基于负载Fe3O4纳米微球的大尺寸单层二维Ti3C2Tx微波吸收性能

肖忆瑶; 何佳豪; 陈南锟; 王超; 宋宁宁

doi:10.7498/aps.72.20231200

摘要

二维碳/氮化物MXene近年来受到了越来越多的关注, 其优异的导电性和表面丰富的官能团可对电磁波吸收有着积极的作用. 然而作为仅有介电损耗的非磁性材料, MXene存在着阻抗不匹配等问题, 极大地限制了实际应用. 因此, 将磁性材料与MXene结合成为了目前微波吸收领域的研究热点, 而降低MXene堆叠现象与调控磁性材料所占比例成为实现良好微波吸收性能的关键因素. 本文通过简单的静电吸附作用将水热法制备的Fe₃O₄纳米微球锚定在大尺寸单层二维Ti₃C₂T_x表面, 并在该Fe₃O₄@Ti₃C₂T_x复合结构中实现了–69.31 dB的最小反射损耗值(频率为16.19 GHz), 且此时的双峰吸收带宽可达到3.39 GHz. 另外, 雷达截面(RCS)模拟计算表明, 该样品也具有优异的RCS值, 表现出对雷达波优异的衰减能力. 本研究对二维材料和磁性材料在微波吸收领域的性能改善与实际应用提供了新的思路.

关键词:

微波吸收 /
MXene /
Fe₃O₄ /
复合结构

Abstract

With the rapid development of electronic equipment, electromagnetic interference and electromagnetic radiation pollution have become serious problems, because excessive electromagnetic interference will not only affect normal operation of electronic equipment but also do great harm to human health. In general, an ideal material for microwave absorption with the characteristics of high reflection loss (RL) intensity, wide effective absorption band (EAB), thin thickness, and lightweight could effectively consume electromagnetic wave (EMW) energy. Therefore, it is crucial to search for such an ideal microwave absorption material to deal with the electromagnetic radiation pollution. Two-dimensional (2D) carbon/nitride MXene has received more and more attention in recent years, because excellent electrical conductivity and rich surface-functional groups in MXene show positive effects on electromagnetic wave absorption. However, as a non-magnetic material with only dielectric loss, MXene exhibits obvious impedance mismatch, which greatly limits its practical applications. Combining MXene with magnetic materials becomes a hotspot for the exploration of ideal microwave absorption materials. As a typical ferrite, Fe₃O₄ shows excellent soft magnetic properties such as high saturation magnetization, high chemical stability, and simple preparation. In this paper, the 2D Fe₃O₄@Ti₃C₂T_x composite is successfully prepared by hydrothermal method and simple electrostatic adsorption process. The Fe₃O₄ nanoparticles are uniformly anchored on the surface of large-sized monolayer Ti₃C₂T_x, which effectively reduces the stacking of MXene. By regulating the proportion of magnetic materials, the microwave absorption performance of 2D Fe₃O₄@Ti₃C₂T_x composite is investigated. With the content of Fe₃O₄ nanoparticles in the 2D Fe₃O₄@Ti₃C₂T_x composite increasing from 4 mg to 8 mg, the microwave absorption performance is enhanced obviously. This is caused by the abundant Fe₃O₄/Ti₃C₂T_x interface, scattering channels, point defect, charge density difference in 2D Fe₃O₄@Ti₃C₂T_x composite, and the optimized impedance matching. The minimum reflection loss (RL_min) of 2D Fe₃O₄@Ti₃C₂T_x composite reaches –69.31 dB at a frequency of 16.19 GHz, and the effective absorption band (EAB) achieves 3.39 GHz. With the content of Fe₃O₄ nanoparticles further increasing to 10 mg, the microwave absorption performance shows a decreasing trend. Excessive Fe₃O₄ nanoparticles in the 2D Fe₃O₄@Ti₃C₂T_x composite lead to the decrease of electrical conductivity and thus the impedance dis-matching and dielectric loss decreasing, which leads the microwave absorption performance to decrease. Radar scattering cross section (RCS) is a physical quantity that evaluates the intensity of the scattered echo energy in the intercepted electromagnetic wave energy. The results of the RCS simulation can be applied to real objects which have been widely utilized in radar wave stealth. Its multi-angle simulation results can be used as an important basis for evaluating the stealth capability of microwave-absorbing material. The RCS simulations show that the average RCS value of 2D Fe₃O₄@Ti₃C₂T_x composite is over –47.92 dBm² at an incidence angle of 25°, demonstrating its excellent radar wave absorption performance. This study provides new ideas for improving and practically using two-dimensional and magnetic materials in the microwave absorption field and gives a new path to the subsequent development of microwave-absorbing composites.

Keywords:

作者及机构信息

北京化工大学数理学院, 北京　100029

通信作者: 宋宁宁, songnn@buct.edu.cn

基金项目: 国家自然科学基金(批准号: 51872021)资助的课题.

Authors and contacts

College of Mathematics and Physics, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Song Ning-Ning, songnn@buct.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant No. 51872021).

文章全文 : translate this paragraph

参考文献

[1]	Liu W, Wang D H, Li K X, Wei X H 2022 ACS Appl. Nano Mater. 5 18488 Google Scholar
[2]	Yue Y, Wang Y X, Xu X D, Wang C J 2023 J. Alloys Compd. 945 169342 Google Scholar
[3]	Wang J Q, Wu Z, Xing Y Q, Li B J, Huang P, Liu L 2023 Small 19 2207051 Google Scholar
[4]	Wu S J, Liu H, Wang Q H, Yin X Y, Hou L X 2023 J. Alloys Compd. 945 169372 Google Scholar
[5]	Xu Y X, Huang Y F, Zhao J, Han X H, Chai C P, Ma H L 2023 J. Alloys Compd. 960 170829 Google Scholar
[6]	Cai Z, Ma Y F, Zhao K, Yun M C, Wang X Y, Tong Z M, Wang M, Suhr J, Xiao L T, Jia S T, Chen X Y 2023 Chem. Eng. J. 462 142042 Google Scholar
[7]	Wang Y, Gao X, Wu X M, Zhang W Z, Luo C Y, Liu P B 2019 Chem. Eng. J. 375 121942 Google Scholar
[8]	Qiang R, Du Y C, Zhao H T, Wang Y, Tian C H, Li Z G, Han X J, Xu P 2015 J. Mater. Chem. A 3 13426 Google Scholar
[9]	Liu Z Y, Tian H L, Xu R X, Men W W, Su T, Qu Y G, Zhao W, Liu D 2023 Carbon 205 138 Google Scholar
[10]	Zeng X J, Zhao C, Yin Y C, Nie T L, Xie N H, Yu R H, Stucky G D 2022 Carbon 193 26 Google Scholar
[11]	Zhang Z W, Cai Z H, Zhang Y, Peng Y L, Wang Z Y, Xia L, Ma S P, Yin Z Z, Wang R F, Cao Y S, Li Z, Huang Y 2021 Carbon 174 484 Google Scholar
[12]	Che R C, Zhi C Y, Liang C Y, Zhou X G 2006 Appl. Phys. Lett. 88 033105 Google Scholar
[13]	Fan X X, Zhang Z Y, Wang S J, Zhang J, Xiong S S 2023 Appl. Surf. Sci. 625 157116 Google Scholar
[14]	Xiu Z L, Li X G, Zhang M Z, Huang B, Ma J Y, Yu J X, Meng X G 2022 J. Alloys Compd. 921 166068 Google Scholar
[15]	Wang S J, Zhang Z Y, Fan X X, Li Y, Zhang J, Xue L L, Xiong S S 2023 J. Alloys Compd. 960 170724 Google Scholar
[16]	Hua T X, Guo H, Qin J, Wu Q X, Li L Y, Qian B 2022 RSC Adv. 12 24980 Google Scholar
[17]	Song S W, Zhang A T, Chen L, Jia Q, Zhou C L, Liu J Q, Wang X X 2021 Carbon 176 279 Google Scholar
[18]	Li X, Xu D M, Zhou D, Pang S Z, Du C, Darwish M A, Zhou T, Sun S K 2023 Carbon 208 374 Google Scholar
[19]	Wang X L, Han N, Zhang Y, Shi G M, Zhang Y J, Li D 2022 J. Mater. Sci. Mater. Electron. 33 21091 Google Scholar
[20]	Guo R, Fan Y C, Wang L J, Jiang W 2020 Carbon 169 214 Google Scholar
[21]	Zhou X J, Li S C, Zhang M L, Yuan X Y, Wen J W, Xi H, Wu H J, Ma X H 2023 Carbon 204 538 Google Scholar
[22]	Wang Y, Dou Q, Jiang W, Su K, You J, Yin S, Wang T, Yang J, Li Q 2022 ACS Appl. Nano Mater. 5 9209 Google Scholar
[23]	Du Q R, Men Q Q, Li R S, Cheng Y W, Zhao B, Che R C 2022 Small 18 2203609 Google Scholar
[24]	Li M M, Xu Q Y, Jiang W, Farooq A, Qi Y R, Liu L F 2023 Fibers Polym. 24 771 Google Scholar
[25]	He J, Shan D Y, Yan S Q, Luo H, Cao C, Peng Y H 2019 J. Magn. Magn. Mater. 492 165639 Google Scholar
[26]	Lei B Y, Hou Y L, Meng W J, Wang Y Q, Yang X X, Ren M X, Zhao D L 2022 Carbon 196 280 Google Scholar
[27]	Liu M, Zhao B, Pei K, Qian Y T, Yang C D, Liu Y H, Cao H, Zhang J C, Che R C 2023 Small 19 2300363 Google Scholar
[28]	Zhang R X, Wang L, Xu C Y, Liang C Y, Liu X H, Zhang X F, Che R C 2022 Nano Res. 15 6743 Google Scholar
[29]	Wang C, Chen N K, Yang T Y, Cheng Q Z, Wu D a, Xiao Y Y, He S L, Song N N 2023 J. Magn. Magn. Mater. 565 170267 Google Scholar
[30]	Shu X F, Zhou J, Lian W, Jiang Y, Wang Y Q, Shu R W, Liu Y, Han J J, Zhuang Y 2021 J. Alloys Compd. 854 157087 Google Scholar
[31]	Chen N K, Wang C, Xiao Y Y, Han R, Wu Q, Song N N 2023 J. Alloys Compd. 947 169554 Google Scholar
[32]	Song N N, Gu S Z, Wu Q, Li C L, Zhou J, Zhang P P, Wang W, Yue M 2018 J. Magn. Magn. Mater. 451 793 Google Scholar
[33]	Song N N, Yang H T, Liu H L, Ren X, Ding H F, Zhang X Q, Cheng Z H 2013 Sci. Rep. 3 3161 Google Scholar
[34]	Wu Y H, Tan S J, Liu P Y, Zhang Y, Li P, Ji G B 2023 J. Mater. Sci. Technol. 151 10 Google Scholar
[35]	Liu Y L, Tian C H, Wang F Y, Hu B, Xu P, Han X J, Du Y C 2023 Chem. Eng. J. 461 141867 Google Scholar
[36]	Zhang S, Huang Y, Wang J M, Han X P, Zhang G Z, Sun X 2023 Carbon 209 118006 Google Scholar
[37]	Wang L H, Su S L, Wang Y D 2022 ACS Appl. Nano Mater. 5 17565 Google Scholar
[38]	Xiao Y Y, Zhang B X, Liao P, Qiu Z H, Song N N, Xu H J 2023 New J. Chem. 47 2575 Google Scholar
[39]	Liu Q H, Cao Q, Bi H, Liang C Y, Yuan K P, She W, Yang Y J, Che R C 2016 Adv. Mater. 28 486 Google Scholar
[40]	Yuan M Y, Zhao B, Yang C D, Pei K, Wang L Y, Zhang R X, You W B, Liu X H, Zhang X F, Che R C 2022 Adv. Funct. Mater. 32 2203161 Google Scholar
[41]	Chen Z H, Zhang Z N, Zhang H Q, Hu D, Ye Z B, Zhang Y, Yu Y, Nie B H, Xi H X, Duan C X 2022 Rare Metals 41 3100 Google Scholar
[42]	Yamashita T, Hayes P 2008 Appl. Surf. Sci. 254 2441 Google Scholar
[43]	Deng B W, Liu Z C, Pan F, Xiang Z, Zhang X, Lu W 2021 J. Mater. Chem. A 9 3500 Google Scholar
[44]	Lv Y H, Ye X Y, Chen S, Ma L, Zhang L, Liang W K, Wu Y P, Wang Q T 2023 Appl. Surf. Sci. 622 156935 Google Scholar
[45]	Zha L L, Zhang X H, Wu J H, Liu J J, Lan J F, Yang Y, Wu B 2023 Ceram. Int. 49 20672 Google Scholar
[46]	Yan H Y, Guo Y, Bai X Z, Qi J W, Zhao X Y, Lu H P, Deng L J 2023 Appl. Surf. Sci. 633 157602 Google Scholar
[47]	Che R C, Peng L M, Duan X F, Chen Q, Liang X L 2004 Adv. Mater. 16 401 Google Scholar
[48]	Olmedo L, Hourquebie P, Jousse F 1993 Adv. Mater. 5 373 Google Scholar
[49]	Liu D W, Du Y C, Li Z N, Wang Y H, Xu P, Zhao H H, Wang F Y, Li C L, Han X J 2018 J. Mater. Chem. C 6 9615 Google Scholar
[50]	Wang C, Han X J, Ping X, Wang J Y, Du Y C, Wang X H, Qin W, Zhang T 2010 J. Phys. Chem. C 114 3196 Google Scholar
[51]	Ding J, Cheng L G 2021 J. Alloys Compd. 881 160574 Google Scholar
[52]	Liu W, Duan P T, Ding Y, Zhang B W, Su H L, Zhang X B, Wang J Z, Zou Z Q 2022 Dalton Trans. 51 6597 Google Scholar
[53]	Zhu X J, Dong Y Y, Pan F, Xiang Z, Liu Z C, Deng B W, Zhang X, Shi Z, Lu W 2021 Compos. Commun. 25 100731 Google Scholar
[54]	Liu J K, Jia Z R, Zhou W H, Liu X H, Zhang C H, Xu B H, Wu G L 2022 Chem. Eng. J. 429 132253 Google Scholar
[55]	Dai B S, Qi T, Song M J, Geng M Q, Dai Y X, Qi Y 2022 Nanoscale 14 10456 Google Scholar

施引文献

图 1 二维Fe₃O₄@Ti₃C₂T_x复合材料制备过程示意图

Fig. 1. Schematic diagram of preparation process for 2D Fe₃O₄@Ti₃C₂T_x composites.

下载: 全尺寸图片幻灯片

图 2 (a)单层二维Ti₃C₂T_x的SEM图; (b) Fe₃O₄纳米颗粒的SEM图; (c), (d)二维Fe₃O₄@Ti₃C₂T_x复合材料的SEM图; (e)二维Fe₃O₄@Ti₃C₂T_x复合材料的TEM图, 插图为Fe₃O₄纳米颗粒的HRTEM图; (f), (g) Fe₃O₄纳米颗粒和Fe₃O₄纳米微球的粒径分布图; (h)元素映射图

Fig. 2. SEM image of (a) single layer Ti₃C₂T_x, (b) Fe₃O₄ nanoparticles, and (c), (d) 2D Fe₃O₄@Ti₃C₂T_x composites; (e) TEM image of 2D Fe₃O₄@Ti₃C₂T_x composites, inset shows HRTEM image of Fe₃O₄ nanoparticle; (f), (g) particle size distributions of Fe₃O₄ nanoparticles and Fe₃O₄ nanomicrospheres; (h) elemental mapping.

下载: 全尺寸图片幻灯片

图 3 (a)不同阶段产物的XRD图; (b)二维 Fe₃O₄@Ti₃C₂T_x复合纳米片、(c) Fe 2p、(d) O 1s、(e) Ti 2p、(f) C 1s的XPS光谱

Fig. 3. (a) XRD patterns of the products at different stages; (b) XPS survey spectra of 2D Fe₃O₄@Ti₃C₂T_x composites, (c) Fe 2p, (d) O 1s, (e) Ti 2p, and (f) C 1s.

下载: 全尺寸图片幻灯片

图 4 FT-4, FT-6, FT-8, FT-10样品的相对复介电常数和相对复磁导率　(a), (b)复介电常数的实部和虚部; (c)介电损耗角正切; (d), (e)复数磁导率的实部和虚部; (f)磁损耗角正切

Fig. 4. (a), (b) Real and imaginary parts of the permittivity, (c) dielectric loss tangent of FT-4, FT-6, FT-8, and FT-10 samples; (d), (e) real and imaginary parts of the complex permeability, (f) magnetic loss tangent of FT-4, FT-6, FT-8, and FT-10 samples.

下载: 全尺寸图片幻灯片

图 5 (a) FT-4, (b) FT-6, (c) FT-8, (d) FT-10的Cole-Cole曲线, 以及4个样品的(e)C₀曲线和(f)衰减常数α

Fig. 5. Cole-Cole plot for (a) FT-4, (b) FT-6, (c) FT-8, and (d) FT-10 samples; (e) C₀ curves and (f) attenuation constant α of the four samples.

下载: 全尺寸图片幻灯片

图 6 填充质量分数为20%的(a) FT-4, (b) FT-6, (c) FT-8, (d) FT-10样品的2D反射损耗图; 填充质量分数为20%的(e) FT-4, (f) FT-6, (g) FT-8, (h) FT-10样品的3D反射损耗图

Fig. 6. 2D reflection loss images of (a) FT-4, (b) FT-6, (c) FT-8, and (d) FT-10 samples with 20% filling; 3D reflection loss images of (e) FT-4, (f) FT-6, (g) FT-8, and (h) FT-10 samples with 20% filling.

下载: 全尺寸图片幻灯片

图 7 填充质量分数为30%的FT-8 样品的(a) 2D反射损耗图, (b) 3D反射损耗图, (c) Cole-Cole曲线, (d)阻抗匹配图, (e)C₀曲线和(f)衰减常数α

Fig. 7. (a) 2D reflection loss image, (b) 3D reflection loss image, (c) Cole-Cole curve, (d) impedance matching plot, (e) C₀ curve and (f) attenuation constant α for FT-8 samples with 30% filling.

下载: 全尺寸图片幻灯片

图 8 填充质量分数为20%的(a) FT-4, (b) FT-6, (c) FT-8, (d) FT-10和(e)填充质量分数为30%的FT-8样品的CST模拟结果; (f) –90°—90°下所有样品的RCS值

Fig. 8. CST simulation results of (a) FT-4, (b) FT-6, (c) FT-8, (d) FT-10 samples with 20% filler, (e) FT-8 sample with 30% filler; (f) RCS values of all samples at –90°–90°.

下载: 全尺寸图片幻灯片

[1]	Liu W, Wang D H, Li K X, Wei X H 2022 ACS Appl. Nano Mater. 5 18488 Google Scholar
[2]	Yue Y, Wang Y X, Xu X D, Wang C J 2023 J. Alloys Compd. 945 169342 Google Scholar
[3]	Wang J Q, Wu Z, Xing Y Q, Li B J, Huang P, Liu L 2023 Small 19 2207051 Google Scholar
[4]	Wu S J, Liu H, Wang Q H, Yin X Y, Hou L X 2023 J. Alloys Compd. 945 169372 Google Scholar
[5]	Xu Y X, Huang Y F, Zhao J, Han X H, Chai C P, Ma H L 2023 J. Alloys Compd. 960 170829 Google Scholar
[6]	Cai Z, Ma Y F, Zhao K, Yun M C, Wang X Y, Tong Z M, Wang M, Suhr J, Xiao L T, Jia S T, Chen X Y 2023 Chem. Eng. J. 462 142042 Google Scholar
[7]	Wang Y, Gao X, Wu X M, Zhang W Z, Luo C Y, Liu P B 2019 Chem. Eng. J. 375 121942 Google Scholar
[8]	Qiang R, Du Y C, Zhao H T, Wang Y, Tian C H, Li Z G, Han X J, Xu P 2015 J. Mater. Chem. A 3 13426 Google Scholar
[9]	Liu Z Y, Tian H L, Xu R X, Men W W, Su T, Qu Y G, Zhao W, Liu D 2023 Carbon 205 138 Google Scholar
[10]	Zeng X J, Zhao C, Yin Y C, Nie T L, Xie N H, Yu R H, Stucky G D 2022 Carbon 193 26 Google Scholar
[11]	Zhang Z W, Cai Z H, Zhang Y, Peng Y L, Wang Z Y, Xia L, Ma S P, Yin Z Z, Wang R F, Cao Y S, Li Z, Huang Y 2021 Carbon 174 484 Google Scholar
[12]	Che R C, Zhi C Y, Liang C Y, Zhou X G 2006 Appl. Phys. Lett. 88 033105 Google Scholar
[13]	Fan X X, Zhang Z Y, Wang S J, Zhang J, Xiong S S 2023 Appl. Surf. Sci. 625 157116 Google Scholar
[14]	Xiu Z L, Li X G, Zhang M Z, Huang B, Ma J Y, Yu J X, Meng X G 2022 J. Alloys Compd. 921 166068 Google Scholar
[15]	Wang S J, Zhang Z Y, Fan X X, Li Y, Zhang J, Xue L L, Xiong S S 2023 J. Alloys Compd. 960 170724 Google Scholar
[16]	Hua T X, Guo H, Qin J, Wu Q X, Li L Y, Qian B 2022 RSC Adv. 12 24980 Google Scholar
[17]	Song S W, Zhang A T, Chen L, Jia Q, Zhou C L, Liu J Q, Wang X X 2021 Carbon 176 279 Google Scholar
[18]	Li X, Xu D M, Zhou D, Pang S Z, Du C, Darwish M A, Zhou T, Sun S K 2023 Carbon 208 374 Google Scholar
[19]	Wang X L, Han N, Zhang Y, Shi G M, Zhang Y J, Li D 2022 J. Mater. Sci. Mater. Electron. 33 21091 Google Scholar
[20]	Guo R, Fan Y C, Wang L J, Jiang W 2020 Carbon 169 214 Google Scholar
[21]	Zhou X J, Li S C, Zhang M L, Yuan X Y, Wen J W, Xi H, Wu H J, Ma X H 2023 Carbon 204 538 Google Scholar
[22]	Wang Y, Dou Q, Jiang W, Su K, You J, Yin S, Wang T, Yang J, Li Q 2022 ACS Appl. Nano Mater. 5 9209 Google Scholar
[23]	Du Q R, Men Q Q, Li R S, Cheng Y W, Zhao B, Che R C 2022 Small 18 2203609 Google Scholar
[24]	Li M M, Xu Q Y, Jiang W, Farooq A, Qi Y R, Liu L F 2023 Fibers Polym. 24 771 Google Scholar
[25]	He J, Shan D Y, Yan S Q, Luo H, Cao C, Peng Y H 2019 J. Magn. Magn. Mater. 492 165639 Google Scholar
[26]	Lei B Y, Hou Y L, Meng W J, Wang Y Q, Yang X X, Ren M X, Zhao D L 2022 Carbon 196 280 Google Scholar
[27]	Liu M, Zhao B, Pei K, Qian Y T, Yang C D, Liu Y H, Cao H, Zhang J C, Che R C 2023 Small 19 2300363 Google Scholar
[28]	Zhang R X, Wang L, Xu C Y, Liang C Y, Liu X H, Zhang X F, Che R C 2022 Nano Res. 15 6743 Google Scholar
[29]	Wang C, Chen N K, Yang T Y, Cheng Q Z, Wu D a, Xiao Y Y, He S L, Song N N 2023 J. Magn. Magn. Mater. 565 170267 Google Scholar
[30]	Shu X F, Zhou J, Lian W, Jiang Y, Wang Y Q, Shu R W, Liu Y, Han J J, Zhuang Y 2021 J. Alloys Compd. 854 157087 Google Scholar
[31]	Chen N K, Wang C, Xiao Y Y, Han R, Wu Q, Song N N 2023 J. Alloys Compd. 947 169554 Google Scholar
[32]	Song N N, Gu S Z, Wu Q, Li C L, Zhou J, Zhang P P, Wang W, Yue M 2018 J. Magn. Magn. Mater. 451 793 Google Scholar
[33]	Song N N, Yang H T, Liu H L, Ren X, Ding H F, Zhang X Q, Cheng Z H 2013 Sci. Rep. 3 3161 Google Scholar
[34]	Wu Y H, Tan S J, Liu P Y, Zhang Y, Li P, Ji G B 2023 J. Mater. Sci. Technol. 151 10 Google Scholar
[35]	Liu Y L, Tian C H, Wang F Y, Hu B, Xu P, Han X J, Du Y C 2023 Chem. Eng. J. 461 141867 Google Scholar
[36]	Zhang S, Huang Y, Wang J M, Han X P, Zhang G Z, Sun X 2023 Carbon 209 118006 Google Scholar
[37]	Wang L H, Su S L, Wang Y D 2022 ACS Appl. Nano Mater. 5 17565 Google Scholar
[38]	Xiao Y Y, Zhang B X, Liao P, Qiu Z H, Song N N, Xu H J 2023 New J. Chem. 47 2575 Google Scholar
[39]	Liu Q H, Cao Q, Bi H, Liang C Y, Yuan K P, She W, Yang Y J, Che R C 2016 Adv. Mater. 28 486 Google Scholar
[40]	Yuan M Y, Zhao B, Yang C D, Pei K, Wang L Y, Zhang R X, You W B, Liu X H, Zhang X F, Che R C 2022 Adv. Funct. Mater. 32 2203161 Google Scholar
[41]	Chen Z H, Zhang Z N, Zhang H Q, Hu D, Ye Z B, Zhang Y, Yu Y, Nie B H, Xi H X, Duan C X 2022 Rare Metals 41 3100 Google Scholar
[42]	Yamashita T, Hayes P 2008 Appl. Surf. Sci. 254 2441 Google Scholar
[43]	Deng B W, Liu Z C, Pan F, Xiang Z, Zhang X, Lu W 2021 J. Mater. Chem. A 9 3500 Google Scholar
[44]	Lv Y H, Ye X Y, Chen S, Ma L, Zhang L, Liang W K, Wu Y P, Wang Q T 2023 Appl. Surf. Sci. 622 156935 Google Scholar
[45]	Zha L L, Zhang X H, Wu J H, Liu J J, Lan J F, Yang Y, Wu B 2023 Ceram. Int. 49 20672 Google Scholar
[46]	Yan H Y, Guo Y, Bai X Z, Qi J W, Zhao X Y, Lu H P, Deng L J 2023 Appl. Surf. Sci. 633 157602 Google Scholar
[47]	Che R C, Peng L M, Duan X F, Chen Q, Liang X L 2004 Adv. Mater. 16 401 Google Scholar
[48]	Olmedo L, Hourquebie P, Jousse F 1993 Adv. Mater. 5 373 Google Scholar
[49]	Liu D W, Du Y C, Li Z N, Wang Y H, Xu P, Zhao H H, Wang F Y, Li C L, Han X J 2018 J. Mater. Chem. C 6 9615 Google Scholar
[50]	Wang C, Han X J, Ping X, Wang J Y, Du Y C, Wang X H, Qin W, Zhang T 2010 J. Phys. Chem. C 114 3196 Google Scholar
[51]	Ding J, Cheng L G 2021 J. Alloys Compd. 881 160574 Google Scholar
[52]	Liu W, Duan P T, Ding Y, Zhang B W, Su H L, Zhang X B, Wang J Z, Zou Z Q 2022 Dalton Trans. 51 6597 Google Scholar
[53]	Zhu X J, Dong Y Y, Pan F, Xiang Z, Liu Z C, Deng B W, Zhang X, Shi Z, Lu W 2021 Compos. Commun. 25 100731 Google Scholar
[54]	Liu J K, Jia Z R, Zhou W H, Liu X H, Zhang C H, Xu B H, Wu G L 2022 Chem. Eng. J. 429 132253 Google Scholar
[55]	Dai B S, Qi T, Song M J, Geng M Q, Dai Y X, Qi Y 2022 Nanoscale 14 10456 Google Scholar

[1]	任延英, 李雅宁, 柳洪盛, 徐楠, 郭坤, 徐朝辉, 陈鑫, 高峻峰. 过渡金属元素掺杂对磁铁矿磁矩及磁各向异性的调控. 物理学报, 2024, 73(6): 066104. doi: 10.7498/aps.73.20231744
[2]	吴宇阳, 李卫, 任青颖, 李金泽, 许巍, 许杰. 金属Sc修饰Ti₂CO₂吸附气体分子的第一性原理研究. 物理学报, 2024, 73(7): 073101. doi: 10.7498/aps.73.20231432
[3]	赵建宁, 魏东, 吕国正, 王子成, 刘冬欢. 一维异质结构的瞬态热整流效应. 物理学报, 2023, 72(4): 044401. doi: 10.7498/aps.72.20222085
[4]	杜立杰, 陈靖雯, 王荣明. 基于C₁₄H₃₁O₃P-Ti₃C₂/Au肖特基结的自驱动近红外探测器. 物理学报, 2023, 72(13): 138502. doi: 10.7498/aps.72.20230480
[5]	韩丹, 刘志华, 刘琭琭, 韩晓美, 刘东明, 禚凯, 桑胜波. 新型二维材料Ti₃C₂T_x MXene制备及其气敏性能研究. 物理学报, 2022, 71(1): 010701. doi: 10.7498/aps.71.20211048
[6]	白亮, 赵启旭, 沈健伟, 杨岩, 袁清红, 钟成, 孙海涛, 孙真荣. 基于MXene涂层保护Cs₃Sb异质结光阴极材料的计算筛选. 物理学报, 2021, 70(21): 218504. doi: 10.7498/aps.70.20210956
[7]	刘超, 杨岳洋, 南策文, 林元华. MAX及其衍生MXene相碳化物的热电性能及展望. 物理学报, 2021, 70(20): 206501. doi: 10.7498/aps.70.20211050
[8]	张博宇, 周佳凯, 任程超, 苏祥林, 任慧志, 赵颖, 张晓丹, 侯国付. 硅异质结太阳电池中钝化层和发射层的优化设计. 物理学报, 2021, 70(18): 188401. doi: 10.7498/aps.70.20210674
[9]	韩丹, 刘志华, 刘琭琭, 韩晓美, 刘东明, 禚凯, 桑胜波. 新型二维材料Ti3C2Tx MXene制备及其气敏性能研究. 物理学报, 2021, (): . doi: 10.7498/aps.70.20211048
[10]	刘祥, 米文博. Verwey相变处Fe₃O₄的结构、磁性和电输运特性. 物理学报, 2020, 69(4): 040505. doi: 10.7498/aps.69.20191763
[11]	陈义豪, 徐威, 王钰琪, 万相, 李岳峰, 梁定康, 陆立群, 刘鑫伟, 连晓娟, 胡二涛, 郭宇锋, 许剑光, 童祎, 肖建. 基于二维材料MXene的仿神经突触忆阻器的制备和长/短时程突触可塑性的实现. 物理学报, 2019, 68(9): 098501. doi: 10.7498/aps.68.20182306
[12]	何学敏, 钟伟, 都有为. 核壳结构磁性复合纳米材料的可控合成与性能. 物理学报, 2018, 67(22): 227501. doi: 10.7498/aps.67.20181027
[13]	李圣昆, 唐军, 毛宏庆, 王明焕, 陈国彬, 翟超, 张晓明, 石云波, 刘俊. Fe3O4纳米颗粒/聚二甲基硅氧烷复合材料磁电容效应的研究. 物理学报, 2014, 63(5): 057501. doi: 10.7498/aps.63.057501
[14]	罗炳成, 陈长乐, 谢廉. Fe3O4薄膜的电输运及光诱导特性研究. 物理学报, 2011, 60(2): 027306. doi: 10.7498/aps.60.027306
[15]	许红霞, 郝颖萍, 韩荣典, 翁惠民, 杜淮江, 叶邦角. 纳米Fe3 O4 颗粒的正电子湮没谱学研究. 物理学报, 2011, 60(6): 067803. doi: 10.7498/aps.60.067803
[16]	孙明昭, 张淳民, 宋晓平. 新型八边形谐振环金属线复合周期结构左手材料奇异性质研究. 物理学报, 2010, 59(8): 5444-5449. doi: 10.7498/aps.59.5444
[17]	孟利军, 肖化平, 唐超, 张凯旺, 钟建新. 碳纳米管-硅纳米线复合结构的形成和热稳定性. 物理学报, 2009, 58(11): 7781-7786. doi: 10.7498/aps.58.7781
[18]	王敬平, 孟健. 磁场下合成Fe3O4粉体的隧道磁阻. 物理学报, 2008, 57(2): 1197-1201. doi: 10.7498/aps.57.1197
[19]	王海燕, 李新建. 硅纳米孔柱阵列及其四氧化三铁复合薄膜的湿敏电容特性研究. 物理学报, 2005, 54(5): 2220-2225. doi: 10.7498/aps.54.2220
[20]	都有为, 张毓昌, 陆怀先. 超细Fe3O4的氧化过程. 物理学报, 1981, 30(3): 424-427. doi: 10.7498/aps.30.424

计量

文章访问数: 3034
PDF下载量: 124
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板

基于负载Fe₃O₄纳米微球的大尺寸单层二维Ti₃C₂T_x微波吸收性能