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铁酸铋薄膜光电流的磁场调制研究

霍冠忠 苏超 王可 叶晴莹 庄彬 陈水源 黄志高

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铁酸铋薄膜光电流的磁场调制研究

霍冠忠, 苏超, 王可, 叶晴莹, 庄彬, 陈水源, 黄志高

Magnetic field modulation of photocurrent in BiFeO3 film

Huo Guan-Zhong, Su Chao, Wang Ke, Ye Qing-Ying, Zhuang Bin, Chen Shui-Yuan, Huang Zhi-Gao
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  • BiFeO3作为一种具有体光伏效应的室温多铁材料, 是近年来多功能材料领域的研究热点. 其中磁、光、电等多种性能之间耦合作用的共存带来了丰富而复杂的物理内涵. 利用脉冲激光沉积在导电玻璃(SnO2:F, FTO)衬底上沉积了BiFeO3薄膜, 实验结果表明, 该薄膜具有良好的铁磁和铁电性能, 并通过磁场实现了对薄膜光电性能的调控. 在标准太阳光照的同时施加1.3 kOe (1 Oe = 103/(4π) A/m)磁场下, 磁-光电流变化率达到232.7%. BiFeO3薄膜中的磁-光电流效应来自于光磁电阻效应, 即光生电子在磁场作用下成为自旋光电子, 在材料导带运动过程中受到自旋相关散射而具有光磁电阻效应; 此外, 磁场作用使这些自旋光电子受到的畴壁散射减弱也进一步增强了磁光电流效应. 本文为磁场、光场调控多铁性薄膜的磁、光、电等物理特性提供了参考, 为多功能光电材料领域的器件研究与应用提供了基础.
    BiFeO3 (BFO) is a kind of room temperature multiferroic material with bulk photovoltaic effect, and it has been a research hotspot in the field of multifunctional materials in recent years. The coexistence of the coupling among magnetic, optical, electrical properties brings rich and complex physical connotations. In this work, BiFeO3 thin film is deposited on FTO substrate by pulsed laser deposition, and the solar cell structure with BiFeO3 film used as light absorption layer and Au film serving as electrode is constructed. X-ray diffraction and Raman spectra indicate that the BFO film grown on FTO substrate has a pure phase structure. The experimental results of physical properties indicate that the BFO film possesses good ferromagnetic and ferroelectric properties and obvious photoelectric effect. According to the hysteresis loop, the remanence (Mr) of the sample is 0.8 emu/cm3, and the coercivity (Hc) is 200 Oe at 300 K. In terms of ferroelectricity, the saturation polarization intensity of the sample can reach 0.997 μC/cm2, the residual polarization intensity is 0.337 μC/cm2, and the coercive electric field is 12.45 kV/cm. The above results show that the BFO film has good multiferroic properties. Under solar illumination conditions, the photocurrent density up to 208 mA/cm2 is obtained when a bias voltage 1 V is applied. More importantly, magneto-photocurrent (MPC) effect is found in the BFO film. No matter whether the magnetic field starts to increase from the positive direction or the negative direction, the MPC usually changes with the magnitude of magnetization. When a 1.3 kOe magnetic field is applied, the magneto-photocurrent change rate up to 232.7% is observed under standard solar illumination condition. The results show that the photocurrent of BFO films is greatly improved by a positive magnetic field and negative magnetic field. This magneto-photocurrent effect in BFO thin film comes from the photo-magnetoresistance effect, that is, the photogenerated electrons become spin photoelectrons under the action of an external magnetic field and receive spin-dependent scattering during moving in the conductive band of the material, thus producing the photo-magnetoresistance effect. In addition, the magneto-photocurrent effect is further enhanced by weakening the domain wall scattering of the spin electrons by the magnetic field. This work provides a reference for the modulation effect of magnetic field and light field on the magnetic, optical and electrical properties in multiferroics, and presents a foundation for the research and application of devices in the field of multifunctional optoelectronic materials.
      通信作者: 陈水源, sychen@fjnu.edu.cn
    • 基金项目: 国家自然科学基金(批准号: 11074031)、国家重点研发计划(批准号: 2017YFE0301401)和福建省自然科学基金(批准号: 2020J01192, 2021J01191)资助的课题.
      Corresponding author: Chen Shui-Yuan, sychen@fjnu.edu.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 11074031), the National Key R&D Program of China (Grant No. 2017YFE0301401), and the Natural Science Foundation of Fujian Province, China (Grant Nos. 2020J01192, 2021J01191).
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  • 图 1  BFO薄膜在300 K温度下的(a) XRD图谱和(b)拉曼光谱

    Fig. 1.  The XRD pattern (a) and Raman spectrum (b) of the BFO thin film at 300 K.

    图 2  BFO薄膜在300 K温度下的(a)磁滞回线图和(b)电滞回线图

    Fig. 2.  The M-H hysteresis loop (a) and the P-E hysteresis loops (b) of the BFO film at 300 K.

    图 3  室温下样品J-V曲线在无磁场黑暗条件下及光照下随外磁场增强的响应情况

    Fig. 3.  The J-V curves of the sample at room temperature under dark conditions without magnetic field and under light with the increase of external magnetic field.

    图 4  在偏压分别为(a), (c) 0 V和(b), (d) 1 V时, 室温下样品的(a), (b)光电流随磁场变化曲线以及(c), (d) $ {D}_{{\rm{M}}{\rm{P}}{\rm{C}},{\rm{V}}} $值随磁场变化的响应曲线

    Fig. 4.  Change curves of photocurrent (a), (b) and $ {D}_{{\rm{M}}{\rm{P}}{\rm{C}},{\rm{V}}} $(c), (d) with the alteration of magnetic field for the sample at room temperature with the bias of (a), (c) 0 V and (b), (d) 1 V.

    图 5  (a) Fe3+简并轨道能量、自旋光电子与电子能带态密度示意图; (b)外磁场作用下Fe3+能带移动示意图

    Fig. 5.  (a) Schematic diagram of the Fe3+ degenerate orbital energy, spin photoelectron and electron band density of state; (b) schematic diagram of the Fe3+ band movement under the external magnetic field.

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  • 被引次数: 0
出版历程
  • 收稿日期:  2022-10-27
  • 修回日期:  2023-01-09
  • 上网日期:  2023-03-06
  • 刊出日期:  2023-03-20

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