搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

平面异质结有机-无机杂化钙钛矿太阳电池研究进展

王福芝 谭占鳌 戴松元 李永舫

引用本文:
Citation:

平面异质结有机-无机杂化钙钛矿太阳电池研究进展

王福芝, 谭占鳌, 戴松元, 李永舫

Recent advances in planar heterojunction organic-inorganic hybrid perovskite solar cells

Wang Fu-Zhi, Tan Zhan-Ao, Dai Song-Yuan, Li Yong-Fang
PDF
导出引用
  • 高效低成本太阳电池的研发是太阳能光伏技术大规模推广应用的关键. 近年来兴起的有机- 无机杂化钙钛矿(以下简称钙钛矿)太阳电池因具有光电能量转换效率高、制备工艺简单等优点, 引起了学术界和产业界的广泛关注, 具有广阔的发展前景. 其中平面异质结钙钛矿太阳电池因具有结构简单, 可低温制备等诸多优点, 成为目前研究的一个重要方向. 平面异质结钙钛矿太阳电池分为n-i-p型和p-i-n型两种结构. 其中钙钛矿分别与电子传输层和空穴传输层形成两个界面, 在这两个界面上实现电子和空穴的快速分离. 电子传输层和空穴传输层分别为电子和空穴提供了独立的输运通道. 平面异质结结构有利于钙钛矿太阳电池中电子和空穴的分离、传输和收集. 此外, 该结构不需要高温烧结的多孔结构氧化物骨架, 扩大了电子和空穴传输材料的选择范围. 可以根据钙钛矿材料的能带分布及载流子传输特性, 来选择能级和载流子传输速率更为匹配的传输材料. 本文对钙钛矿的材料特性, 平面异质结结构的由来及发展进行了简要的概述. 其中重点介绍了平面异质结钙钛矿太阳电池的结构特征、工作机理、钙钛矿/电荷传输层的界面特性, 以及电池性能的优化, 包括钙钛矿薄膜制备、空穴和电子传输层的优化等. 最后对钙钛矿电池的发展前景及存在问题进行了阐述, 为今后高效、稳定钙钛矿太阳电池的研究提供参考.
    The development of highly efficient and low-cost solar cells is the key to large-scale application of solar photovoltaic technology. In recent years, the solution-processed organic-inorganic perovskite solar cells attracted considerable attention because of their advantages of high energy conversion efficiency, low cost, and ease of processing. The ambipolar semiconducting characteristic of perovskite enables the construction of planar heterojunction architecture to be possible in perovskite-based solar cells. This kind of architecture avoids the use of mesoporous metal oxide film, which simplifies the processing route and makes it easier to fabricate flexible and tandem perovskite-based solar cells. Planar heterojunction perovskite solar cells can be divided into n-i-p type and p-i-n type according to the charge flow direction. Two interfaces are formed between perovskite film and hole/electron transport layer, where efficient charge separation can be realized. Hole and electron transport layers can form separated continuous paths for the transport of holes and electrons, thus beneficial to improving exciton separation, charge transportation, and collection efficiency. In addition, this planar architecture avoids the use of high temperature sintered mesoporous metal oxide framework; this is beneficial to expanding the choice of the charge transport materials. In this paper, we review the recent progress on the planar heterojunction perovskite solar cells. First, we introduce the material properties of perovskite, the evolution of device architecture, and the working principle of p-i-n type and n-i-p type planar heterojunction perovskite solar cells. Then, we review the recent progress and optimization of planar heterojunction perovskite solar cells from every aspect of perovskite preparation and the selection of electron/hole transport materials. Finally, we would like to give a perspective view on and address the concerns about perovskite solar cells.
    • 基金项目: 国家自然科学基金(批准号: 51173040, 91023039, 51303052)、高等学校博士学科点专项科研基金(批准号: 20130036110007)、新世纪优秀人才支持计划(批准号: NCET-12-0848)、北京高等学校青年英才计划项目(批准号: YETP0713)和中央高校基本科研业务费专项资金(批准号: 13ZD11, 2014ZD11, 2014MS35, 2014ZZD07)资助的课题.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51173040, 91023039, 51303052), the Specialized Research Fund for the Doctoral Program (Grant No. 20130036110007), the Program for New Century Excellent Talents in University of China (Grant No. NCET-12-0848), Beijing Higher Education Young Elite Program (Grant No. YETP0713), and the Fundamental Research Funds for the Central Universities, China (Grant Nos. 13ZD11, 2014ZD11, 2014MS35, 2014ZZD07).
    [1]

    Yella A, Lee H W, Tsao H N, Yi C, Chandiran A K, Nazeeruddin M K, Diau E W, Yeh C Y, Zakeeruddin S M, Grätzel M 2011 Science 334 629

    [2]

    Mathew S, Yella A, Gao P, Humphry-Baker R, CurchodBasile F E, Ashari-Astani N, Tavernelli I, Rothlisberger U, NazeeruddinMd K, Grätzel M 2014 Nat. Chem. 6 242

    [3]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [4]

    Burschka J, Pellet N, Moon S J, Humphry-Baker R, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316

    [5]

    Liu M, Johnston M B, Snaith H J 2013 Nature 501 395

    [6]

    Zhou H, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z, You J, Liu Y, Yang Y 2014 Science 345 542

    [7]

    Albert V A, Barbazuk W B, dePamphilis C W, Der J P, Leebens-Mack J, Ma H, Palmer J D, Rounsley S, Sankoff D, Schuster S C, Soltis D E, Soltis P S, Wessler S R, Wing R A, Albert V A, Ammiraju J S, Barbazuk W B, Chamala S, Chanderbali A S, dePamphilis C W, Der J P, Determann R, Leebens-Mack J, Ma H, Ralph P, Rounsley S, Schuster S C, Soltis D E, Soltis P S, Talag J, Tomsho L, Walts B, Wanke S, Wing R A, Albert V A, Barbazuk W B, Chamala S, Chanderbali A S, Chang T H, Determann R, Lan T, Soltis D E, Soltis P S, Arikit S, Axtell M J, Ayyampalayam S, Barbazuk W B, Burnette J M 3rd, Chamala S, De Paoli E, dePamphilis C W, Der J P, Estill J C, Farrell N P, Harkess A, Jiao Y, Leebens-Mack J, Liu K, Mei W, Meyers B C, Shahid S, Wafula E, Walts B, Wessler S R, Zhai J, Zhang X, Albert V A, Carretero-Paulet L, dePamphilis C W, Der J P, Jiao Y, Leebens-Mack J, Lyons E, Sankoff D, Tang H, Wafula E, Zheng C, Albert V A, Altman N S, Barbazuk W B, Carretero-Paulet L, dePamphilis C W, Der J P, Estill J C, Jiao Y, Leebens-Mack J, Liu K, Mei W, Wafula E, Altman NS, Arikit S, Axtell M J, Chamala S, Chanderbali A S, Chen F, Chen J Q, Chiang V, De Paoli E, dePamphilis C W, Der J P, Determann R, Fogliani B, Guo C, Harholt J, Harkess A, Job C, Job D, Kim S, Kong H, Leebens-Mack J, Li G, Li L, Liu J, Ma H, Meyers B C, Park J, Qi X, Rajjou L, Burtet-Sarramegna V, Sederoff R, Shahid S, Soltis D E, Soltis P S, Sun Y H, Ulvskov P, Villegente M, Xue J Y, Yeh T F, Yu X, Zhai J, Acosta J J, Albert VA, Barbazuk W B, Bruenn R A, Chamala S, de Kochko A, dePamphilis C W, Der JP, Herrera-Estrella LR, Ibarra-Laclette E, Kirst M, Leebens-Mack J, Pissis S P, Poncet V, Schuster S C, Soltis D E, Soltis P S, Tomsho L 2013 Science 342 1438

    [8]

    Kim H S, Im S H, Park N G 2014 J. Phys. Chem. C 118 5615

    [9]

    Sun S, Salim T, Mathews N, Duchamp M, Boothroyd C, Xing G, Sum T C, Lam Y M 2014 Energ. Environ. Sci. 7 399

    [10]

    Tanaka K, Takahashi T, Ban T, Kondo T, Uchida K, Miura N 2003 Solid State Commun. 127 619

    [11]

    Stoumpos C C, Malliakas C D, Kanatzidis M G 2013 Inorg. Chem. 52 9019

    [12]

    Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J P, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341

    [13]

    Baikie T, Fang Y, Kadro J M, Schreyer M, Wei F, Mhaisalkar S G, Graetzel M, White T J 2013 J. Mater. Chem. A 1 5628

    [14]

    Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J 2012 Science 338 643

    [15]

    Edri E, Kirmayer S, Cahen D, Hodes G 2013 J. Phys. Chem. Lett. 4 897

    [16]

    Wojciechowski K, Saliba M, Leijtens T, Abate A, Snaith H J 2014 Energ. Environ. Sci. 7 1142

    [17]

    Xiao M, Huang F, Huang W, Dkhissi Y, Zhu Y, Etheridge J, Gray-Weale A, Bach U, Cheng Y B, Spiccia L 2014 Angew. Chem. Int. Ed. Engl. 53 9898

    [18]

    Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088

    [19]

    Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E 2012 Sci. Rep. 2 591

    [20]

    Chen H, Pan X, Liu W, Cai M, Kou D, Huo Z, Fang X, Dai S 2013 Chem. Commun. 49 7277

    [21]

    Ball J M, Lee M M, Hey A, Snaith H J 2013 Energ. Environ. Sci. 6 1739

    [22]

    Kim H S, Mora-Sero I, Gonzalez-Pedro V, Fabregat-Santiago F, Juarez-Perez E J, Park N G, Bisquert J 2013 Nat. Commun. 4 2242

    [23]

    Bi D, Moon S-J, Häggman L, Boschloo G, Yang L, Johansson E M J, Nazeeruddin M K, Grätzel M, Hagfeldt A 2013 RSC Advances 3 18762

    [24]

    Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grätzel M, Han H 2014 Science 345 295

    [25]

    Heo J H, Im S H, Noh J H, Mandal T N, Lim C S, Chang J A, Lee Y H, Kim H j, Sarkar A, NazeeruddinMd K, Grätzel M, Seok S I 2013 Na.t Photon. 7 486

    [26]

    Etgar L, Gao P, Xue Z, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K, Grätzel M 2012 J. Am. Chem. Soc. 134 17396

    [27]

    Jeng J Y, Chiang Y F, Lee M H, Peng S R, Guo T F, Chen P, Wen T C 2013 Adv. Mater. 25 3727

    [28]

    Zhang H, Azimi H, Hou Y, Ameri T, Przybilla T, Spiecker E, Kraft M, Scherf U, Brabec C J 2014 Chem. Mater. 26 5190

    [29]

    Malinkiewicz O, Yella A, Lee Y H, Espallargas G M, Graetzel M, Nazeeruddin M K, Bolink H J 2014 Nat. Photon. 8 128

    [30]

    Kim J, Kim G, Kim T K, Kwon S, Back H, Lee J, Lee S H, Kang H, Lee K 2014 J. Mater. Chem. A 2 17291

    [31]

    Seo J, Park S, Chan Kim Y, Jeon N J, Noh J H, Yoon S C, Seok S I 2014 Energ. Environ. Sci. 7 2642

    [32]

    Chiang C H, Tseng Z L, Wu C G 2014 J. Mater. Chem. A 2 15897

    [33]

    Wang Q, Shao Y, Dong Q, Xiao Z, Yuan Y, Huang J 2014 Energ. Environ. Sci. 7 2359

    [34]

    Xiao Z, Bi C, Shao Y, Dong Q, Wang Q, Yuan Y, Wang C, Gao Y, Huang J 2014 Energ. Environ. Sci. 7 2619

    [35]

    Singh T B, Marjanovi?N, Matt G J, Gnes S, Sariciftci N S, Montaigne Ramil A, Andreev A, Sitter H, Schwödiauer R, Bauer S 2005 Org. Electron. 6 105

    [36]

    Xing G, Mathews N, Sun S, Lim S S, Lam Y M, Grätzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [37]

    Ponseca C S, Savenije T J, Abdellah M, Zheng K, Yartsev A, Pascher T, Harlang T, Chabera P, Pullerits T, Stepanov A, Wolf J P, Sundström V 2014 J. Am. Chem. Soc. 136 5189

    [38]

    Liang P W, Chueh C C, Xin X K, Zuo F, Williams S T, Liao C Y, Jen A K Y 2014 Adv. Energy. Mater. DOI:101002aenm201400960

    [39]

    Conings B, Baeten L, De Dobbelaere C, D'Haen J, Manca J, Boyen H G 2013 Adv. Mater. 26 2041

    [40]

    Jeng J Y, Chen K C, Chiang T Y, Lin P Y, Tsai T D, Chang Y C, Guo T F, Chen P, Wen T C, Hsu Y J 2014 Adv. Mater. 26 4107

    [41]

    Docampo P, Ball J M, Darwich M, Eperon G E, Snaith H J 2013 Nat. Commun. 4 2761

    [42]

    Eperon G E, Burlakov V M, Docampo P, Goriely A, Snaith H J 2014 Adv. Funct. Mater. 24 151

    [43]

    Choi J J, Yang X, Norman Z M, Billinge S J L, Owen J S 2013 Nano. Lett. 14 127

    [44]

    Wang K C, Jeng J Y, Shen P S, Chang Y C, Diau E W, Tsai C H, Chao T Y, Hsu H C, Lin P Y, Chen P, Guo T F, Wen T C 2014 Sci. Rep. 4 4756

    [45]

    Chen Q, Zhou H, Hong Z, Luo S, Duan H S, Wang H H, Liu Y, Li G, Yang Y 2014 J. Am. Chem. Soc. 136 622

    [46]

    Wu Z, Bai S, Xiang J, Yuan Z, Yang Y, Cui W, Gao X, Liu Z, Jin Y, Sun B 2014 Nanoscale 6 10505

    [47]

    Barrows A T, Pearson A J, Kwak C K, Dunbar A D F, Buckley A R, Lidzey D G 2014 Energ. Environ. Sci. 7 2944

    [48]

    Hsu H-L, Chen C, Chang J-Y, Yu Y-Y, Shen Y-K 2014 Nanoscale 6 10281

    [49]

    Bi D, Boschloo G, Schwarzmuller S, Yang L, Johansson E M, Hagfeldt A 2013 Nanoscale 5 11686

    [50]

    You J, Hong Z, Yang Y, Chen Q, Cai M, Song T B, Chen C C, Lu S, Liu Y, Zhou H 2014 ACS Nano 8 1674

    [51]

    Abrusci A, Stranks S D, Docampo P, Yip H L, Jen A K, Snaith H J 2013 Nano. Lett. 13 3124

    [52]

    Liang P W, Liao C Y, Chueh C C, Zuo F, Williams S T, Xin X K, Lin J, Jen A K 2014 Adv. Mater. 26 3748

    [53]

    Zhao Y, Zhu K 2014 J. Phys. Chem. C 118 9412

    [54]

    Grätzel M 2014 Nat. Mater. 13 838

    [55]

    Wehrenfennig C, Eperon G E, Johnston M B, Snaith H J, Herz L M 2014 Adv. Mater. 26 1584

    [56]

    Kim H B, Choi H, Jeong J, Kim S, Walker B, Song S, Kim J Y 2014 Nanoscale 6 6679

    [57]

    Jeon N J, Noh J H, Kim Y C, Yang W S, Ryu S, Seok S I 2014 Nat. Mater. 13 897

    [58]

    Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, Toyoda T, Yoshino K, Pandey S S, Ma T, Hayase S 2014 J. Phys. Chem. Lett. 5 1004

    [59]

    Hao F, Stoumpos C C, Chang R P H, Kanatzidis M G 2014 J. Am. Chem. Soc. 136 8094

    [60]

    Hao F, Stoumpos C C, Cao D H, Chang R P H, Kanatzidis M G 2014 Nat. Photon. 8 489

    [61]

    Noel N K, Stranks S D, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A A, Sadhanala A, Eperon G E, Pathak S K, Johnston M B, Petrozza A, Herz L M, Snaith H J 2014 Energ. Environ. Sci. 7 3061

    [62]

    Zuo F, Williams S T, Liang P W, Chueh C C, Liao C Y, Jen A K 2014 Adv. Mater. 26 6454

    [63]

    Hu H, Wang D, Zhou Y, Zhang J, Lv S, Pang S, Chen X, Liu Z, Padture N P, Cui G 2014 RSC Advances 4 28964

    [64]

    Wang K C, Shen P S, Li M H, Chen S, Lin M W, Chen P, Guo T F 2014 ACS Appl. Mater. Interfaces 6 11851

    [65]

    Chen Q, Zhou H, Hong Z, Luo S, Duan H S, Wang H-H, Liu Y, Li G, Yang Y 2013 J. Am. Chem. Soc. 136 622

    [66]

    O'Malley K M, Li C Z, Yip H L, Jen A K Y 2012 Adv. Energy. Mater. 2 82

    [67]

    Lim K G, Kim H B, Jeong J, Kim H, Kim J Y, Lee T W 2014 Adv. Mater. 26 6461

    [68]

    Yip H L, Jen A K Y 2012 Energ. Environ. Sci. 5 5994

    [69]

    Chen S, Manders J R, Tsang S W, So F 2012 J. Mater. Chem. A 22 24202

    [70]

    Meyer J, Hamwi S, Kroger M, Kowalsky W, Riedl T, Kahn A 2012 Adv. Mater. 24 5408

    [71]

    Wang F Z, Sun G, Li C, Liu J Y, Hu S Q, Zheng H, Tan Z A, Li Y F 2014 ACS Appl. Mater. Interfaces 6 9458

    [72]

    Liu D, Kelly T L 2013 Nat. Photon. 8 133

    [73]

    Wu Y, Islam A, Yang X, Qin C, Liu J, Zhang K, Peng W, Han L 2014 Energ. Environ. Sci. 7 2934

    [74]

    He Y J, Chen H Y, Hou J H, Li Y F 2010 J. Am. Chem. Soc. 132 1377

  • [1]

    Yella A, Lee H W, Tsao H N, Yi C, Chandiran A K, Nazeeruddin M K, Diau E W, Yeh C Y, Zakeeruddin S M, Grätzel M 2011 Science 334 629

    [2]

    Mathew S, Yella A, Gao P, Humphry-Baker R, CurchodBasile F E, Ashari-Astani N, Tavernelli I, Rothlisberger U, NazeeruddinMd K, Grätzel M 2014 Nat. Chem. 6 242

    [3]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [4]

    Burschka J, Pellet N, Moon S J, Humphry-Baker R, Gao P, Nazeeruddin M K, Grätzel M 2013 Nature 499 316

    [5]

    Liu M, Johnston M B, Snaith H J 2013 Nature 501 395

    [6]

    Zhou H, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z, You J, Liu Y, Yang Y 2014 Science 345 542

    [7]

    Albert V A, Barbazuk W B, dePamphilis C W, Der J P, Leebens-Mack J, Ma H, Palmer J D, Rounsley S, Sankoff D, Schuster S C, Soltis D E, Soltis P S, Wessler S R, Wing R A, Albert V A, Ammiraju J S, Barbazuk W B, Chamala S, Chanderbali A S, dePamphilis C W, Der J P, Determann R, Leebens-Mack J, Ma H, Ralph P, Rounsley S, Schuster S C, Soltis D E, Soltis P S, Talag J, Tomsho L, Walts B, Wanke S, Wing R A, Albert V A, Barbazuk W B, Chamala S, Chanderbali A S, Chang T H, Determann R, Lan T, Soltis D E, Soltis P S, Arikit S, Axtell M J, Ayyampalayam S, Barbazuk W B, Burnette J M 3rd, Chamala S, De Paoli E, dePamphilis C W, Der J P, Estill J C, Farrell N P, Harkess A, Jiao Y, Leebens-Mack J, Liu K, Mei W, Meyers B C, Shahid S, Wafula E, Walts B, Wessler S R, Zhai J, Zhang X, Albert V A, Carretero-Paulet L, dePamphilis C W, Der J P, Jiao Y, Leebens-Mack J, Lyons E, Sankoff D, Tang H, Wafula E, Zheng C, Albert V A, Altman N S, Barbazuk W B, Carretero-Paulet L, dePamphilis C W, Der J P, Estill J C, Jiao Y, Leebens-Mack J, Liu K, Mei W, Wafula E, Altman NS, Arikit S, Axtell M J, Chamala S, Chanderbali A S, Chen F, Chen J Q, Chiang V, De Paoli E, dePamphilis C W, Der J P, Determann R, Fogliani B, Guo C, Harholt J, Harkess A, Job C, Job D, Kim S, Kong H, Leebens-Mack J, Li G, Li L, Liu J, Ma H, Meyers B C, Park J, Qi X, Rajjou L, Burtet-Sarramegna V, Sederoff R, Shahid S, Soltis D E, Soltis P S, Sun Y H, Ulvskov P, Villegente M, Xue J Y, Yeh T F, Yu X, Zhai J, Acosta J J, Albert VA, Barbazuk W B, Bruenn R A, Chamala S, de Kochko A, dePamphilis C W, Der JP, Herrera-Estrella LR, Ibarra-Laclette E, Kirst M, Leebens-Mack J, Pissis S P, Poncet V, Schuster S C, Soltis D E, Soltis P S, Tomsho L 2013 Science 342 1438

    [8]

    Kim H S, Im S H, Park N G 2014 J. Phys. Chem. C 118 5615

    [9]

    Sun S, Salim T, Mathews N, Duchamp M, Boothroyd C, Xing G, Sum T C, Lam Y M 2014 Energ. Environ. Sci. 7 399

    [10]

    Tanaka K, Takahashi T, Ban T, Kondo T, Uchida K, Miura N 2003 Solid State Commun. 127 619

    [11]

    Stoumpos C C, Malliakas C D, Kanatzidis M G 2013 Inorg. Chem. 52 9019

    [12]

    Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J P, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341

    [13]

    Baikie T, Fang Y, Kadro J M, Schreyer M, Wei F, Mhaisalkar S G, Graetzel M, White T J 2013 J. Mater. Chem. A 1 5628

    [14]

    Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J 2012 Science 338 643

    [15]

    Edri E, Kirmayer S, Cahen D, Hodes G 2013 J. Phys. Chem. Lett. 4 897

    [16]

    Wojciechowski K, Saliba M, Leijtens T, Abate A, Snaith H J 2014 Energ. Environ. Sci. 7 1142

    [17]

    Xiao M, Huang F, Huang W, Dkhissi Y, Zhu Y, Etheridge J, Gray-Weale A, Bach U, Cheng Y B, Spiccia L 2014 Angew. Chem. Int. Ed. Engl. 53 9898

    [18]

    Im J H, Lee C R, Lee J W, Park S W, Park N G 2011 Nanoscale 3 4088

    [19]

    Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E 2012 Sci. Rep. 2 591

    [20]

    Chen H, Pan X, Liu W, Cai M, Kou D, Huo Z, Fang X, Dai S 2013 Chem. Commun. 49 7277

    [21]

    Ball J M, Lee M M, Hey A, Snaith H J 2013 Energ. Environ. Sci. 6 1739

    [22]

    Kim H S, Mora-Sero I, Gonzalez-Pedro V, Fabregat-Santiago F, Juarez-Perez E J, Park N G, Bisquert J 2013 Nat. Commun. 4 2242

    [23]

    Bi D, Moon S-J, Häggman L, Boschloo G, Yang L, Johansson E M J, Nazeeruddin M K, Grätzel M, Hagfeldt A 2013 RSC Advances 3 18762

    [24]

    Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grätzel M, Han H 2014 Science 345 295

    [25]

    Heo J H, Im S H, Noh J H, Mandal T N, Lim C S, Chang J A, Lee Y H, Kim H j, Sarkar A, NazeeruddinMd K, Grätzel M, Seok S I 2013 Na.t Photon. 7 486

    [26]

    Etgar L, Gao P, Xue Z, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K, Grätzel M 2012 J. Am. Chem. Soc. 134 17396

    [27]

    Jeng J Y, Chiang Y F, Lee M H, Peng S R, Guo T F, Chen P, Wen T C 2013 Adv. Mater. 25 3727

    [28]

    Zhang H, Azimi H, Hou Y, Ameri T, Przybilla T, Spiecker E, Kraft M, Scherf U, Brabec C J 2014 Chem. Mater. 26 5190

    [29]

    Malinkiewicz O, Yella A, Lee Y H, Espallargas G M, Graetzel M, Nazeeruddin M K, Bolink H J 2014 Nat. Photon. 8 128

    [30]

    Kim J, Kim G, Kim T K, Kwon S, Back H, Lee J, Lee S H, Kang H, Lee K 2014 J. Mater. Chem. A 2 17291

    [31]

    Seo J, Park S, Chan Kim Y, Jeon N J, Noh J H, Yoon S C, Seok S I 2014 Energ. Environ. Sci. 7 2642

    [32]

    Chiang C H, Tseng Z L, Wu C G 2014 J. Mater. Chem. A 2 15897

    [33]

    Wang Q, Shao Y, Dong Q, Xiao Z, Yuan Y, Huang J 2014 Energ. Environ. Sci. 7 2359

    [34]

    Xiao Z, Bi C, Shao Y, Dong Q, Wang Q, Yuan Y, Wang C, Gao Y, Huang J 2014 Energ. Environ. Sci. 7 2619

    [35]

    Singh T B, Marjanovi?N, Matt G J, Gnes S, Sariciftci N S, Montaigne Ramil A, Andreev A, Sitter H, Schwödiauer R, Bauer S 2005 Org. Electron. 6 105

    [36]

    Xing G, Mathews N, Sun S, Lim S S, Lam Y M, Grätzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [37]

    Ponseca C S, Savenije T J, Abdellah M, Zheng K, Yartsev A, Pascher T, Harlang T, Chabera P, Pullerits T, Stepanov A, Wolf J P, Sundström V 2014 J. Am. Chem. Soc. 136 5189

    [38]

    Liang P W, Chueh C C, Xin X K, Zuo F, Williams S T, Liao C Y, Jen A K Y 2014 Adv. Energy. Mater. DOI:101002aenm201400960

    [39]

    Conings B, Baeten L, De Dobbelaere C, D'Haen J, Manca J, Boyen H G 2013 Adv. Mater. 26 2041

    [40]

    Jeng J Y, Chen K C, Chiang T Y, Lin P Y, Tsai T D, Chang Y C, Guo T F, Chen P, Wen T C, Hsu Y J 2014 Adv. Mater. 26 4107

    [41]

    Docampo P, Ball J M, Darwich M, Eperon G E, Snaith H J 2013 Nat. Commun. 4 2761

    [42]

    Eperon G E, Burlakov V M, Docampo P, Goriely A, Snaith H J 2014 Adv. Funct. Mater. 24 151

    [43]

    Choi J J, Yang X, Norman Z M, Billinge S J L, Owen J S 2013 Nano. Lett. 14 127

    [44]

    Wang K C, Jeng J Y, Shen P S, Chang Y C, Diau E W, Tsai C H, Chao T Y, Hsu H C, Lin P Y, Chen P, Guo T F, Wen T C 2014 Sci. Rep. 4 4756

    [45]

    Chen Q, Zhou H, Hong Z, Luo S, Duan H S, Wang H H, Liu Y, Li G, Yang Y 2014 J. Am. Chem. Soc. 136 622

    [46]

    Wu Z, Bai S, Xiang J, Yuan Z, Yang Y, Cui W, Gao X, Liu Z, Jin Y, Sun B 2014 Nanoscale 6 10505

    [47]

    Barrows A T, Pearson A J, Kwak C K, Dunbar A D F, Buckley A R, Lidzey D G 2014 Energ. Environ. Sci. 7 2944

    [48]

    Hsu H-L, Chen C, Chang J-Y, Yu Y-Y, Shen Y-K 2014 Nanoscale 6 10281

    [49]

    Bi D, Boschloo G, Schwarzmuller S, Yang L, Johansson E M, Hagfeldt A 2013 Nanoscale 5 11686

    [50]

    You J, Hong Z, Yang Y, Chen Q, Cai M, Song T B, Chen C C, Lu S, Liu Y, Zhou H 2014 ACS Nano 8 1674

    [51]

    Abrusci A, Stranks S D, Docampo P, Yip H L, Jen A K, Snaith H J 2013 Nano. Lett. 13 3124

    [52]

    Liang P W, Liao C Y, Chueh C C, Zuo F, Williams S T, Xin X K, Lin J, Jen A K 2014 Adv. Mater. 26 3748

    [53]

    Zhao Y, Zhu K 2014 J. Phys. Chem. C 118 9412

    [54]

    Grätzel M 2014 Nat. Mater. 13 838

    [55]

    Wehrenfennig C, Eperon G E, Johnston M B, Snaith H J, Herz L M 2014 Adv. Mater. 26 1584

    [56]

    Kim H B, Choi H, Jeong J, Kim S, Walker B, Song S, Kim J Y 2014 Nanoscale 6 6679

    [57]

    Jeon N J, Noh J H, Kim Y C, Yang W S, Ryu S, Seok S I 2014 Nat. Mater. 13 897

    [58]

    Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, Toyoda T, Yoshino K, Pandey S S, Ma T, Hayase S 2014 J. Phys. Chem. Lett. 5 1004

    [59]

    Hao F, Stoumpos C C, Chang R P H, Kanatzidis M G 2014 J. Am. Chem. Soc. 136 8094

    [60]

    Hao F, Stoumpos C C, Cao D H, Chang R P H, Kanatzidis M G 2014 Nat. Photon. 8 489

    [61]

    Noel N K, Stranks S D, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A A, Sadhanala A, Eperon G E, Pathak S K, Johnston M B, Petrozza A, Herz L M, Snaith H J 2014 Energ. Environ. Sci. 7 3061

    [62]

    Zuo F, Williams S T, Liang P W, Chueh C C, Liao C Y, Jen A K 2014 Adv. Mater. 26 6454

    [63]

    Hu H, Wang D, Zhou Y, Zhang J, Lv S, Pang S, Chen X, Liu Z, Padture N P, Cui G 2014 RSC Advances 4 28964

    [64]

    Wang K C, Shen P S, Li M H, Chen S, Lin M W, Chen P, Guo T F 2014 ACS Appl. Mater. Interfaces 6 11851

    [65]

    Chen Q, Zhou H, Hong Z, Luo S, Duan H S, Wang H-H, Liu Y, Li G, Yang Y 2013 J. Am. Chem. Soc. 136 622

    [66]

    O'Malley K M, Li C Z, Yip H L, Jen A K Y 2012 Adv. Energy. Mater. 2 82

    [67]

    Lim K G, Kim H B, Jeong J, Kim H, Kim J Y, Lee T W 2014 Adv. Mater. 26 6461

    [68]

    Yip H L, Jen A K Y 2012 Energ. Environ. Sci. 5 5994

    [69]

    Chen S, Manders J R, Tsang S W, So F 2012 J. Mater. Chem. A 22 24202

    [70]

    Meyer J, Hamwi S, Kroger M, Kowalsky W, Riedl T, Kahn A 2012 Adv. Mater. 24 5408

    [71]

    Wang F Z, Sun G, Li C, Liu J Y, Hu S Q, Zheng H, Tan Z A, Li Y F 2014 ACS Appl. Mater. Interfaces 6 9458

    [72]

    Liu D, Kelly T L 2013 Nat. Photon. 8 133

    [73]

    Wu Y, Islam A, Yang X, Qin C, Liu J, Zhang K, Peng W, Han L 2014 Energ. Environ. Sci. 7 2934

    [74]

    He Y J, Chen H Y, Hou J H, Li Y F 2010 J. Am. Chem. Soc. 132 1377

  • [1] 王其, 延玲玲, 陈兵兵, 李仁杰, 王三龙, 王鹏阳, 黄茜, 许盛之, 侯国付, 陈新亮, 李跃龙, 丁毅, 张德坤, 王广才, 赵颖, 张晓丹. 钙钛矿/硅异质结叠层太阳电池: 光学模拟的研究进展. 物理学报, 2021, 70(5): 057802. doi: 10.7498/aps.70.20201585
    [2] 卢辉东, 韩红静, 刘杰. FA1–xCsx PbI3–y Bry钙钛矿材料优化及太阳电池性能计算. 物理学报, 2021, 70(3): 036301. doi: 10.7498/aps.70.20201387
    [3] 卢辉东, 韩红静, 刘杰. 有机铅碘钙钛矿太阳电池结构优化及光电性能计算. 物理学报, 2021, 70(16): 168802. doi: 10.7498/aps.70.20210134
    [4] 徐婷, 王子帅, 李炫华, 沙威. 基于等效电路模型的钙钛矿太阳电池效率损失机理分析. 物理学报, 2021, 70(9): 098801. doi: 10.7498/aps.70.20201975
    [5] 李燕, 贺红, 党威武, 陈雪莲, 孙璨, 郑嘉璐. 钙钛矿太阳电池中各功能层的光辐照稳定性研究进展. 物理学报, 2021, 70(9): 098402. doi: 10.7498/aps.70.20201762
    [6] 甘永进, 蒋曲博, 覃斌毅, 毕雪光, 李清流. 锡基钙钛矿太阳能电池载流子传输层的探讨. 物理学报, 2021, 70(3): 038801. doi: 10.7498/aps.70.20201219
    [7] 梁晓娟, 曹宇, 蔡宏琨, 苏健, 倪牮, 李娟, 张建军. 肖特基钙钛矿太阳电池结构设计与优化. 物理学报, 2020, 69(5): 057901. doi: 10.7498/aps.69.20191891
    [8] 陈永亮, 唐亚文, 陈沛润, 张力, 刘琪, 赵颖, 黄茜, 张晓丹. 钙钛矿太阳电池中的缓冲层研究进展. 物理学报, 2020, 69(13): 138401. doi: 10.7498/aps.69.20200543
    [9] 吴步军, 林东旭, 李征, 程振平, 李新, 陈科, 时婷婷, 谢伟广, 刘彭义. 钙钛矿薄膜气相制备的晶粒尺寸优化及高效光伏转换. 物理学报, 2019, 68(7): 078801. doi: 10.7498/aps.68.20182221
    [10] 陈俊帆, 任慧志, 侯福华, 周忠信, 任千尚, 张德坤, 魏长春, 张晓丹, 侯国付, 赵颖. 钙钛矿/硅叠层太阳电池中平面a-Si:H/c-Si异质结底电池的钝化优化及性能提高. 物理学报, 2019, 68(2): 028101. doi: 10.7498/aps.68.20181759
    [11] 李海涛, 江亚晓, 涂丽敏, 李少华, 潘玲, 李文标, 杨仕娥, 陈永生. 退火温度对电子束蒸发沉积Cu2O薄膜性能的影响. 物理学报, 2018, 67(5): 053301. doi: 10.7498/aps.67.20172463
    [12] 曹宇, 祝新运, 陈翰博, 王长刚, 张鑫童, 侯秉东, 申明仁, 周静. 硒化锑薄膜太阳电池的模拟与结构优化研究. 物理学报, 2018, 67(24): 247301. doi: 10.7498/aps.67.20181745
    [13] 杜相, 陈思, 林东旭, 谢方艳, 陈建, 谢伟广, 刘彭义. 十二烷二酸修饰TiO2电子传输层改善钙钛矿太阳电池的电流特性. 物理学报, 2018, 67(9): 098801. doi: 10.7498/aps.67.20172779
    [14] 李少华, 李海涛, 江亚晓, 涂丽敏, 李文标, 潘玲, 杨仕娥, 陈永生. 高效平面异质结有机-无机杂化钙钛矿太阳电池的质量管理. 物理学报, 2018, 67(15): 158801. doi: 10.7498/aps.67.20172600
    [15] 刘毅, 徐征, 赵谡玲, 乔泊, 李杨, 秦梓伦, 朱友勤. 双添加剂处理电子传输层富勒烯衍生物[6,6]-苯基-C61丁酸甲酯对钙钛矿太阳能电池性能的影响. 物理学报, 2017, 66(11): 118801. doi: 10.7498/aps.66.118801
    [16] 王军霞, 毕卓能, 梁柱荣, 徐雪青. 新型碳材料在钙钛矿太阳电池中的应用研究进展. 物理学报, 2016, 65(5): 058801. doi: 10.7498/aps.65.058801
    [17] 刘博智, 黎瑞锋, 宋凌云, 胡炼, 张兵坡, 陈勇跃, 吴剑钟, 毕刚, 王淼, 吴惠桢. 氧化锌锡作为电子传输层的量子点发光二极管. 物理学报, 2013, 62(15): 158504. doi: 10.7498/aps.62.158504
    [18] 李艳武, 刘彭义, 侯林涛, 吴冰. Rubrene作电子传输层的异质结有机太阳能电池. 物理学报, 2010, 59(2): 1248-1251. doi: 10.7498/aps.59.1248
    [19] 王 宇, 华玉林, 吴晓明, 张国辉, 惠娟利, 张丽娟, 刘 倩, 印寿根. 发光层和空穴传输层对白色电致发光器件性能的影响. 物理学报, 2007, 56(12): 7213-7218. doi: 10.7498/aps.56.7213
    [20] 姜 燕, 杨盛谊, 张秀龙, 滕 枫, 徐 征, 侯延冰. 基于ZnSe的有机-无机异质结电致发光器件. 物理学报, 2006, 55(9): 4860-4864. doi: 10.7498/aps.55.4860
计量
  • 文章访问数:  7484
  • PDF下载量:  4017
  • 被引次数: 0
出版历程
  • 收稿日期:  2014-10-20
  • 修回日期:  2014-11-21
  • 刊出日期:  2015-02-05

平面异质结有机-无机杂化钙钛矿太阳电池研究进展

  • 1. 华北电力大学新型薄膜太阳电池北京市重点实验室, 北京 102206;
  • 2. 华北电力大学能源的安全与清洁利用北京市重点实验室, 北京 102206;
  • 3. 中国科学院化学研究所有机固体实验室, 北京 100190
    基金项目: 国家自然科学基金(批准号: 51173040, 91023039, 51303052)、高等学校博士学科点专项科研基金(批准号: 20130036110007)、新世纪优秀人才支持计划(批准号: NCET-12-0848)、北京高等学校青年英才计划项目(批准号: YETP0713)和中央高校基本科研业务费专项资金(批准号: 13ZD11, 2014ZD11, 2014MS35, 2014ZZD07)资助的课题.

摘要: 高效低成本太阳电池的研发是太阳能光伏技术大规模推广应用的关键. 近年来兴起的有机- 无机杂化钙钛矿(以下简称钙钛矿)太阳电池因具有光电能量转换效率高、制备工艺简单等优点, 引起了学术界和产业界的广泛关注, 具有广阔的发展前景. 其中平面异质结钙钛矿太阳电池因具有结构简单, 可低温制备等诸多优点, 成为目前研究的一个重要方向. 平面异质结钙钛矿太阳电池分为n-i-p型和p-i-n型两种结构. 其中钙钛矿分别与电子传输层和空穴传输层形成两个界面, 在这两个界面上实现电子和空穴的快速分离. 电子传输层和空穴传输层分别为电子和空穴提供了独立的输运通道. 平面异质结结构有利于钙钛矿太阳电池中电子和空穴的分离、传输和收集. 此外, 该结构不需要高温烧结的多孔结构氧化物骨架, 扩大了电子和空穴传输材料的选择范围. 可以根据钙钛矿材料的能带分布及载流子传输特性, 来选择能级和载流子传输速率更为匹配的传输材料. 本文对钙钛矿的材料特性, 平面异质结结构的由来及发展进行了简要的概述. 其中重点介绍了平面异质结钙钛矿太阳电池的结构特征、工作机理、钙钛矿/电荷传输层的界面特性, 以及电池性能的优化, 包括钙钛矿薄膜制备、空穴和电子传输层的优化等. 最后对钙钛矿电池的发展前景及存在问题进行了阐述, 为今后高效、稳定钙钛矿太阳电池的研究提供参考.

English Abstract

参考文献 (74)

目录

    /

    返回文章
    返回