宽带隙钙钛矿材料及太阳电池的研究进展

崔兴华; 许巧静; 石标; 侯福华; 赵颖; 张晓丹

doi:10.7498/aps.69.20200822

摘要

金属卤化物钙钛矿太阳电池在近几年获得了巨大进展. 目前单结钙钛矿太阳电池转化效率已经达到25.2%. 经过带隙调整得到的1.63 eV及以上的宽带隙钙钛矿太阳电池是制备多结叠层太阳电池中顶部吸收层的最佳材料. 除高效叠层太阳电池外, 宽带隙钙钛矿在光伏建筑一体化以及光解水制氢等领域中也有着广阔的应用前景. 然而这种钙钛矿薄膜本身缺陷较多, 在光照下还容易发生卤素分离, 这也是限制宽带隙钙钛矿太阳电池发展的关键因素. 本文综述了目前宽带隙钙钛矿及太阳电池的发展现状, 最后对其未来发展前景进行了展望.

关键词:

Abstract

Organic-inorganic metal halide perovskites are a new type of photovoltaic material, they have attracted wide attention and made excellent progress in recent years. The power conversion efficiency of a single-junction perovskite solar cell has been increased to 25.2% just within a decade. Meanwhile, crystalline silicon solar cells account for nearly 90% of industrialized solar cells and have a maximum efficiency of 26.7%, approaching to their theoretical limit. It is more difficult to further improve the efficiency of single junction solar cells. It has been shown that multi-junction tandem solar cells prepared by stacking absorption layers with different bandgaps can better use sunlight, which is one of the most promising strategies to break the efficiency limitation of single-junction solar cells. Due to the bandgap tunability and low-temperature solution processability, perovskites stand out among many other materials for manufacturing multi-junction tandem solar cells. Wide bandgap perovskites with a bandgap of 1.63 eV or above have been combined with narrow band gap inorganic absorption layers such as silicon, copper indium gallium selenide, cadmium telluride or narrow bandgap perovskite to produce high efficiency tandem solar cells. In addition to the promoting of the efficiency improvement of solar cells, the wide bandgap perovskites have broad applications in photovoltaic building integration and photocatalytic fields. Therefore, it is very important to explore and develop high quality wide bandgap perovskite materials and solar cells. Unfortunately, the wide bandgap perovskites have several intrinsic weaknesses, including being more vulnerable to the migration of halogen ions under being illuminated, more defects, and greater possibility of energy level mismatching with the charge transport layers than the narrow bandgap counterparts, which limits the further development of the wide bandgap perovskite solar cells. In this review, the development status of wide bandgap perovskite solar cells is summarized and corresponding strategies for improving their performance are put forward. Furthermore, some personal views on the future development of wide bandgap perovskite solar cells are also presented here in this paper.

Keywords:

作者及机构信息

1.
南开大学，光电子薄膜器件与技术研究所，天津　300350

2.
天津市光电子薄膜器件与技术重点实验室，天津　300350

3.
薄膜光电子技术教育部工程研究中心，天津　300350

4.
化学科学与工程协同创新中心，天津　300072

5.
南开大学，可再生能源转换与储存中心，天津　300072

通信作者: 张晓丹, xdzhang@nankai.edu.cn

基金项目: 国家重点研发计划(批准号: 2018YFB1500103)、国家自然科学基金(批准号: 61674084)、高等学校学科创新引智计划(111 计划) (批准号: B16027)、天津市科技项目(批准号: 18ZXJMTG00220)和中央高校基本科研业务费(批准号: 63201171)资助的课题

Authors and contacts

1.
Institute of Photoelectronic Thin Film Devices and Technology, Nankai University, Tianjin 300350, China

2.
Key Laboratory of Photoelectronic Thin Film Devices and Technology of Tianjin, Tianjin 300350, China

3.
Engineering Research Center of Thin Film Photoelectronic Technology, Ministry of Education, Tianjin 300350, China

4.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

5.
Renewable Energy Conversion and Storage Center of Nankai University, Tianjin 300072, China

Corresponding author: Zhang Xiao-Dan, xdzhang@nankai.edu.cn

Funds: Project supported by the National Key Research and Development Program of China (Grant No. 2018YFB1500103), the National Natural Science Foundation of China (Grant No. 61674084), the Overseas Expertise Introduction Project for Discipline Innovation of Higher Education of China (Grant No. B16027), the Science and Technology Project of Tianjin, China (Grant No. 18ZXJMTG00220), and the Fundamental Research Fund for the Central Universities, China (Grant No. 63201171)

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施引文献

图 1 宽带隙钙钛矿太阳电池性能统计图(E_g ≥ 1.63 eV, PCE > 15%)　(a) V_OC与E_g之间的关系, 红色阴影部分表示的是qV_OC与E_g的比值小于0.75, 其中q表示单位电荷量; (b) PCE和E_g之间的关系

Fig. 1. Performance statistics of WBG-PSCs (E_g ≥ 1.63 eV, PCE > 15%): (a) Relationship between V_OC and E_g. The red shaded part indicates that the ratio between qV_OC and E_g is less than 0.75, where q represents the unit charge; (b) relationship between PCE and E_g.

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图 2 (a)钙钛矿结构; (b)不同钙钛矿所对应的容差因子图以及相应的晶体结构^[67]

Fig. 2. (a) Structure of perovskite; (b) corresponding tolerance factor and crystal structure of different perovskites^[67].

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图 3 (a) MAPb(Br_xI_1–x)₃的紫外可见吸收光谱、不同颜色钙钛矿薄膜照片以及带隙随Br含量变化的函数图^[70]; (b) FAPb(Br_1–yI_y)₃的紫外可见吸收光谱和光致发光(PL)光谱^[71]; (c) CsPb(Br_zI_1–z)₃的钙钛矿溶液和对应的光致发光(PL)谱^[79]

Fig. 3. (a) UV-visible absorption spectra, photos of perovskite films with different colors, as well as functional graph between bandgap and bromine content of MAPb(Br_xI_1–x)₃^[70]; (b) UV-visible absorption spectra and photoluminescence (PL) spectra of FAPb(Br_1–yI_y)₃^[71]; (c) photos of CsPb(Br_zI_1–z)₃ solutions and corresponding PL spectra^[79].

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图 4 (a)卤素离子在光照下发生迁移和团簇示意图^[90]; (b) MAPb(Br_0.4I_0.6)₃在光照下的光致发光(PL)光谱, 插图表示初始PL增长率的温度依赖性^[85]; (c)在约50 mW /cm²的条件下, MAPb(Br_0.4I_0.6)₃膜在白光浸泡5 min前(黑色线)、后(红色线)的XRD图谱, 将MAPb(Br_0.2I_0.8)₃膜(绿色虚线)和MAPb(Br_0.7I_0.3)₃膜(棕色虚线)的XRD图谱进行比较^[85]

Fig. 4. (a) Schematic illustration of halogen ion migration and clusters under light^[90]; (b) photoluminescence (PL) spectra of MAPb(Br_0.4I_0.6)₃ under light. The illustration shows the temperature dependence of the initial PL growth rate^[85]; (c) the XRD pattern of MAPb(Br_0.4I_0.6)₃ film before (black) and after (red) white-light soaking for 5 min at about 50 mW/cm². XRD patterns of the MAPb(Br_0.2I_0.8)₃ film (dashed green) and the MAPb(Br_0.7I_0.3)₃ film (dashed brown) are included for comparison^[85].

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图 5 (a) APbI₃钙钛矿的容差因子^[56]; (b) FACs基钙钛矿光稳定性明显提高^[57]; (c) Cs_xFA_1–xPb(Br_yI_1–y)₃材料中的带隙和V_OC 变化^[37]; (d) K⁺钝化作用示意图^[52]

Fig. 5. (a) Tolerance factor of APbI₃^[56]; (b) FACs-based perovskite light stability was improved obviously^[57]; (c) changes of E_g and V_OC in the Cs_xFA_1–xPb(Br_yI_1–y)₃ compositions^[37]; (d) schematic of K⁺ passivation^[52].

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图 6 (a) 3种阳离子的分子构型以及MA⁺空间旋转的示意图^[55]; (b) CsFA和CSMAFA钙钛矿太阳电池最佳J-V曲线和EQE曲线^[55]; (c) Cs⁺和GA⁺混合到钙钛矿晶格以及对带隙的调控曲线^[102]; (d) DMA⁺对钙钛矿带隙的调整^[43]

Fig. 6. (a) The molecular configurations of the three cations and the rotation of MA⁺ in space^[55]; (b) J-V and EQE curves of the best-performing CsFA and CsMAFA PSCs^[55]; (c) Cs⁺ and GA⁺ are mixed into the perovskite lattice and the tuning curves of the E_g^[102]; (d) DMA⁺ adjusts the E_g of perovskite^[43].

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图 7 基于MACl以及MAH₂PO₂添加剂的钙钛矿薄膜SEM图像^[40]

Fig. 7. SEM images of perovskite films based on MACl and MAH₂PO₂ additives^[40].

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图 8 三卤化物钙钛矿的光稳定性　(a), (b)对照组钙钛矿薄膜(Cs25Br20)经过10倍和100倍太阳光照20 min后的PL光谱, 箭头表示PL峰位随时间变化的方向; (c)对照组薄膜的光谱中心随时间的移动, 在更强光照下, 红移变得更加明显; (d), (e)三卤钙钛矿薄膜(Cs25Br20+Cl3)分别经过10倍和100倍太阳光照20 min后的PL光谱; (f)三卤钙钛矿薄膜的光谱中心随时间的移动, 在更强光照下, 蓝移变得更加明显^[44]

Fig. 8. Light stability of triple-halide perovskite: (a), (b) PL spectra of control perovskite films (Cs25Br20) under 10-sun and 100-sun illumination for 20 min, respectively. Arrows indicate the direction of the PL shift over time; (c) the shift of the spectral centroids of control films over time. The red shift becomes more obvious under higher injection; (d), (e) PL spectra of triple-halide perovskites (Cs22Br15+Cl3) under 10-sun and 100-sun illumination for 20 min, respectively; (f) the shift of the spectral centroids of triple-halide perovskites over time. The blue shift becomes more obvious under higher injection^[44].

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图 9 (a)硫氰酸铅添加剂和DMF溶剂辅助退火对钙钛矿薄膜性能的改善^[50]; (b), (c)阴离子工程的钙钛矿太阳电池的器件性能和光稳定性^[45]

Fig. 9. (a) Performance improvement of perovskite film by adding Pb(SCN)₂ and DMF solvent assisted annealing^[50]; (b), (c) the device performance and stability of PSCs with anion engineering^[45].

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图 10 (a)非加快反溶剂萃取(左)和加快反溶剂萃取(右)制备的钙钛矿薄膜SEM图像^[119]; (b)无尿素添加剂(左)和尿素添加剂(右)的700 nm厚钙钛矿薄膜SEM图像^[119]; (c)甲酰胺诱导直接形成钙钛矿相, 抑制非钙钛矿相的形成^[53]; (d)甲酰胺添加剂提高钙钛矿薄膜结晶质量(右)^[53]

Fig. 10. (a) SEM images of perovskite films prepared using no-boosted solvent extraction (BSE) (left) and BSE (right) methods ^[119]; (b) SEM images of thick perovskite films without urea additives (left) and with urea additives (right) ^[119]; (c) formamide induces direct formation of perovskite phase and inhibits the formation of non-perovskite phase^[53]; (d) improvement of perovskite film crystallization quality by formamide additives (right)^[53].

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图 11 (a) BA分子与钙钛矿薄膜表面作用示意图^[49]; (b)用BABr的异丙醇溶液处理钙钛矿薄膜表面形成二维钙钛矿薄层^[59]; (c)经过BABr溶液处理的钙钛矿太阳电池J-V曲线⁵⁹; (d) BABr溶液处理的钙钛矿太阳电池稳定功率输出曲线(SPCE)⁵⁹; (e)在连续照明(AM 1.5 G)下测量的最优电池的稳态开路电压(V_OC)⁵⁹; (f), (g)两种电池的开路电压和效率统计^[59]

Fig. 11. (a) Schematic of the impact of BA modification on the perovskite film^[49]; (b) the perovskite film surface was treated with BABr solution to form a 2D perovskite thin layer^[59]; (c) J-V and (d) SPCE curve of PSC with and without BABr treatment^[59]; (e) steady-state V_OC of the best-performing PSC measured under continuous illumination (AM 1.5 G)^[59]; (f), (g) V_OC and PCE statistics of two kinds of PSCs^[59].

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图 12 宽带隙钙钛矿、窄带隙钙钛矿和常用电荷传输层的能带图

Fig. 12. Energy band schematic of wide bandgap perovskite, narrow bandgap perovskite, and commonly used charge transport layers.

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图 13 (a) 2T叠层太阳电池的理论效率图^[81]; (b), (c) N-I-P型和P-I-N型2T钙钛矿/硅TSCs结构示意图(TCO: 透明导电氧化物, AR coating: 抗反射膜)

Fig. 13. (a) Theoretical efficiency limit for 2T tandem solar cells; (b), (c) schematics of device structures for N-I-P and P-I-N 2T perovskite/silicon TSCs (TCO: Transparent Conductive Oxide. AR coating: Antireflective coating).

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表 1 宽带隙钙钛矿太阳电池性能统计(E_g ≥ 1.63 eV, PCE > 15%)

Table 1. WBG-PSCs performance statistics (E_g ≥ 1.63 eV and PCE > 15%).

Type	Perovskite	E_g/eV	V_OC/V	qV_OC/E_g	J_SC/mA·cm^–2	FF/%	PCE/%	Ref.
p-i-n	MAPbI_2.5Br_0.5	1.72	1.060	0.61	18.30	78.2	16.60	[35]
p-i-n	(FA_0.83MA_0.17)_0.95Cs_0.05Pb(I_0.6Br_0.4)₃	1.71	1.210	0.71	19.70	77.5	18.50	[36]
p-i-n	FA_0.6Cs_0.4Pb(I_0.7Br_0.3)₃	1.75	1.170	0.67	17.50	80.0	16.30	[37]
p-i-n	FA_0.83MA_0.17Pb(I_0.6Br_0.4)₃	1.72	1.150	0.67	19.40	77.0	17.20	[38]
p-i-n	FA_0.8Cs_0.2Pb(I_0.7Br_0.3)₃	1.75	1.240	0.71	17.92	81.9	18.19	[39]
p-i-n	(FA_0.65MA_0.20Cs_0.15)Pb(I_0.8Br_0.2)₃	1.68	1.170	0.70	21.20	79.8	19.50	[27]
p-i-n	Cs_0.15(FA_0.83MA_0.17)_0.85Pb(I_0.8Br_0.2)₃	1.64	1.190	0.73	19.50	80.2	18.60	[40]
p-i-n	CsPbI₃	1.73	1.160	0.67	17.70	78.6	16.10	[41]
p-i-n	CsPbI₂Br	1.80	1.230	0.67	15.26	78.0	15.19	[42]
p-i-n	FA_0.6Cs_0.3DMA_0.1PbI_2.4Br_0.6	1.70	1.200	0.70	19.60	82.0	19.40	[43]
p-i-n	FA_0.75Cs_0.25Pb(I_0.8Br_0.2)₃	1.68	1.217	0.72	20.18	83.6	20.42	[44]
p-i-n	(FA_0.65MA0_.2Cs_0.15)Pb(I_0.8Br_0.2)₃	1.67	1.200	0.72	NA	NA	20.70	[45]
p-i-n	(FA_0.64MA_0.20Cs_0.15)Pb_0.99(I_0.79Br_0.2)₃	1.68	1.196	0.71	21.65	81.5	21.00	[46]
n-i-p	Rb_0.05(FA_0.75MA_0.15Cs_0.1)_0.95PbI₂Br	1.73	1.120	0.71	19.40	73.0	15.90	[47]
n-i-p	FA_0.83Cs_0.17Pb(I_0.6Br_0.4)₃	1.75	1.160	0.66	18.27	78.5	16.28	[48]
n-i-p	FA_0.85Cs_0.15Pb(I_0.73Br_0.27)₃	1.72	1.240	0.72	19.83	73.7	18.13	[49]
n-i-p	FA_0.8Cs_0.2Pb(I_0.7Br_0.3)₃	1.75	1.250	0.71	18.53	79.0	18.27	[50]
n-i-p	MAPb(Br_0.2I_0.8)₃	1.72	1.120	0.65	17.30	82.3	15.90	[51]
n-i-p	K_0.1(Cs_0.06FA_0.79MA_0.15)_0.9Pb(I_0.4Br_0.6)₃	1.78	1.230	0.69	17.90	79.0	17.50	[52]
n-i-p	FA_0.83Cs_0.17Pb(I_0.6Br_0.4)₃	1.75	1.230	0.70	18.34	79.0	17.80	[53]
n-i-p	Cs_0.17FA_0.83PbI_2.2Br_0.8	1.72	1.270	0.74	19.30	77.4	18.60	[54]
n-i-p	Cs_0.12MA_0.05FA_0.83Pb(I_0.6Br_0.4)₃	1.74	1.250	0.72	19.00	81.5	19.10	[55]
n-i-p	Rb₅(Cs₅MAFA)₉₅Pb(I_0.83Br_0.17)₃	1.63	1.240	0.76	22.80	81.0	21.60	[56]
n-i-p	FA_0.83Cs_0.17Pb(I_0.6Br_0.4)₃	1.74	1.200	0.70	19.40	75.1	17.00	[57]
n-i-p	FA_0.17Cs_0.83PbI_2.2Br_0.8	1.72	1.244	0.72	19.80	75.0	18.60	[51]
n-i-p	Cs_0.2FA_0.8Pb(I_0.75Br_0.25)₃	1.65	1.220	0.74	21.20	80.5	20.70	[55]
n-i-p	BA_0.09(FA_0.83 Cs_0.17)_0.91Pb(I_0.6Br_0.4)₃	1.72	1.180	0.69	19.80	73.0	17.30	[38]
n-i-p	FA_0.15Cs_0.85Pb(I_0.73Br_0.27)₃	1.72	1.240	0.72	19.83	73.7	18.10	[58]
n-i-p	FA_0.83Cs_0.17Pb(I_0.6Br_0.4)₃	1.72	1.310	0.76	19.30	78.0	19.50	[59]
n-i-p	Rb_0.05Cs_0.095 MA_0.1425 FA_0.7125PbI₂Br	1.72	1.205	0.70	18.00	78.9	17.10	[54]
n-i-p	CsPbI₃	1.73	1.080	0.62	18.41	79.32	15.71	[60]
n-i-p	CsPbI₂Br	1.80	1.230	0.68	16.79	77.81	16.07	[61]
n-i-p	β-CsPbI₃	1.68	1.110	0.66	20.23	82.0	18.40	[62]
n-i-p	CsPbI_3-xBr_x	1.77	1.234	0.69	18.30	82.5	18.64	[63]
n-i-p	CsPbI₂Br	1.80	1.270	0.71	15.40	79.0	15.50	[64]
注: NA表示文献中没有给出具体数值; FF表示填充因子.

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表 2 钙钛矿中常用离子有效半径^[56,72]

Table 2. Effective radius of commonly used ions in perovskite^[56,72].

序号	钙钛矿中常用离子	有效半径R/pm
1	胍离子(GA⁺)	278
2	二甲胺离子(DMA⁺)	272
3	甲脒离子(FA⁺)	253
4	甲胺离子(MA⁺)	217
5	铯离子(Cs⁺)	167
6	铷离子(Rb⁺)	152
7	钾离子(K⁺)	138
8	钠离子(Na⁺)	102
9	铅离子(Pb²⁺)	119
10	锡离子(Sn²⁺)	112
11	碘离子(I^–)	220
12	溴离子(Br^–)	196
13	氯离子(Cl^–)	181

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表 3 近年来典型的2T钙钛矿/硅TSCs的详细性能参数总结

Table 3. Summary of detailed performance of typical 2T perovskite/silicon TSCs in recent years.

Type	Perovskite	E_g/eV	V_OC/V	Jsc/mA·cm^–2	FF/%	PCE/%	Year	Area/cm²	Ref.
N-I-P	MAPbI₃	1.61	1.580	11.50	75.00	13.70	2015	1.00	[15]
	FA_0.83MA_0.17Pb(I_0.84Br_0.16)₃	1.63	1.785	14.00	79.50	19.90	2016	0.16	[133]
	MAPbI₃	1.60	1.692	15.80	79.90	21.40	2016	0.17	[134]
	MAPbI₃	1.60	1.701	16.10	70.10	19.20	2016	1.22	[134]
	Cs_0.19MA_0.81PbI₃	1.59	1.751	18.80	77.10	22.70	2018	0.25	[135]
	Cs_0.19MA_0.81PbI₃	1.59	1.779	16.50	74.10	21.70	2018	1.43	[135]
	Cs_0.19FA_0.81Pb(I_0.78Br_0.22)₃	1.63	1.769	16.50	65.40	19.10	2018	12.96	[135]
	MA_0.37FA_0.48Cs_0.15PbI_2.01Br_0.99	1.69	1.703	15.26	79.20	20.57	2017	0.03	[136]
	FA_0.5MA_0.38Cs_0.12PbI_2.04Br_0.96	1.69	1.655	16.50	81.10	22.22	2018	0.06	[137]
	FA_0.75MA_0.25 Pb(I_0.76B_0.24)₃	1.65	1.710	15.49	71.00	18.81	2018	0.13	[138]
	Cs_0.08FA_0.74MA_0.18Pb(I_0.88Br_0.12)₃	1.65	1.780	17.82	75.00	23.73	2018	0.13	[139]
	Cs_0.1(FA_0.75MA_0.25)_0.9Pb(I_0.78Br_0.22)₃	1.67	1.830	16.74	70.00	21.31	2019	0.13	[133]
	Cs _0.08FA_0.69MA_0.23Pb(I_0.78Br₂₂)₃	1.67	1.750	16.89	74.18	21.93	2019	0.13	[140]
	CsRbFAMAPbI_3-xBr_x	1.62	1.763	17.80	78.10	24.50	2018	1.00	[132]
P-I-N	Cs_0.17FA_0.83Pb(Br_0.17I_0.83)₃	1.63	1.650	18.10	79.00	23.60	2017	1.00	[141]
	FA _0.75Cs_0.25Pb(I_0.8Br_0.2)₃	1.68	1.770	18.40	77.00	25.00	2018	1.00	[142]
	Cs_0.05(MA_0.17FA_0.83)Pb_1.1(I_0.83Br_0.17)₃	1.60	1.760	18.50	78.50	25.50	2018	0.81	[143]
	Cs_xFA_1-xPb(I, Br)₃	1.60	1.788	19.50	73.10	25.20	2018	1.42	[144]
	Cs_xFA_1-x Pb(I, Br)₃	1.60	1.741	19.50	74.70	25.40	2018	1.42	[145]
	Cs_0.15(FA_0.83MA_0.17)_0.85Pb(I_0.8Br_0.2)₃	1.64	1.800	17.80	79.40	25.40	2018	0.49	[40]
	Cs_0.05(FA_0.83MA_0.17)_0.95Pb(I_0.82Br_0.18)₃	1.63	1.792	19.02	74.60	25.43	2019	1.00	[146]
	Cs_0.1MA_0.9Pb(I_0.9Br_0.1)₃	1.60	1.820	19.20	75.30	26.20	2020	NA	[147]
	Cs _0.25FA_0.75Pb(I_0.85Br_0.15Cl_0.05)₃	1.67	1.890	19.10	75.30	27.04	2020	1.00	[44]
	Cs_0.05MA_0.15FA_0.8Pb(I_0.75Br_0.25)₃	1.68	1.700	19.80	77.00	25.70	2020	0.83	[46]
	(FA_0.65MA_0.2Cs_0.15)Pb(I_0.8Br_0.2)₃	1.68	1.818	18.90	76.40	26.20	2020	1.00	[45]
注: NA表示文献中没有给出具体数值.

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