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Research progress and application prospect of Fe-based soft magnetic amorphous/nanocrystalline alloys

Yao Ke-Fu Shi Ling-Xiang Chen Shuang-Qin Shao Yang Chen Na Jia Ji-Li

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Research progress and application prospect of Fe-based soft magnetic amorphous/nanocrystalline alloys

Yao Ke-Fu, Shi Ling-Xiang, Chen Shuang-Qin, Shao Yang, Chen Na, Jia Ji-Li
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  • Amorphous alloy is a kind of metallic materials prepared by rapidly cooling the alloy melt through hindering crystallization in cooling process. Due to the unique structure of atomic random packing, Fe-based amorphous alloys exhibit not only structural and property isotropy, but also small structural correlation length, small magnetic anisotropic constant, and then small coercivity Hc. Like crystalline Fe-based alloys, Fe-based amorphous alloys also possess high saturation induction Bs. As a result, research on engineering applications of Fe-based amorphous alloys has been promoted by their excellent soft magnetic properties. Now Fe-based soft magnetic amorphous/nanocrystalline alloys have been produced and applied to various areas on a large scale. Here in this paper, the processes of discovery, development and application of Fe-based soft magnetic amorphous alloys are reviewed, and the effects of chemical composition, structure and preparation technology on the soft magnetic properties are introduced and discussed. The obtained theoretic results and the technological innovation show that the great contributions have been made to the development and application of Fe-based soft magnetic amorphous/crystalline alloys. Based on the progress of structure and soft magnetic property and our understanding, the development process of the fundamental research and the application progress of Fe-based soft magnetic amorphous alloys could be divided into three periods. In addition, the present challenge topics in their researches and applications are proposed.
      Corresponding author: Yao Ke-Fu, kfyao@tsinghua.edu.cn
    • Funds: Project supported by the State Key Research and Development Program of China (Grant No. 2016YB0300500) and the National Natural Science Foundation of China (Grant No. 51571127).
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    [2]

    Klement W, Willens R H, Duwez P 1960 Nature 187 869

    [3]

    Duwez P, Lin S C H 1967 J. Appl. Phys. 38 4096

    [4]

    Pond R, Maddin R 1969 Trans. TMS-AIME 245 2475

    [5]

    Hasegawa R, OHandley R C 1979 J. Appl. Phys. 50 1551

    [6]

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    [16]

    Hasegawa R, Chien C L 1976 Solid State Commun. 18 913

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    Fujimori H, Yoshimoto H, Masumoto T, Mitera T 1981 J. Appl. Phys. 52 189

    [18]

    Narasimhan M C 1979 US Patent 4 142 571

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    Luborsky F E, Walter J L 1980 US Patent 4 217 135

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    DeCristofaro N J, Freilich A, Nathasingh D M 1980 US Patent 4 219 355

    [21]

    Zhou S X, Lu Z C, Chen J C 2002 Physics 31 430(in Chinese) [周少雄, 卢志超, 陈金昌 2002 物理 31 430]

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    Herzer G 2005 J. Magn. Magn. Mater. 294 99

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    Herzer G 2013 Acta Mater. 61 718

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    Hono K, Ping D, Ohnuma M, Onodera H 1999 Acta Mater. 47 997

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    Suzuki K, Makino A, Inoue A, Masumoto T 1991 J. Appl. Phys. 70 6232

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    Willard M A, Laughlin D E, McHenry M E, Thoma D, Sickafus K, Cross J O, Harris V 1998 J. Appl. Phys. 84 6773

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    Ogawa Y, Naoe M, Yoshizawa Y, Hasegawa R 2006 J. Magn. Magn. Mater. 304 e675

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    Makino A, Kubota T, Chang C, Makabe M, Inoue A 2007 Mater. Trans. 48 3024

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    Makino A, Men H, Kubota T, Yubuta K, Inoue A 2009 Mater. Trans.. 50 204

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    Matsuura M, Nishijima M, Takenaka K, Takeuchi A, Ofuchi H, Makino A 2015 J. Appl. Phys. 117 17A324

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    Gao J E, Li H X, Jiao Z B, Wu Y, Chen Y H, Yu T, L Z P 2011 Appl. Phys. Lett. 99 052504

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    Liu F J, Yao K F, Ding H Y 2011 Intermetallics 19 1674

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    Zhang J, Chang C, Wang A, Shen B 2012 J. Non-Cryst. Solids 358 1443

    [36]

    Wang A, Zhao C, Men H, He A, Chang C, Wang X 2015 J. Alloy. Compd. 630 209

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    Ohta M, Yoshizawa Y 2011 J. Phys. D: Appl. Phys. 44 064004

    [38]

    Kong F, Men H, Liu T, Shen B 2012 J. Appl. Phys. 111 07A311

    [39]

    Fan X, Men H, Ma A, Shen B 2013 J. Magn. Magn. Mater. 326 22

    [40]

    Xiang Z, Wang A, Zhao C, Men H, Wang X, Chang C 2015 J. Alloy. Compd. 622 1000

    [41]

    Sharma P, Zhang X, Zhang Y, Makino A 2015 Scripta Mater. 95 3

    [42]

    Jafari S, Beitollahi A, Yekta B E, Ohkubo T, Budinsky V, Marsilius M, Herzer G, Hono K 2016 J. Alloy. Compd. 674 136

    [43]

    Suzuki K, Parsons R, Zang B, Onodera K, Kishimoto H, Kato A 2017 Appl. Phys. Lett. 110 012407

    [44]

    Li J F, Liu X, Zhao S F, Ding H Y, Yao K F 2015 J. Magn. Magn. Mater. 386 107

    [45]

    Li J F, Shao Y, Liu X, Yao K F 2015 Sci. Bull. 60 396

  • [1]

    Gubanov A I 1960 Soviet Physics-Solid State 30 275

    [2]

    Klement W, Willens R H, Duwez P 1960 Nature 187 869

    [3]

    Duwez P, Lin S C H 1967 J. Appl. Phys. 38 4096

    [4]

    Pond R, Maddin R 1969 Trans. TMS-AIME 245 2475

    [5]

    Hasegawa R, OHandley R C 1979 J. Appl. Phys. 50 1551

    [6]

    Luborsky F E, Becker J J, McCarry R O 1975 IEEE Trans. Magn. Mag. 11 1644

    [7]

    Hasegawa R, OHandley R C, Tanner L E, Ray R, Kavesh S 1976 Appl. Phys. Lett. 29 219

    [8]

    Hasegawa R, Narasimhan M C, DeCristofaro N 1978 J. Appl. Phys. 49 1712

    [9]

    Hasegawa R, Ray R 1978 J. Appl. Phys. 49 4178

    [10]

    Luborsky F E, Walter J L 1980 US Patent. 4 217 135

    [11]

    Hatta S, Egami T, Graham C D 1979 Appl. Phys. Lett. 34 113

    [12]

    Sherwood R C, Gyorgy E M, Chen H S, Ferris S D, Norman G, Leamy H J 1975 AIP Conf. Proc. 24 745

    [13]

    OHandley R C, Mendelson L I, Nesbitt E A 1976 IEEE Trans. Magn. Mag. 12 942

    [14]

    Simpson A W, Brambley D R 1971 Phys. Status Solidi 43 291

    [15]

    Chi G C, Cargill G S 1976 Mater. Sci. Eng. 23 155

    [16]

    Hasegawa R, Chien C L 1976 Solid State Commun. 18 913

    [17]

    Fujimori H, Yoshimoto H, Masumoto T, Mitera T 1981 J. Appl. Phys. 52 189

    [18]

    Narasimhan M C 1979 US Patent 4 142 571

    [19]

    Luborsky F E, Walter J L 1980 US Patent 4 217 135

    [20]

    DeCristofaro N J, Freilich A, Nathasingh D M 1980 US Patent 4 219 355

    [21]

    Zhou S X, Lu Z C, Chen J C 2002 Physics 31 430(in Chinese) [周少雄, 卢志超, 陈金昌 2002 物理 31 430]

    [22]

    Herzer G 2005 J. Magn. Magn. Mater. 294 99

    [23]

    Herzer G 2013 Acta Mater. 61 718

    [24]

    Yoshizawa Y, Oguma S, Yamauchi K 1988 J. Appl. Phys. 64 6044

    [25]

    Hono K, Ping D, Ohnuma M, Onodera H 1999 Acta Mater. 47 997

    [26]

    Suzuki K, Makino A, Inoue A, Masumoto T 1991 J. Appl. Phys. 70 6232

    [27]

    Willard M A, Laughlin D E, McHenry M E, Thoma D, Sickafus K, Cross J O, Harris V 1998 J. Appl. Phys. 84 6773

    [28]

    Ogawa Y, Naoe M, Yoshizawa Y, Hasegawa R 2006 J. Magn. Magn. Mater. 304 e675

    [29]

    Makino A, Kubota T, Chang C, Makabe M, Inoue A 2007 Mater. Trans. 48 3024

    [30]

    Makino A, Men H, Kubota T, Yubuta K, Inoue A 2009 Mater. Trans.. 50 204

    [31]

    Makino A, Men H, Kubota T, Yubuta K, Inoue A 2009 IEEE Trans. Magn. 45 4302

    [32]

    Matsuura M, Nishijima M, Takenaka K, Takeuchi A, Ofuchi H, Makino A 2015 J. Appl. Phys. 117 17A324

    [33]

    Gao J E, Li H X, Jiao Z B, Wu Y, Chen Y H, Yu T, L Z P 2011 Appl. Phys. Lett. 99 052504

    [34]

    Liu F J, Yao K F, Ding H Y 2011 Intermetallics 19 1674

    [35]

    Zhang J, Chang C, Wang A, Shen B 2012 J. Non-Cryst. Solids 358 1443

    [36]

    Wang A, Zhao C, Men H, He A, Chang C, Wang X 2015 J. Alloy. Compd. 630 209

    [37]

    Ohta M, Yoshizawa Y 2011 J. Phys. D: Appl. Phys. 44 064004

    [38]

    Kong F, Men H, Liu T, Shen B 2012 J. Appl. Phys. 111 07A311

    [39]

    Fan X, Men H, Ma A, Shen B 2013 J. Magn. Magn. Mater. 326 22

    [40]

    Xiang Z, Wang A, Zhao C, Men H, Wang X, Chang C 2015 J. Alloy. Compd. 622 1000

    [41]

    Sharma P, Zhang X, Zhang Y, Makino A 2015 Scripta Mater. 95 3

    [42]

    Jafari S, Beitollahi A, Yekta B E, Ohkubo T, Budinsky V, Marsilius M, Herzer G, Hono K 2016 J. Alloy. Compd. 674 136

    [43]

    Suzuki K, Parsons R, Zang B, Onodera K, Kishimoto H, Kato A 2017 Appl. Phys. Lett. 110 012407

    [44]

    Li J F, Liu X, Zhao S F, Ding H Y, Yao K F 2015 J. Magn. Magn. Mater. 386 107

    [45]

    Li J F, Shao Y, Liu X, Yao K F 2015 Sci. Bull. 60 396

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  • Received Date:  28 June 2017
  • Accepted Date:  19 October 2017
  • Published Online:  05 January 2018

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