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Developing thermally conductive polymers is of fundamental interest and technological importance. Common polymers have low thermal conductivities on the order of 0.1 W·m–1·K–1 and thus are regarded as thermal insulators. Compared with the traditional heat conductors (metals and ceramics), polymers have unparalleled combined properties such as light weight, corrosion resistance, electrical insulation and low cost. Turning polymer insulators into heat conductors will provide new opportunities for future thermal management applications. Polymers may replace many metals and ceramics, serving as lightweight heat dissipators in electronics, refrigerators, and electrical vehicles. In this review and perspectives, we discuss the research progress of thermal transport mechanisms in polymers and reveal the relations between thermal conductivity and polymer structural parameters such as bond strength, crystallinity, crystallite size, chain orientation, radius of gyration, and molecular weight. We discuss the advanced strategies for developing thermally conductive polymers by both bottom-up and top-down approaches. We highlight how thermally conductive polymers provide new opportunities for thermal management applications. Finally, we emphasize the future challenges to and opportunities for designing and synthesizing polymers with metal-like thermal conductivity and exploring the thermal transport physics in polymers. We believe that the thermally conductive polymers with their unparalleled combination of characteristics (light weight, electrical insulation, easy processability, corrosion resistance, etc.) promise to possess many existing and unforeseen thermal management applications. -
Keywords:
- thermally conductive polymers /
- thermal conductivity /
- thermal transport mechanisms in polymers /
- thermal management applications
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图 1 微纳尺度及原子尺度下的高分子结构. 高分子链端、无定型链、链缠结、杂质等缺陷都可能成为热载流子散射点, 导致高分子聚合物高分子的热导率比较低 (约0.1 W·m–1·K–1)[24]
Figure 1. Polymer structures at micro-nano scale and atomic scale. Defects such as chain ends, amorphous chains, chain entanglement, impurities in polymers act as heat carrier scattering sites and hinder efficient thermal transport, result in relatively low thermal conductivity (about 0.1 W·m–1·K–1)[24].
图 2 室温下聚乙烯(PE)的热导率实验数据[21,38,39,43-50,58,83,87,94-97]及模拟值[35,54,98]; 室温下聚噻吩(PT)的热导率实验数据[39,40,99,100]及模拟值[56]
Figure 2. Thermal conductivities of polyethylene at room temperature in experimental measurements[21,38,39,43-50,58,83,87,94-97]and simulations[35,54,98]. Thermal conductivities of polythiophene at room temperature in experimental measurements[39,40,99,100]and simulations[56].
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[1] Moore A L, Shi L 2014 Mater. Today 17 163Google Scholar
[2] Schelling P K, Shi L, Goodson K E 2005 Mater. Today 8 30
[3] Pop E, Goodson K E 2006 J. Electron. Packag. 128 102Google Scholar
[4] Chen G 2005 Nanoscale Energy Transport and Conversion: A Parallel Treatment of Electrons, Molecules, Phonons, and Photons (New York: Oxford University Press)
[5] Li Y, Li W, Han T, Zheng X, Li J, Li B, Fan S, Qiu C W 2021 Nat. Rev. Mater. 6 488Google Scholar
[6] Hao M, Li J, Park S, Moura S, Dames C 2018 Nat. Energy 3 899Google Scholar
[7] Xia G, Cao L, Bi G 2017 J. Power Sources 367 90Google Scholar
[8] Feng C P, Yang L Y, Yang J, Bai L, Bao R Y, Liu Z Y, Yang M B, Lan H B, Yang W 2020 Compos. Commun. 22 100528Google Scholar
[9] Huaiyu Y, Koh S, van Zeijl H, Gielen A, Guoqi Z 2011 J. Semicond. 32 014008Google Scholar
[10] Siricharoenpanich A, Wiriyasart S, Srichat A, Naphon P 2019 Case Stud. Therm. Eng. 15 100545Google Scholar
[11] Xu Y, Wang X, Hao Q 2021 Compos. Commun. 24 100617Google Scholar
[12] Chen M, Dongxu O, Liu J, Wang J 2019 Appl. Therm. Eng. 157 113750Google Scholar
[13] Sklan S R, Li B 2018 Natl. Sci. Rev. 5 138Google Scholar
[14] Chen S, Wu Q, Mishra C, Kang J, Zhang H, Cho K, Cai W, Balandin A A, Ruoff R S 2012 Nat. Mater. 11 203Google Scholar
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[16] Pop E, Varshney V, Roy A K 2012 MRS Bull. 37 1273Google Scholar
[17] Chen K, Song B, Ravichandran N K, Zheng Q, Chen X, Lee H, Sun H, Li S, Gamage G A G U, Tian F 2020 Science 367 555Google Scholar
[18] Tian F, Song B, Chen X, Ravichandran N K, Lü Y, Chen K, Sullivan S, Kim J, Zhou Y, Liu T H 2018 Science 361 582Google Scholar
[19] Kang J S, Li M, Wu H, Nguyen H, Hu Y 2018 Science 361 575Google Scholar
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[24] Henry A 2014 Annu. Rev. Heat Transfer 17 485Google Scholar
[25] Chen H, Ginzburg V V, Yang J, Yang Y, Liu W, Huang Y, Du L, Chen B 2016 Prog. Polym. Sci. 59 41Google Scholar
[26] Anderson D 1966 Chem. Rev. 66 677Google Scholar
[27] Guo Y, Ruan K, Shi X, Yang X, Gu J 2020 Compos. Sci. Technol. 193 108134Google Scholar
[28] Choy C 1977 Polymer 18 984Google Scholar
[29] Mehra N, Mu L, Ji T, Yang X, Kong J, Gu J, Zhu J 2018 Appl. Mater. Today 12 92Google Scholar
[30] Chen G 2014 Annu. Rev. Heat Transfer 17 1Google Scholar
[31] Guo Y, Zhou Y, Xu Y 2021 Polymer 233 124168Google Scholar
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[33] Huang C, Qian X, Yang R 2018 Mater. Sci. Eng. , R 132 1Google Scholar
[34] Xu X, Zhou J, Chen J 2020 Adv. Funct. Mater. 30 1904704Google Scholar
[35] Henry A, Chen G 2008 Phys. Rev. Lett. 101 235502Google Scholar
[36] Chen G 2021 Nat. Rev. Phys. 3 555Google Scholar
[37] Fermi E, Pasta P, Ulam S, Tsingou M 1955 Report No. LA-1940 (New Mexico, United States: Los Alamos Scientific Lab.)
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[39] Xu Y, Kraemer D, Song B, Jiang Z, Zhou J, Loomis J, Wang J, Li M, Ghasemi H, Huang X 2019 Nat. Commun. 10 1771Google Scholar
[40] Singh V, Bougher T L, Weathers A, Cai Y, Bi K, Pettes M T, McMenamin S A, Lü W, Resler D P, Gattuso T R 2014 Nat. Nanotechnol. 9 384Google Scholar
[41] Kim G H, Lee D, Shanker A, Shao L, Kwon M S, Gidley D, Kim J, Pipe K P 2015 Nat. Mater. 14 295Google Scholar
[42] Gibson A, Greig D, Sahota M, Ward I, Choy C 1977 J. Polym. Sci., Polym. Lett. Ed. 15 183Google Scholar
[43] Choy C, Luk W, Chen F 1978 Polymer 19 155Google Scholar
[44] Mergenthaler D, Pietralla M, Roy S, Kilian H J M 1992 Macromolecules 25 3500Google Scholar
[45] Cao B Y, Li Y W, Kong J, Chen H, Xu Y, Yung K L, Cai A 2011 Polymer 52 1711Google Scholar
[46] Ma J, Zhang Q, Mayo A, Ni Z, Yi H, Chen Y, Mu R, Bellan L M, Li D 2015 Nanoscale 7 16899Google Scholar
[47] Ronca S, Igarashi T, Forte G, Rastogi S 2017 Polymer 123 203Google Scholar
[48] Zhu B, Liu J, Wang T, Han M, Valloppilly S, Xu S, Wang X 2017 ACS Omega 2 3931Google Scholar
[49] Huang Y F, Wang Z G, Yu W C, Ren Y, Lei J, Xu J Z, Li Z M 2019 Polymer 180 121760Google Scholar
[50] Pan X, Schenning A H, Shen L, Bastiaansen C W 2020 Macromolecules 53 5599Google Scholar
[51] Sweet J, Roth E, Moss M 1987 Int. J. Thermophys. 8 593Google Scholar
[52] Som S 2008 Introduction to Heat transfer (New Delhi: PHI learning Pvt. Ltd.)
[53] Cahill D G, Ford W K, Goodson K E, Mahan G D, Majumdar A, Maris H J, Merlin R, Phillpot S R 2003 J. Appl. Phys. 93 793Google Scholar
[54] Henry A, Chen G, Plimpton S J, Thompson A 2010 Phys. Rev. B. 82 144308Google Scholar
[55] Xiao M, Du B X 2016 High Volt. 1 34Google Scholar
[56] Zhang T, Wu X, Luo T 2014 J. Phys. Chem. C. 118 21148Google Scholar
[57] Shanker A, Li C, Kim G H, Gidley D, Pipe K P, Kim J 2017 Sci. Adv. 3 e1700342Google Scholar
[58] Robbins A B, Drakopoulos S X, Martin-Fabiani I, Ronca S, Minnich A J 2019 Proc. Natl. Acad. Sci. U. S. A. 116 17163Google Scholar
[59] Cevallos J G, Bergles A E, Bar-Cohen A, Rodgers P, Gupta S K 2012 Heat Transfer Eng. 33 1075Google Scholar
[60] Sæther S, Falck M, Zhang Z, Lervik A, He J 2021 Macromolecules 54 6563Google Scholar
[61] Hansen D, Bernier G 1972 Polym. Eng. Sci. 12 204Google Scholar
[62] Liu J, Yang R 2012 Phys. Rev. B. 86 104307Google Scholar
[63] Wei X, Luo T 2019 Phys. Chem. Chem. Phys. 21 15523Google Scholar
[64] Zhang T, Luo T 2016 J. Phys. Chem. B 120 803Google Scholar
[65] Subramanyan H, Zhang W, He J, Kim K, Li X, Liu J 2019 J. Appl. Phys. 125 095104Google Scholar
[66] Zhang T, Luo T 2012 J. Appl. Phys. 112 094304Google Scholar
[67] Wei X, Zhang T, Luo T 2016 Phys. Chem. Chem. Phys. 18 32146Google Scholar
[68] Lin S, Cai Z, Wang Y, Zhao L, Zhai C 2019 Comput. Mater. Sci. 5 126
[69] Akatsuka M, Takezawa Y 2003 J. Appl. Polym. Sci. 89 2464Google Scholar
[70] Ruan K, Zhong X, Shi X, Dang J, Gu J 2021 Mater. Today Phys. 20 100456Google Scholar
[71] Wei X, Huang Z, Koch S, Zamengo M, Deng Y, Minus M L, Morikawa J, Guo R, Luo T 2021 ACS Appl. Polym. Mater. 3 2979Google Scholar
[72] Lee J, Kim Y, Joshi S R, Kwon M S, Kim G H 2021 Polym. Chem. 12 975Google Scholar
[73] Chen A, Wu Y, Zhou S, Xu W, Jiang W, Lü Y, Guo W, Chi K, Sun Q, Fu T 2020 Mater. Adv. 1 1996Google Scholar
[74] Kikugawa G, Desai T G, Keblinski P, Ohara T 2013 J. Appl. Phys. 114 034302Google Scholar
[75] Knappe W, Yamamoto O 1970 Kolloid-Zeitschrift und Zeitschrift für Polymere 240 775
[76] Toberer E S, Zevalkink A, Snyder G J 2011 J. Mater. Chem. 21 15843Google Scholar
[77] Ma H, Ma Y, Tian Z 2019 ACS Appl. Polym. Mater. 1 2566
[78] Nomura R, Yoneyama K, Ogasawara F, Ueno M, Okuda Y, Yamanaka A 2003 Jpn. J. Appl. Phys. 42 5205Google Scholar
[79] Hsieh W-P, Losego M D, Braun P V, Shenogin S, Keblinski P, Cahill D G 2011 Phys. Rev. B. 83 174205Google Scholar
[80] Zhang T, Xu J, Luo T 2020 https://arxiv.org/abs/2009.13708
[81] Deng S, Ma D, Zhang G, Yang N 2021 J. Mater. Chem. A. 9 24472Google Scholar
[82] Deng S, Yuan J, Lin Y, Yu X, Ma D, Huang Y, Ji R, Zhang G, Yang N 2021 Nano Energy 82 105749Google Scholar
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[84] Xu Y, Wang X, Zhou J, Song B, Jiang Z, Lee E M, Huberman S, Gleason K K, Chen G 2018 Sci. Adv. 4 eaar3031Google Scholar
[85] Xie X, Li D, Tsai T H, Liu J, Braun P V, Cahill D G 2016 Macromolecules 49 972Google Scholar
[86] Yu X, Ma D, Deng C, Wan X, An M, Meng H, Li X, Huang X, Yang N 2021 Chin. Phys. Lett. 38 014401Google Scholar
[87] Shrestha R, Li P, Chatterjee B, Zheng T, Wu X, Liu Z, Luo T, Choi S, Hippalgaonkar K, De Boer M P 2018 Nat. Commun. 9 1664Google Scholar
[88] Donovan B F, Warzoha R J, Cosby T, Giri A, Wilson A A, Borgdorff A J, Vu N T, Patterson E A, Gorzkowski E P 2020 Macromolecules 53 11089Google Scholar
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[90] Canetta C, Guo S, Narayanaswamy A 2014 Rev. Sci. Instrum. 85 104901Google Scholar
[91] Lu C, Chiang S W, Du H, Li J, Gan L, Zhang X, Chu X, Yao Y, Li B, Kang F 2017 Polymer 115 52Google Scholar
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