2型层状Zintl材料热电性能汇总表

Table 1. Summary of thermoelectric properties of 1-2-2 type layered Zintl materials.

时间	材料	Ρ/(mΩ·cm)	S/(μV·K^–1)	κ/(W·m^–1·K^–1)	ZT	T/K	ZT_RT
2005	Ca_0.25Yb_0.75Zn₂Sb₂^[36]	3.7	170	1.4	0.56	773	0.08
2007	BaZn₂Sb₂^[38]	6.1	185	1.25	0.33	673	0.05
2008	YbZn_1.9Mn_0.1Sb₂^[57]	1.5	150	1.6	0.65	726	0.05
2008	EuZn₂Sb₂^[58]	1.8	180	1.45	0.9	713	0.16
2009	YbCd_1.6Zn_0.4Sb₂^[46]	1.66	180	1.1	1.2	650	0.2
2010	Yb_0.6Ca_0.4Cd₂Sb₂^[37]	4.4	240	0.9	0.96	700	0.14
2010	Yb_0.75Eu_0.25Cd₂Sb₂^[59]	4	240	1	0.97	650	0.18
2010	EuZn_1.8Cd_0.2Sb₂^[47]	2	200	1.4	1.06	650	0.18
2011	YbCd_1.85Mn_0.15Sb₂^[60]	5.7	245	0.6	1.14	650	0.17
2012	YbMg₂Bi₂^[39]	5	180	1.8	0.44	650	0.07
2014	Yb_0.99Zn₂Sb₂^[61]	1.3	160	1.7	0.85	800	0.05
2016	YbCd_1.9Mg_0.1Sb₂^[40]	3.3	230	1.02	1.08	650	0.2
2016	Ca_0.5Yb_0.5Mg₂Bi₂^[49]	2.8	187	1.08	1	873	0.1
2016	Ca_0.995Na_0.005Mg₂Bi_1.98^[54]	3	200	1.25	0.9	873	0.05
2016	Eu_0.2Yb_0.2Ca_0.6Mg₂Bi₂^[8]	3.5	215	0.92	1.3	875	0.25
2018	YbCd_1.5Zn_0.5Sb₂^[34]	1.7	172	1.2	1.26	700	0.18
2018	Yb_0.96Ba_0.04Cd_1.5Zn_0.5Sb₂^[34]	2	185	0.94	1.3	700	0.18
2019	Ba_0.7975Yb_0.2Na_0.0025Cd₂Sb₂^[41]	4.1	210	0.81	0.93	700	0.1
2019	EuCd_1.4Zn_0.6Sb₂^[42]	3.5	220	1	0.96	700	0.18
2020	Ca_0.65Yb_0.35Mg_1.9Zn_0.1Bi_1.98^[43]	2.63	185	1.04	1	773	0.2
2020	YbMg₂Bi_1.58Sb_0.4^[44]	4.1	219	1	1.05	873	0.14
2020	Sm_0.25Yb_0.375Eu_0.375Mg₂Bi_1.99^[45]	3.7	197	0.9	0.9	773	0.18
2020	(Yb_0.9Mg_0.1)Mg_0.8Zn_1.198Ag_0.002Sb₂^[21]	4.75	257	0.74	1.5	773	0.28

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表 2 Mg₃Sb₂基Zintl材料热电性能汇总表

Table 2. Summary of thermoelectric properties of Mg₃Sb₂-based layered Zintl materials.

时间	材料	ρ/(mΩ·cm)	S/(μV·K^–1)	κ/(W·m^–1·K^–1)	ZT	T/K	ZT_RT
2006	Mg₃Sb₂^[83]	29	288	1.2	0.21	875	0.001
2013	Mg₃Bi_0.2Sb_1.8^[76]	40	400	0.58	0.6	750	0.01
2014	Mg₃Pb_0.2Sb_1.8^[48]	28.6	280	0.28	0.84	773	0.03
2015	Mg_2.9875Na_0.0125Sb₂^[66]	5.4	200	0.95	0.6	773	0.03
2017	Mg_2.985Ag_0.015Sb₂^[22]	9	205	0.65	0.51	725	0.08
2016	Mg_3.2Sb_1.5Bi_0.49Te_0.01^[67]	5	–286	0.79	1.51	716	0.2
2016	Mg₃Sb_1.48Bi_0.48Te_0.04^[53]	10	–205	0.73	1.6	750	0.6
2017	Mg_3.05Nb_0.15Sb_1.5Bi_0.49Te_0.01^[9]	4.35	–277	0.84	1.57	700	0.31
2017	Mg_3.1Co_0.1Sb_1.5Bi_0.49Te_0.01^[69]	5.1	–295	0.78	1.7	773	0.4
2018	Mg_3.15Mn_0.05Sb_1.5Bi0_.49Te_0.01^[10]	4.5	–302	0.79	1.85	723	0.42
2019	Mg_3+δSb_1.5Bi_0.49Te_0.01:Mn_0.01^[78]	4.5	–290	0.9	1.6	773	0.65
2019	Mg_3.05SbBi_0.97Te_0.03^[74]	1.7	–202	0.92	1.31	500	0.71
2019	Mg_3.02Y_0.02Sb_1.5Bi_0.5^[11]	4.2	–270	0.76	1.8	773	0.2
2020	Mg_3.2Sb_1.99Te_0.01+GNP^[23]	6.4	–320	0.74	1.7	750	0.18
2021	Mg_3.17B_0.03Sb_1.5Bi0_.49Te_0.01^[12]	5.4	–296	0.69	1.81	773	0.62

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表 3 9–4+x–9型层状Zintl材料热电性能汇总表

Table 3. Summary of thermoelectric properties of 9–4+x–9 type layered Zintl materials.

时间	材料	ρ/(mΩ·cm)	S/(μV·K^–1)	κ/(W·m^–1·K^–1)	ZT	T/K	ZT_RT
2014	Yb₉Mn_4.2Sb₉^[87]	7.9	185	0.58	0.7	950	0.035
2015	Eu₉Cd_3.75Ag_1.42Sb₉^[91]	2.0	85	1.0	0.32	750	0.03
2016	Ca₉Zn_4.35Cu_0.15Sb₉^[89]	3.0	140	0.8	0.72	873	0.1
2017	Ca₉Zn_4.6Sb₉^[27]	11.0	270	0.48	1.1	873	0.1
2019	Ca_6.75Eu_2.25Zn_4.7Sb₉^[28]	5.55	200	0.53	1.05	773	0.21
2021	Sr₉Mg_4.45Bi₉^[90]	3.75	135	0.65	0.57	773	0.14 (323 K)

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表 4 2-1-2型层状Zintl材料热电性能汇总表

Table 4. Summary of thermoelectric properties of 2-1-2 type layered Zintl materials.

时间	材料	ρ/(mΩ·cm)	S/(μV·K^–1)	κ/(W·m^–1·K^–1)	ZT	T/K	ZT_RT
2017	Yb₂CdSb₂^[92]	5	155	0.52	0.2	523	0.23
2017	Yb_1.64Eu_0.36CdSb₂^[92]	3.5	170	0.6	0.7	523	0.26
2018	Eu₂ZnSb₂^[25]	24.4	290	0.42	0.6	723	0.14
2018	Eu₂Zn_0.98Sb₂^[25]	8	220	0.48	1	823	0.22
2020	Eu₂Zn_0.97Ag_0.06Sb₂^[24]	10	220	0.43	0.93	823	0.2
2020	Eu₂Zn_0.95Ag_0.06Sb₂^[24]	5.3	194	0.5	1.1	823	0.2

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表 5 1-1-1型层状Zintl材料热电性能汇总表

Table 5. Summary of thermoelectric properties of 1-1-1 type layered Zintl materials.

时间	材料	ρ/(mΩ·cm)	S/(μV·K^–1)	κ/(W·m^-1·K^–1)	ZT	T/K	ZT_RT
2018	Ca_0.85La_0.15Ag_0.89Sb^[106]	1.85	120	1.3	0.52	860	0.07
2018	Ca_0.55Sr_0.3La_0.15Ag_0.89Sb^[106]	1.6	125	1.0	0.7	823	0.1
2020	SrAgSb^[26]	0.95	114	2.2	0.5	773	0.07
2020	Sr_1.01AgSb^[26]	1.27	125	1.7	0.58	773	0.1
2020	EuCuSb^[26]	0.64	83	2.9	0.3	773	0.03
2020	EuAgSb^[26]	0.74	90	2.4	0.35	773	0.05

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[1]	Rowe D M 2006 Thermoelectrics Handbook: Macro to Nano (Boca Raton: CRC/Taylor & Francis)
[2]	Goldsmid H J 2010 Introduction to Thermoelectricity (Vol. 121) (Berlin, Heidelberg: Springer Berlin Heidelberg)
[3]	Snyder G J, Toberer E S 2008 Nat. Mater. 7 105 Google Scholar
[4]	Pei Y Z, Wang H, Snyder G J 2012 Adv. Mater. 24 6125 Google Scholar
[5]	Ren Z F, Lan Y C, Zhang Q Y 2017 Advanced Thermoelectrics: Materials, Contacts, Devices, and Systems (Boca Raton, FL: CRC Press)
[6]	Zintl E 1939 Angew. Chem. 52 1 Google Scholar
[7]	Laves F 1941 Naturwissenschaften 29 244 Google Scholar
[8]	Shuai J, Geng H Y, Lan Y C, Zhu Z, Wang C, Liu Z, Bao J M, Chu C W, Sui J H, Ren Z F 2016 Proc. Natl. Acad. Sci. U. S. A. 113 E4125 Google Scholar
[9]	Shuai J, Mao J, Song S W, Zhu Q, Sun J F, Wang Y M, He R, Zhou J W, Chen G, Singh D J, Ren Z F 2017 Energy Environ. Sci. 10 799 Google Scholar
[10]	Chen X X, Wu H J, Cui J, Xiao Y, Zhang Y, He J Q, Chen Y, Cao J, Cai W, Pennycook S J, Liu Z H, Zhao L D, Sui J H 2018 Nano Energy 52 246 Google Scholar
[11]	Song S W, Mao J, Bordelon M, He R, Wang Y M, Shuai J, Sun J Y, Lei X B, Ren Z S, Chen S, Wilson S, Nielsch K, Zhang Q Y, Ren Z F 2019 Mater. Today Phys. 8 25 Google Scholar
[12]	Chen X X, Zhu J B, Qin D D, Qu N, Xue W H, Wang Y M, Zhang Q, Cai W, Guo F K, Sui J H 2021 Science China-Materials 64 1761
[13]	Song S W, Mao J, Shuai J, Zhu H T, Ren Z, Saparamadu U, Tang Z J, Wang B, Ren Z F 2018 Appl. Phys. Lett. 112 092103 Google Scholar
[14]	Brown S R, Kauzlarich S M, Gascoin F, Snyder G J 2006 Chem. Mater. 18 1873 Google Scholar
[15]	Hu Y, Bux S K, Grebenkemper J H, Kauzlarich S M 2015 J. Mater. Chem. C 3 10566 Google Scholar
[16]	Tan W, Liu Y, Zhu M, Zhu T, Zhao X, Tao X, Xia S 2017 Inorg. Chem. 56 1646 Google Scholar
[17]	Baranets S, Bobev S 2020 Mater. Today Adv. 7 100094 Google Scholar
[18]	Zevalkink A, Toberer E S, Zeier W G, Flage-Larsen E, Snyder G J 2011 Energy Environ. Sci. 4 510 Google Scholar
[19]	Xia S Q, Bobev S 2008 J. Comput. Chem. 29 2125 Google Scholar
[20]	Toberer E S, Zevalkink A, Crisosto N, Snyder G J 2010 Adv. Funct. Mater. 20 4375 Google Scholar
[21]	Zhang Z W, Yan Y R, Li X F, Wang X Y, Li J, Chen C, Cao F, Sui J H, Lin X, Liu X J, Xie G Q, Zhang Q 2020 Adv. Energy Mater. 10 2001229 Google Scholar
[22]	Song L R, Zhang J W, Iversen B B 2017 J. Mater. Chem. A 5 4932 Google Scholar
[23]	Lin Y, Wood M, Imasato K, Kuo J J, Lam D, Mortazavi A N, Slade T J, Hodge S A, Xi K, Kanatzidis M G, Clarke D R, Hersam M C, Snyder G J 2020 Energy Environ. Sci. 13 4114 Google Scholar
[24]	Chen C, Li X F, Xue W H, Bai F X, Huang Y, Yao H H, Li S, Zhang Z W, Wang X Y, Sui J H, Liu X J, Cao F, Wang Y M, Zhang Q 2020 Nano Energy 73 104771 Google Scholar
[25]	Chen C, Xue W H, Li S, Zhang Z W, Li X F, Wang X Y, Liu Y J, Sui J H, Liu X J, Cao F, Ren Z F, Chu C W, Wang Y M, Zhang Q 2019 Proc. Natl. Acad. Sci. U.S.A. 116 2831 Google Scholar
[26]	Zhang W M, Chen C, Yao H H, Xue W H, Li S, Bai F X, Huang Y F, Li X F, Lin X, Cao F, Sui J H, Wang S F, Yu B, Wang Y M, Liu X J, Zhang Q 2020 Chem. Mater. 32 6983 Google Scholar
[27]	Ohno S, Aydemir U, Amsler M, Pöhls J H, Chanakian S, Zevalkink A, White M A, Bux S K, Wolverton C, Snyder G J 2017 Adv. Funct. Mater. 27 1606361 Google Scholar
[28]	Chen C, Xue W H, Li X F, Lan Y C, Zhang Z W, Wang X Y, Zhang F, Yao H H, Li S, Sui J H, Han P D, Liu X J, Cao F, Wang Y M, Zhang Q 2019 ACS Appl. Mater. Interfaces 11 37741 Google Scholar
[29]	Aydemir U, Zevalkink A, Ormeci A, Gibbs Z M, Bux S, Snyder G J 2015 Chem. Mater. 27 1622 Google Scholar
[30]	Aydemir U, Zevalkink A, Ormeci A, Bux S, Snyder G J 2016 J. Mater. Chem. A 4 1867 Google Scholar
[31]	Sales B C, Mandrus D, Williams R K 1996 Science 272 1325 Google Scholar
[32]	Brown S R, Toberer E S, Ikeda T, Cox C A, Gascoin F, Kauzlarich S M, Snyder G J 2008 Chem. Mater. 20 3412 Google Scholar
[33]	Toberer E S, Cox C A, Brown S R, Ikeda T, May A F, Kauzlarich S M, Snyder G J 2008 Adv. Funct. Mater. 18 2795 Google Scholar
[34]	Wang X, Li J, Wang C, Zhou B Q, Zheng L T, Gao B, Chen Y, Pei Y Z 2018 Chem. Mater. 30 5339 Google Scholar
[35]	Ohno S, Zevalkink A, Takagiwa Y, Bux S K, Snyder G J 2014 J. Mater. Chem. A 2 7478 Google Scholar
[36]	Gascoin F, Ottensmann S, Stark D, Haïle S M, Snyder G J 2005 Adv. Funct. Mater. 15 1860 Google Scholar
[37]	Cao Q G, Zhang H, Tang M B, Chen H H, Yang X X, Grin Y, Zhao J T 2010 J. Appl. Phys. 107 053714 Google Scholar
[38]	Wang X J, Tang M B, Zhao J T, Chen H H, Yang X X 2007 Appl. Phys. Lett. 90 232107 Google Scholar
[39]	May A F, McGuire M A, Singh D J, Ma J, Delaire O, Huq A, Cai W, Wang H 2012 Phys. Rev. B 85 035202 Google Scholar
[40]	Cao Q, Zheng J, Zhang K, Ma G 2016 J. Alloys Compd. 680 278 Google Scholar
[41]	Wang X, Li W, Zhou B, Sun C, Zheng L, Tang J, Shi X, Pei Y 2019 Mater. Today Phys. 8 123 Google Scholar
[42]	Zheng L T, Li W, Wang X, Pei Y Z 2019 J. Mater. Chem. A 7 12773 Google Scholar
[43]	Guo M C, Zhu J B, Guo F K, Zhang Q, Cai W, Sui J H 2020 Mater. Today Phys. 15 100270 Google Scholar
[44]	Wang J, Guo M C, Zhu J B, Qin D D, Guo F kai, Zhang Q, Cai W, Sui J H 2020 J. Mater. Sci. Technol. 59 189 Google Scholar
[45]	Saparamadu U, Tan X J, Sun J F, Ren Z S, Song S W, Singh D J, Shuai J, Jiang J, Ren Z F 2020 J. Mater. Chem. A 8 15760 Google Scholar
[46]	Wang X J, Tang M B, Chen H H, Yang X X, Zhao J T, Burkhardt U, Grin Y 2009 Appl. Phys. Lett. 94 092106 Google Scholar
[47]	Zhang H, Baitinger M, Tang M B, Man Z Y, Chen H H, Yang X X, Liu Y, Chen L, Grin Y, Zhao J T 2010 Dalton Trans. 39 1101 Google Scholar
[48]	Bhardwaj A, Misra D K 2014 RSC Adv. 4 34552 Google Scholar
[49]	Shuai J, Liu Z H, Kim H S, Wang Y, Mao J, He R, Sui J H, Ren Z F 2016 J. Mater. Chem. A 4 4312 Google Scholar
[50]	Zhu M, Wu Z, Liu Q, Zhu T J, Zhao X B, Huang B, Tao X, Xia S Q 2018 J. Mater. Chem. A 6 11773 Google Scholar
[51]	Yang C H, Guo K, Yang X X, Xing J J, Wang K, Luo J, Zhao J T 2019 ACS Appl. Energy Mater. 2 889 Google Scholar
[52]	Zhang X, Gu H S, Zhang Y, Guo L J, Yang J T, Luo S J, Lu X, Chen K S, Chai H X, Wang G Y, Zhang X, Zhou X Y 2019 Chem. Eng. J. 374 589 Google Scholar
[53]	Zhang J W, Song L R, Madsen G K H, Fischer K F F, Zhang W Q, Shi X, Iversen B B 2016 Nat. Commun. 7 10892 Google Scholar
[54]	Shuai J, Kim H S, Liu Z H, He R, Sui J H, Ren Z F 2016 Appl. Phys. Lett. 108 183901 Google Scholar
[55]	Gong J J, Hong A J, Shuai J, Li L, Yan Z B, Ren Z F, Liu J M 2016 Phys. Chem. Chem. Phys. 18 16566 Google Scholar
[56]	Pomrehn G S, Zevalkink A, Zeier W G, van de Walle A, Snyder G J 2014 Angew. Chem. Int. Ed. 53 3422 Google Scholar
[57]	Yu C, Zhu T J, Zhang S N, Zhao X B, He J, Su Z, Tritt T M 2008 J. Appl. Phys. 104 013705 Google Scholar
[58]	Zhang H, Zhao J T, Grin Y, Wang X J, Tang M B, Man Z Y, Chen H H, Yang X X 2008 J. Chem. Phys. 129 164713 Google Scholar
[59]	Zhang H, Fang L, Tang M B, Man Z Y, Chen H H, Yang X X, Baitinger M, Grin Y, Zhao J T 2010 J. Chem. Phys. 133 194701 Google Scholar
[60]	Guo K, Cao Q G, Feng X J, Tang M B, Chen H H, Guo X, Chen L, Grin Y, Zhao J T 2011 Eur. J. Inorg. Chem. 2011 4043 Google Scholar
[61]	Zevalkink A, Zeier W G, Cheng E, Snyder J, Fleurial J P, Bux S 2014 Chem. Mater. 26 5710 Google Scholar
[62]	Zhang J, Song L, Iversen B B 2019 npj Comput. Mater. 5 76 Google Scholar
[63]	Shuai J, Mao J, Song S W, Zhang Q Y, Chen G, Ren Z F 2017 Mater. Today Phys. 1 74 Google Scholar
[64]	Bhardwaj A, Chauhan N S, Misra D K 2015 J. Mater. Chem. A 3 10777 Google Scholar
[65]	Meng F C, Sun S S, Ma J L, Chronister C, He J, Li W 2020 Mater. Today Phys. 13 100217 Google Scholar
[66]	Shuai J, Wang Y M, Kim H S, Liu Z H, Sun J Y, Chen S, Sui J H, Ren Z F 2015 Acta Mater. 93 187 Google Scholar
[67]	Tamaki H, Sato H K, Kanno T 2016 Adv. Mater. 28 10182 Google Scholar
[68]	Kanno T, Tamaki H, Yoshiya M, Uchiyama H, Maki S, Takata M, Miyazaki Y 2021 Adv. Funct. Mater. 31 2008469 Google Scholar
[69]	Mao J, Shuai J, Song S W, Wu Y X, Dally R, Zhou J W, Liu Z H, Sun J F, Zhang Q Y, dela Cruz C, Wilson S, Pei Y Z, Singh D J, Chen G, Chu C W, Ren Z F 2017 Proc. Natl. Acad. Sci. U.S.A. 114 10548 Google Scholar
[70]	Imasato K, Fu C G, Pan Y, Wood M, Kuo J J, Felser C, Snyder G J 2020 Adv. Mater. 32 1908218 Google Scholar
[71]	Kuo J J, Kang S D, Imasato K, Tamaki H, Ohno S, Kanno T, Snyder G J 2018 Energy Environ. Sci. 11 429 Google Scholar
[72]	Ohno S, Imasato K, Anand S, Tamaki H, Kang S D, Gorai P, Sato H K, Toberer E S, Kanno T, Snyder G J 2018 Joule 2 141 Google Scholar
[73]	Kanno T, Tamaki H, Sato H K, Kang S D, Ohno S, Imasato K, Kuo J J, Snyder G J, Miyazaki Y 2018 Appl. Phys. Lett. 112 033903 Google Scholar
[74]	Shi X M, Sun C, Bu Z L, Zhang X Y, Wu Y X, Lin S Q, Li W, Faghaninia A, Jain A, Pei Y Z 2019 Adv. Sci. 6 1802286 Google Scholar
[75]	Shi X M, Zhao T T, Zhang X Y, Sun C, Chen Z W, Lin S Q, Li W, Gu H, Pei Y Z 2019 Adv. Mater. 31 1903387 Google Scholar
[76]	Bhardwaj A, Rajput A, Shukla A K, Pulikkotil J J, Srivastava A K, Dhar A, Gupta G, Auluck S, Misra D K, Budhani R C 2013 RSC Adv. 3 8504 Google Scholar
[77]	Shi X M, Wang X, Li W, Pei Y Z 2018 Small Methods 2 1800022 Google Scholar
[78]	Shu R, Zhou Y C, Wang Q, Han Z J, Zhu Y B, Liu Y, Chen Y X, Gu M, Xu W, Wang Y, Zhang W Q, Huang L, Liu W S 2019 Adv. Funct. Mater. 29 1807235 Google Scholar
[79]	Hu L P, Zhu T J, Liu X H, Zhao X B 2014 Adv. Funct. Mater. 24 5211 Google Scholar
[80]	Hu L, Wu H, Zhu T, Fu C, He J, Ying P, Zhao X 2015 Adv. Energy Mater. 5 1500411 Google Scholar
[81]	Fu T, Yue X, Wu H, Fu C, Zhu T, Liu X, Hu L, Ying P, He J, Zhao X 2016 J. Materiomics 2 141 Google Scholar
[82]	Imasato K, Kang S D, Snyder G J 2019 Energy Environ. Sci. 12 965 Google Scholar
[83]	Condron C L, Kauzlarich S M, Gascoin F, Snyder G J 2006 J. Solid State Chem. 179 2252 Google Scholar
[84]	Brechtel E, Cordier G, Schafer H 1979 Z. Naturforsch. , B:Chem. Sci. 34 1229 Google Scholar
[85]	Kim S J, Salvador J, Bilc D, Mahanti S D, Kanatzidis M G 2001 J. Am. Chem. Soc. 123 12704 Google Scholar
[86]	Bobev S, Thompson J D, Sarrao J L, Olmstead M M, Hope H, Kauzlarich S M 2004 Inorg. Chem. 43 5044 Google Scholar
[87]	Bux S K, Zevalkink A, Janka O, Uhl D, Kauzlarich S, Snyder J G, Fleurial J P 2014 J. Mater. Chem. A 2 215 Google Scholar
[88]	Kazem N, Zaikina J V, Ohno S, Snyder G J, Kauzlarich S M 2015 Chem. Mater. 27 7508 Google Scholar
[89]	Wu Z, Li J, Li X, Zhu M, Wu K C, Tao X T, Huang B B, Xia S Q 2016 Chem. Mater. 28 6917 Google Scholar
[90]	Zhang J, Liu Q, Liu K F, Tan W J, Liu X C, Xia S Q 2021 Inorg. Chem. 60 4026 Google Scholar
[91]	Liu X C, Wu Z, Xia S Q, Tao X T, Bobev S 2015 Inorg. Chem. 54 947 Google Scholar
[92]	Cooley J A, Promkhan P, Gangopadhyay S, Donadio D, Pickett W E, Ortiz B R, Toberer E S, Kauzlarich S M 2018 Chem. Mater. 30 484 Google Scholar
[93]	Xia S Q, Bobev S 2007 J. Am. Chem. Soc. 129 4049 Google Scholar
[94]	Wilson D K, Saparov B, Bobev S 2011 Z. Anorg. Allg. Chem. 637 2018 Google Scholar
[95]	Wang J, Xia S Q, Tao X T, Schäfer M C, Bobev S 2013 J. Solid State Chem. 205 116 Google Scholar
[96]	Yan J, Gorai P, Ortiz B, Miller S, Barnett S A, Mason T, Stevanović V, Toberer E S 2015 Energy Environ. Sci. 8 983 Google Scholar
[97]	Ovchinnikov A, Saparov B, Xia S Q, Bobev S 2017 Inorg. Chem. 56 12369 Google Scholar
[98]	Sun J F, Singh D J 2017 J. Mater. Chem. A 5 8499 Google Scholar
[99]	Ma H Q, Li G D, Zhang X L, Huang H J, Duan B, Zhai P C 2020 J. Alloys Compd. 843 155981 Google Scholar
[100]	Li Y, Chen J X, Cai P W, Wen Z H 2018 J. Mater. Chem. A 6 4948 Google Scholar
[101]	Yao H H, Chen C, Xue W H, Bai F X, Cao F, Lan Y C, Liu X J, Wang Y M, Singh D J, Lin X, Zhang Q 2021 Sci. Adv. 7 eabd6162 Google Scholar
[102]	Merlo F, Pani M, Fornasini M L 1990 J. Less-Common Met. 166 319 Google Scholar
[103]	Romaka V V, Falmbigl M, Grytsiv A, Rogl P 2014 J. Alloys Compd. 585 287 Google Scholar
[104]	Altayeb A, Sondezi B M, Tchoula Tchokonté M B, Strydom A M, Doyle T B, Kaczorowski D 2017 AIP Adv. 7 055714 Google Scholar
[105]	Chen S C, Lee J R, Syu K J, Lee W H 2014 Solid State Commun. 195 6 Google Scholar
[106]	Guo J, Zhu M, Li X, Tao X T, Xia S Q 2018 Inorg. Chem. Front. 5 1902 Google Scholar
[107]	May A F, Toberer E S, Snyder G J 2009 J. Appl. Phys. 106 013706 Google Scholar
[108]	Pan Y, Fan F R, Hong X, He B, Le C, Schnelle W, He Y, Imasato K, Borrmann H, Hess C, Buechner B, Sun Y, Fu C, Snyder G J, Felser C 2020 Adv. Mater. 33 2003168 Google Scholar
[109]	Liu Q, Liu X C, Liu K F, Zhang J, Xia S Q 2020 J. Alloys Compd. 847 156551 Google Scholar
[110]	Balvanz A, Qu J X, Baranets S, Ertekin E, Gorai P, Bobev S 2020 Chem. Mater. 32 10697 Google Scholar

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