a-C: Fe/AlOx/Si基异质结的光伏效应

吴利华; 章晓中; 于奕; 万蔡华; 谭新玉

doi:10.7498/aps.60.037807

摘要

使用脉冲激光沉积(PLD)依次沉积氧化铝和碳膜制备了a-C: Fe/AlOx/Si基异质结,研究了其光伏效应及其在太阳能电池上的应用.该太阳能电池在标准日光照射(AM1.5,100 mW/cm2)下,可获得0.33 V的开路电压和4.5 mA/cm2的电流密度,太阳能电池的转换效率为0.35%.通过C-V测量,证明了氧化铝层的引入降低了界面能级数目,增加了界面势垒高度.界面能级数目降低减少了光生载流子在界面复合的

关键词:

Abstract

The photovoltaic effect of a-C: Fe/AlOx/Si based heterostructures prepared by Pulsed Laser Deposition (PLD) and its applications for solar cells were investigated. Thin alumina layer with a thickness of ~2nm was introduced to the interface between carbon and silicon, and the photovoltatic properties, such as open circuit voltage of ~0.33 V and short current density of ~4.5 mA/cm2, were improved dramatically compared with the samples without the insulation alumina layer. This may be related to the improvement of interface quality, where there are lower recombination centers such as defects and traps, which are approved by the C-V measurement. This work may shed light on the carbon/silicon based solar cells.

Keywords:

作者及机构信息

1.
先进材料教育部重点实验室,清华大学材料科学与工程系,北京 100084

基金项目: 国家自然科学基金委-广东联合基金重点项目(批准号: U0734001), 国家自然科学基金(批准号: 50772054), 973计划前期研究专项(批准号: 2008CB617601)资助的课题.

Authors and contacts

1.
Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China

参考文献

[1]	Goetzberger A, Hebling C, Schock H W 2003 Mat. Science Eng. R 40 1
[2]	90 3438
[3]	Kelzenberg M D, Boettcher S W, Petykiewicz J A, Turner-Evans D B, Putnam M C, Warren E L, Spurgeon J M, Briggs R M, Lewis N S, Atwater H A 2010 Nature Mater. 9 239
[4]	Harry A A, Albert P 2010 Nature 9 205
[5]	Wenham S R, Green MA, Watt M E, Corkish R 2007 Applied photovoltaics (2nd ed) (London: Earthscan Publications Ltd.)
[6]	Zhu H W, Wei J Q, Wang K L, Wu D H 2009 Sol. Energy Mater Sol. Cells 93 1461
[7]	Hao H Y, Kong G L, Zeng X B, Xu Y, Diao H W, Liao X B 2005 Acta Phys. Sin. 54 3327 (in Chinese) [郝会颖、孔光临、曾湘波、许颖、刁宏伟、廖显伯 2005 物理学报 54 3327]
[8]	Li Y J, Zheng J G, Feng L H, Li B, Zeng G G, Cai Y P, Zhang J Q, Li W, Lei Z, Wu L L, Cai W 2010 Acta Phys. Sin. 59 625 (in Chinese) [李愿杰、郑家贵、冯良桓、黎兵、曾广根、蔡亚平、张静全、李卫、雷智、武莉莉、蔡伟 2010 物理学报 59 625]
[9]	Zhang W Y, Wu X P, Sun L J, Lin B X, Fu Z X 2008 Acta Phys. Sin. 57 4471 (in Chinese) [张伟英、邬小鹏、孙利杰、林碧霞、傅竹西 2008物理学报57 4471]
[10]	Li Z R, Saini V, Dervishi E, Xu Y, Mahmood M, Biris A R, Biris A S 2009 Nanotech Conference Expo 1 53
[11]	Krishna K M, Nukaya Y, Soga T, Jimbo T, Umeno M 2001 Sol. Energy Mater. Sol. Cells 65 163
[12]	Tetsuo S, Toshihide K, Yasuhiko H, Jimbo T 2005 Thin Solid Films 482 86
[13]	Hao L Z, Xue Q Z, Gao X L, Li Q, Zheng Q B, Yan K Y 2007 J. Appl. Phys. 101 053718
[14]	Wan C H, Zhang X Z, Zhang X, Gao X L, Tan X Y 2009 Appl. Phys. Lett. 95 022105
[15]	Freitag M, Martin Y, Misewich J A 2003 Nano. Lett. 3 1067
[16]	Balasubramanian K, Fan Y W, Burghard M 2004 Appl. Phys. Lett. 84 2400
[17]	Lee J U 2005 Appl. Phys. Lett. 87 073101
[18]	Kymakis E, Amaratunga G A 2002 J. Appl. Phys. Lett. 80 112
[19]	Kawano T, Christensen D, Chen S P, Cho C Y, Lin L W 2006 Appl. Phys. Lett. 89 163510
[20]	Behnam A, Johnson J L, Choi Y, Ertosun M G, Okyay A K, Kapur P, Saraswat K C, Ural A 2008 Appl. Phys. Lett. 92 243116
[21]	Wei J Q, Jia Y, Shu Q K, Gu Z Y, Wang K L, Zhuang D M, Zhang G, Wang Z C, Luo J B, Cao A Y, Wu D H 2007 Nano. Lett. 7 2317
[22]	Zhou S Y, Gweon G H, Fedorov A V, First P N, De Heer W A, Lee D H, Guinea F, Neto A H C, Lanzara A 2007 Nature Mater. 6 770
[23]	Yu H A, Kaneko Y, Yoshimura S, Otani S 1996 Appl. Phys. Lett. 68 547
[24]	Krishna K M, Umeno M, Nukaya Y, Soga T, Jimbo T 2000 Appl. Phys. Lett. 77 1472
[25]	Rusop M, Mominuzzaman S M, Soga T, Jimbo T, Umeno M 2006 Sol. Energy Mater. Sol. Cells 90 3205
[26]	Yap S S, Tou T Y 2008 Vacuum 82 1449
[27]	Taguchi M, Kawamoto K, Tsuge S, Baba T, Sakata H, Morizane M, Uchihashi K, Nakamura N, Kiyama S, Oota O 2000 Prog. Photovolt: Res. Appl. 8 503
[28]	Zhao L, Zhou C L, Li H L, Diao H W, Wang W J 2008 Acta Phys. Sin. 57 3212 (in Chinese) [赵雷、周春兰、李海玲、刁宏伟、王文静 2008 物理学报 57 3212]
[29]	Feng Q, Hao Y, Yue Y Z 2008 Acta Phys. Sin. 57 1886 (in Chinese) [冯倩、郝跃、岳远征2008 物理学报 57 1886]
[30]	Ech-chamikh E, Essafti A, Azizan M, Ijdiyaou Y 2006 Sol. Energy Mater. Sol. Cells 90 1424
[31]	Veerasamy V S, Amartunga G A J, Park J S, Mackenzie H S, Milne W L 1995 IEEE Trans. Electr. Dev. 42 577
[32]	Sugiura M, Uragou K, Noda M, Tachiki M, Kobayashi T 1999 Jpn. J. Appl. Phys. 38 2675
[33]	Terlinden N M, Dingemans G, van de Sanden M C M, Kesselsa W M M 2010 Appl. Phys. Lett. 96 112101
[34]	Agostinelli G, Delabie A, Vitanov P, Alexieva Z, Dekkers H F W, De Wolf S, Beaucarne G 2006 Sol. Energy Mater. Sol. Cells

施引文献

[1]	Goetzberger A, Hebling C, Schock H W 2003 Mat. Science Eng. R 40 1
[2]	90 3438
[3]	Kelzenberg M D, Boettcher S W, Petykiewicz J A, Turner-Evans D B, Putnam M C, Warren E L, Spurgeon J M, Briggs R M, Lewis N S, Atwater H A 2010 Nature Mater. 9 239
[4]	Harry A A, Albert P 2010 Nature 9 205
[5]	Wenham S R, Green MA, Watt M E, Corkish R 2007 Applied photovoltaics (2nd ed) (London: Earthscan Publications Ltd.)
[6]	Zhu H W, Wei J Q, Wang K L, Wu D H 2009 Sol. Energy Mater Sol. Cells 93 1461
[7]	Hao H Y, Kong G L, Zeng X B, Xu Y, Diao H W, Liao X B 2005 Acta Phys. Sin. 54 3327 (in Chinese) [郝会颖、孔光临、曾湘波、许颖、刁宏伟、廖显伯 2005 物理学报 54 3327]
[8]	Li Y J, Zheng J G, Feng L H, Li B, Zeng G G, Cai Y P, Zhang J Q, Li W, Lei Z, Wu L L, Cai W 2010 Acta Phys. Sin. 59 625 (in Chinese) [李愿杰、郑家贵、冯良桓、黎兵、曾广根、蔡亚平、张静全、李卫、雷智、武莉莉、蔡伟 2010 物理学报 59 625]
[9]	Zhang W Y, Wu X P, Sun L J, Lin B X, Fu Z X 2008 Acta Phys. Sin. 57 4471 (in Chinese) [张伟英、邬小鹏、孙利杰、林碧霞、傅竹西 2008物理学报57 4471]
[10]	Li Z R, Saini V, Dervishi E, Xu Y, Mahmood M, Biris A R, Biris A S 2009 Nanotech Conference Expo 1 53
[11]	Krishna K M, Nukaya Y, Soga T, Jimbo T, Umeno M 2001 Sol. Energy Mater. Sol. Cells 65 163
[12]	Tetsuo S, Toshihide K, Yasuhiko H, Jimbo T 2005 Thin Solid Films 482 86
[13]	Hao L Z, Xue Q Z, Gao X L, Li Q, Zheng Q B, Yan K Y 2007 J. Appl. Phys. 101 053718
[14]	Wan C H, Zhang X Z, Zhang X, Gao X L, Tan X Y 2009 Appl. Phys. Lett. 95 022105
[15]	Freitag M, Martin Y, Misewich J A 2003 Nano. Lett. 3 1067
[16]	Balasubramanian K, Fan Y W, Burghard M 2004 Appl. Phys. Lett. 84 2400
[17]	Lee J U 2005 Appl. Phys. Lett. 87 073101
[18]	Kymakis E, Amaratunga G A 2002 J. Appl. Phys. Lett. 80 112
[19]	Kawano T, Christensen D, Chen S P, Cho C Y, Lin L W 2006 Appl. Phys. Lett. 89 163510
[20]	Behnam A, Johnson J L, Choi Y, Ertosun M G, Okyay A K, Kapur P, Saraswat K C, Ural A 2008 Appl. Phys. Lett. 92 243116
[21]	Wei J Q, Jia Y, Shu Q K, Gu Z Y, Wang K L, Zhuang D M, Zhang G, Wang Z C, Luo J B, Cao A Y, Wu D H 2007 Nano. Lett. 7 2317
[22]	Zhou S Y, Gweon G H, Fedorov A V, First P N, De Heer W A, Lee D H, Guinea F, Neto A H C, Lanzara A 2007 Nature Mater. 6 770
[23]	Yu H A, Kaneko Y, Yoshimura S, Otani S 1996 Appl. Phys. Lett. 68 547
[24]	Krishna K M, Umeno M, Nukaya Y, Soga T, Jimbo T 2000 Appl. Phys. Lett. 77 1472
[25]	Rusop M, Mominuzzaman S M, Soga T, Jimbo T, Umeno M 2006 Sol. Energy Mater. Sol. Cells 90 3205
[26]	Yap S S, Tou T Y 2008 Vacuum 82 1449
[27]	Taguchi M, Kawamoto K, Tsuge S, Baba T, Sakata H, Morizane M, Uchihashi K, Nakamura N, Kiyama S, Oota O 2000 Prog. Photovolt: Res. Appl. 8 503
[28]	Zhao L, Zhou C L, Li H L, Diao H W, Wang W J 2008 Acta Phys. Sin. 57 3212 (in Chinese) [赵雷、周春兰、李海玲、刁宏伟、王文静 2008 物理学报 57 3212]
[29]	Feng Q, Hao Y, Yue Y Z 2008 Acta Phys. Sin. 57 1886 (in Chinese) [冯倩、郝跃、岳远征2008 物理学报 57 1886]
[30]	Ech-chamikh E, Essafti A, Azizan M, Ijdiyaou Y 2006 Sol. Energy Mater. Sol. Cells 90 1424
[31]	Veerasamy V S, Amartunga G A J, Park J S, Mackenzie H S, Milne W L 1995 IEEE Trans. Electr. Dev. 42 577
[32]	Sugiura M, Uragou K, Noda M, Tachiki M, Kobayashi T 1999 Jpn. J. Appl. Phys. 38 2675
[33]	Terlinden N M, Dingemans G, van de Sanden M C M, Kesselsa W M M 2010 Appl. Phys. Lett. 96 112101
[34]	Agostinelli G, Delabie A, Vitanov P, Alexieva Z, Dekkers H F W, De Wolf S, Beaucarne G 2006 Sol. Energy Mater. Sol. Cells

[1]	孟祥琛, 王丹, 蔡亚辉, 叶振, 贺永宁, 徐亚男. 氧化铝表面二次电子发射抑制及其在微放电抑制中的应用. 物理学报, 2023, 72(10): 107901. doi: 10.7498/aps.72.20222404
[2]	谈松林, 庄永起, 易健宏. 溶胶-喷雾法制备多壁碳纳米管增强氧化铝基复合材料及性能研究. 物理学报, 2022, 71(1): 018801. doi: 10.7498/aps.71.20211043
[3]	舒衍涛, 张有为, 王顺. 基于过渡金属硫族化合物同质结的光电探测器. 物理学报, 2021, 70(17): 177301. doi: 10.7498/aps.70.20210859
[4]	刘川川, 郝飞翔, 殷月伟, 李晓光. Pt/BiFeO₃/Nb:SrTiO₃异质结的光伏效应和光调控整流特性. 物理学报, 2020, 69(12): 127301. doi: 10.7498/aps.69.20200280
[5]	王文静, 李冲, 张毛毛, 高琨. 共轭聚合物内非均匀场驱动的超快激子输运的动力学研究. 物理学报, 2019, 68(17): 177201. doi: 10.7498/aps.68.20190432
[6]	蔡田怡, 雎胜. 铁电体的光伏效应. 物理学报, 2018, 67(15): 157801. doi: 10.7498/aps.67.20180979
[7]	陈新亮, 陈莉, 周忠信, 赵颖, 张晓丹. Cu2O/ZnO氧化物异质结太阳电池的研究进展. 物理学报, 2018, 67(11): 118401. doi: 10.7498/aps.67.20172037
[8]	左依凡, 李培丽, 栾开智, 王磊. 基于自准直效应的光子晶体异质结偏振分束器. 物理学报, 2018, 67(3): 034204. doi: 10.7498/aps.67.20171815
[9]	张强, 王建元, 罗炳成, 邢辉, 金克新, 陈长乐. La1.3Sr1.7Mn2O7/SrTiO3-Nb异质结的整流和光伏特性. 物理学报, 2016, 65(10): 107301. doi: 10.7498/aps.65.107301
[10]	魏纪周, 张铭, 邓浩亮, 楚上杰, 杜敏永, 严辉. Bi0.8Ba0.2FeO3/La0.7Sr0.3MnO3异质结制备及其交换偏置效应研究. 物理学报, 2015, 64(8): 088101. doi: 10.7498/aps.64.088101
[11]	薛源, 郜超军, 谷锦华, 冯亚阳, 杨仕娥, 卢景霄, 黄强, 冯志强. 薄膜硅/晶体硅异质结电池中本征硅薄膜钝化层的性质及光发射谱研究. 物理学报, 2013, 62(19): 197301. doi: 10.7498/aps.62.197301
[12]	何悦, 窦亚楠, 马晓光, 陈绍斌, 褚君浩. 热原子层沉积氧化铝对硅的钝化性能及热稳定性. 物理学报, 2012, 61(24): 248102. doi: 10.7498/aps.61.248102
[13]	赵赓, 程晓曼, 田海军, 杜博群, 梁晓宇, 吴峰. V2O5电极修饰对C60/Pentacene双层异质结场效应晶体管性能的影响. 物理学报, 2012, 61(21): 218502. doi: 10.7498/aps.61.218502
[14]	张歆, 章晓中, 谭新玉, 于奕, 万蔡华. Al2O3增强的Co2-C98/Al2O3/Si异质结的光伏效应. 物理学报, 2012, 61(14): 147303. doi: 10.7498/aps.61.147303
[15]	陈鹏, 金克新, 陈长乐, 谭兴毅. La0.88 Te0.12 MnO3/Si异质结的整流和光伏特性研究. 物理学报, 2011, 60(6): 067303. doi: 10.7498/aps.60.067303
[16]	李晓溪, 贾天卿, 冯东海, 徐至展. 超短脉冲激光照射下氧化铝的烧蚀机理. 物理学报, 2004, 53(7): 2154-2158. doi: 10.7498/aps.53.2154
[17]	刘红, 陈将伟. 纳米碳管异质结的结构及其电学性质. 物理学报, 2003, 52(3): 664-667. doi: 10.7498/aps.52.664
[18]	汪大云, 刘思敏, 陈晓虎, 赵红娥, 郭儒, 杨立森, 高垣梅, 黄春福, 陆猗. 非相干辐照对LiNbO3:Fe晶体光折变非线性的影响与控制作用. 物理学报, 2003, 52(2): 395-400. doi: 10.7498/aps.52.395
[19]	侯春风, 李师群, 李斌, 孙秀冬. 有外加电场的光伏光折变晶体中的非相干耦合亮-暗屏蔽光伏孤子对. 物理学报, 2001, 50(9): 1709-1712. doi: 10.7498/aps.50.1709
[20]	侯春风, 袁保红, 孙秀冬, 许克彬. 非相干耦合屏蔽光伏孤子对. 物理学报, 2000, 49(10): 1969-1972. doi: 10.7498/aps.49.1969

计量

文章访问数: 9434
PDF下载量: 776
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

搜索

留言板