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温室气体及碳同位素比值红外光谱反演精度的影响因素研究

李相贤 徐亮 高闽光 童晶晶 冯明春 刘建国 刘文清

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Citation:

温室气体及碳同位素比值红外光谱反演精度的影响因素研究

李相贤, 徐亮, 高闽光, 童晶晶, 冯明春, 刘建国, 刘文清

Influence factors of quantitative analysis precision of greenhouse gases and carbon isotope ratio based on infrared spectroscopy

Li Xiang-Xian, Xu Liang, Gao Min-Guang, Tong Jing-Jing, Feng Ming-Chun, Liu Jian-Guo, Liu Wen-Qing
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  • 由于傅里叶变换红外光谱(FTIR)技术在定量反演中受到气体温度、压强等气体特性以及水汽交叉吸收的影响, 使其在温室气体及碳同位素比值高精度检测领域的应用受到限制. 本文首先研究了气体特性与水汽吸收敏感性修正方法; 然后,结合实验研究中建立的敏感性修正函数, 对标准气体实测数据进行了气体特性敏感性修正, 修正后,五种测量组分的精密度均有明显提高, 其标准偏差降低倍数分布在1.80到3.38之间. 研究结果对于FTIR技术在大气本底温室气体及碳同位素比值高精度监测领域的应用具有重要意义.
    The quantitative analysis based on Fourier transform infrared (FTIR) technology is affected by the temperature and pressure properties of gas and the H2O cross section, so the applications of FTIR technology to high-precision measurement area of the greenhouse gases and isotope ratio are restricted. Firstly, the methods of correcting the gas property sensitivities and H2O cross sensitivity are studied, then the standard gas measurements are corrected with these sensitivity correcting functions established through experimental study. The standard deviations of CO, CO2, N2O, CH4 and δ13CO2 are all improved after correcting the sensitivities, and reduced by 1.80-3.38 times. These studies are significant for the applications of FTIR technology to the high-precision measurement area of greenhouse gases and isotope ratio.
    • 基金项目: 国家重大科学仪器设备开发专项(批准号: 2013YQ22064302)、国家自然科学基金(批准号:41305020)和“十二五”农村领域国家科技计划(批准号: 2012BAJ24B02-5)资助的课题.
    • Funds: Project supported by the National Key Scientific Instrument and Equipment Development Projects, China (Grant No. 2013YQ22064302), the National Natural Science Foundation of China (Grant No. 41305020), and the “Twelfth Five-Year” National Science and Technology Project in Rural Arear, China (Grant No. 2012BAJ24B02-5).
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    Dubowski Y, Harush D, Shaviv A, Stone L, Linker R 2014 Soil. Sci. Am. J. 78 61

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    Hammer S, Griffith D W T, Konrad G, Vardag S, Caldow C, Levin I 2013 Atmos. Meas. Tech. 6 1153

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    Li X X, Xu L, Gao M G, Tong J J, Jin L, Li S, Wei X L, Feng M C 2013 Acta Phys. Sin. 62 180203 (in Chinese) [李相贤, 徐亮, 高闽光, 童晶晶, 金岭, 李胜, 魏秀丽, 冯明春 2013 物理学报 62 180203]

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    Nakamichi S, Kawaguchi Y, Fukuda H, Enami S, Hashimoto S, Kawasaki M, Umekawa T, Morino I, Suto H, Inoue G 2006 Phys. Chem. Chem. Phys. 8 364

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  • [1]

    Solomon S, Qin D, Manning M, Chen Z, Marquis M, Averyt K B, Tignor M, Miller H L 2007 Contribution of Working Group 1 to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (Cambridge: Cambridge University Press) pIPCC. 2007. Climate Change 2007

    [2]

    16th WMO/IAEA Meeting on carbon Dioxide, Other Greenhouse Gases, and Related Measurement Techniques (GGMT-2011) Wellington, New Zealand, October 25-28, 2011

    [3]

    Feng M C, Gao M G, Xu L, Wei X L, Cheng S Y, Tong J J, Li X X, Jin L, Li S, Jiao Y 2012 Acta Opt. Sin. 32 0401002 (in Chinese) [冯明春, 高闽光, 徐亮, 魏秀丽, 程巳阳, 童晶晶, 李相贤, 金岭, 李胜, 焦洋 2012 光学学报 32 0401002]

    [4]

    Yang S, Li Y X, Ma Q Y, Xu X W, Niu P J, Li Y Z, Niu S L, Li H T 2005 Acta Phys. Sin. 54 2256 (in Chinese) [杨帅, 李养贤, 马巧云, 徐学文, 牛萍娟, 李永章, 牛胜利, 李洪涛 2005 物理学报 54 2256]

    [5]

    Liu Z M, Liu W Q, Gao M G, Tong J J, Zhang T S, Xu L, Wei X L 2008 Chin. Phys. B 17 4184

    [6]

    Li X X, Gao M G, Xu L, Tong J J, Wei X L, Cheng S Y, Feng M C 2011 Infrared Technol. 33 473 (in Chinese) [李相贤, 高闽光, 徐亮, 童晶晶, 魏秀丽, 程巳阳, 冯明春 2011 红外技术 33 473]

    [7]

    Dubowski Y, Harush D, Shaviv A, Stone L, Linker R 2014 Soil. Sci. Am. J. 78 61

    [8]

    Angelbratt J, Mellqvist J, Blumenstock T, Borsdorff T, Brohede S, Duchatelet P, Forster F, Hase F, Mahieu E, Murtagh D 2011 Atmos. Chem. Phys. 11 6167

    [9]

    Rothman L S, Gordon I E, Barbe A, Chris Benner D, Bernath P F, Birk M, Boudon V, Brown L R, Campargue A, Champion J P, Chance K, Coudert L H, Dana V, Devi V M, Fally S, Flaud J M, Gamache R R, Goldman A, Jacquemart D, Kleiner I, Lacome N, Lafferty W J, Mandin J Y, Massie S T, Mikhailenko S N, Miller C E, Moazzen-Ahmadi N, Naumenko O V, Nikitin A V, Orphal J, Perevalov V I, Perrin A, Predoi-Cross A, Rinsland C P, Rotger M, Simeckova M, Smith M A H, Sung K, Tashkun S A, Tennyson J, Toth R A, Vandaele A C, van der Auwera J 2009 J. Quant. Spectrosc. Ra. 110 533

    [10]

    Hammer S, Griffith D W T, Konrad G, Vardag S, Caldow C, Levin I 2013 Atmos. Meas. Tech. 6 1153

    [11]

    Li X X, Xu L, Gao M G, Tong J J, Jin L, Li S, Wei X L, Feng M C 2013 Acta Phys. Sin. 62 180203 (in Chinese) [李相贤, 徐亮, 高闽光, 童晶晶, 金岭, 李胜, 魏秀丽, 冯明春 2013 物理学报 62 180203]

    [12]

    William J P, David H P, Nickolas A G 2010 Technical Report for Period October 2009-September 2010

    [13]

    Long D A, Bielska K, Havey D K, Okumura M, Miller C E 2011 J. Chem. Phys. 135 064308

    [14]

    Nakamichi S, Kawaguchi Y, Fukuda H, Enami S, Hashimoto S, Kawasaki M, Umekawa T, Morino I, Suto H, Inoue G 2006 Phys. Chem. Chem. Phys. 8 364

    [15]

    Mohn J, Werner R A, Buchmann B, Emmenegger L 2007 J. Mol. Struct. 834 95

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出版历程
  • 收稿日期:  2014-07-09
  • 修回日期:  2014-08-22
  • 刊出日期:  2015-01-05

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