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大面积单层二硫化钼的制备及其光电性能

武鹏 谈论 李炜 曹立伟 赵俊博 曲尧 李昂

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大面积单层二硫化钼的制备及其光电性能

武鹏, 谈论, 李炜, 曹立伟, 赵俊博, 曲尧, 李昂

Preparation and photoelectric property of large scale monolayer MoS2

Wu Peng, Tan Lun, Li Wei, Cao Li-Wei, Zhao Jun-Bo, Qu Yao, Li Ang
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  • 过渡金属硫族化合物(TMDCs)材料具有优异的电学和光电性能, 在下一代光电子器件中具有广阔的应用前景. 然而, 大面积均匀生长单层的TMDCs仍然具有相当大的挑战. 本工作提出了一种简单而有效的利用化学气相沉积(CVD)制备大面积单层二硫化钼(MoS2)的方法, 并通过调整氧化物前驱体的比例, 调整MoS2单晶/薄膜生长. 随后, 利用叉指电极掩膜板制备出单层MoS2薄膜光电探测器. 最后, 在405 nm激光激发下, 不同电压和不同激光功率条件下均表现出高稳定和可重复的光电响应, 响应时间可达毫秒(ms)量级. 此外, 该光电探测器实现了405—830 nm的可见光到近红外的宽光谱检测范围, 光响应度(R)高达291.7 mA/W, 光探测率(D* )最高达1.629 × 109 Jones. 基于该CVD制备的单层MoS2薄膜光电探测器具有成本低、能大规模制备, 且在可见光到近红外的宽光谱范围内具有良好的稳定性和重复性的优点, 为未来电子和光电子器件的应用提供了更多的可能性.
    Transition metal dichalcogenide (TMDC) monolayers exhibit enhanced electrical and optoelectrical properties, which are promising for next-generation optoelectronic devices. However, large-scale and uniform growth of TMDC monolayers with large grain size is still a considerable challenge. Presented in this work is a simple and effective approach to fabricating largescale molybdenum (MoS2) disulfide monolayers by chemical vapor deposition (CVD) method. It is found that MoS2 grows from single crystal into thin film with the increase of oxide precursor proportion. The photodetector of large scale monolayer layer MoS2 film is fabricated by depositing metal electrodes on the interdigital electrode mask through using thermal evaporation coating. Finally, the highly stable and repeatable photoelectric responses under the conditions of different voltages and different laser power are characterized under 405-nm laser excitation, with response time decreasing down to the order of milliseconds (ms). In addition, the photodetector achieves a wide spectral detection range from 405 nm to 830 nm, that is, from visible light to near-infrared light wavelength range, with optical response (R) of 291.7 mA/W and optical detection rate (D*) of 1.629×109 Jones. The monolayer MoS2 thin film photodetector demonstrated here has the advantages of low cost, feasibility of large-scale preparation, and good stability and repeatability in the wide spectrum range from visible light to near infrared light wavelength, providing the possibilities for future applications of electronic and optoelectronic devices .
      通信作者: 李昂, ang.li@bjut.edu.cn
    • 基金项目: 北京卓越科学家项目 (批准号: BJJWZYJH01201910005018)和国家重点研发计划(批准号: 2021YFA1200201)资助的课题.
      Corresponding author: Li Ang, ang.li@bjut.edu.cn
    • Funds: Project supported by the Beijing Outstanding Young Scientists Projects, China (Grant No. BJJWZYJH01201910005018) and the National Key Research and Development Program, China (Grant No. 2021YFA1200201).
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  • 图 1  (a) CVD生长单层MoS2薄膜实验装置示意图; (b)化学反应区放大图; (c) CVD生长过程温度曲线

    Fig. 1.  (a) CVD experimental equipment for MoS2 synthesis; (b) enlarged view of the chemical reaction zone; (c) temperature curve of CVD growth process.

    图 2  (a)—(d)不同MoO3前驱体量下制备的MoS2的SEM形貌; (e) MoS2覆盖率随前驱体量的变化曲线; (f) MoS2的AFM照片(插图)和图中黑线高度随位置的变化曲线

    Fig. 2.  (a)–(d) SEM morphologies of MoS2 prepared under different volumes of MoO3 precursor; (e) curve of MoS2 coverage with precursor volume; (f) the height of MoS2 as a function of position marked as black line in the inset, inset is AFM photograph of MoS2.

    图 3  (a) MoS2单晶光学显微镜图像; (b)单晶MoS2的拉曼成像; (c) Si/SiO2基底拉曼成像; (d)对应图(a)中各点的拉曼光谱; (e) MoS2薄膜的光学显微镜图像; (f) MoS2薄膜的拉曼成像; (g) Si/SiO2基底拉曼成像; (h)图(e)各点对应的拉曼光谱

    Fig. 3.  (a) Optical microscope image of single crystal MoS2; (b) Raman mapping of single crystal MoS2; (c) Raman mapping of Si/SiO2 substrate; (d) Raman spectra of each point in Fig. (a); (e) optical microscope image of thin film MoS2; (f) Raman mapping of thin film MoS2; (g) Raman mapping of Si/SiO2 substrate; (h) Raman spectra of each point in Fig. (e).

    图 4  (a)叉指电极装置示意图; (b) Au和Ti/Au电极上的电流和电压曲线, 插图是MoS2叉指器件实物图

    Fig. 4.  (a) Schematic diagram of interdigital device; (b) the current and voltage curve with Au and Ti/Au electrodes, the inset shows the image of the MoS2 interdigital device.

    图 5  不同电压(a)和光功率(b)条件的电流随时间变化关系; 光电探测器件的响应度和探测率随波长(c)和光功率(d)的变化关系; 器件的响应上升时间(e)和下降恢复时间(f)

    Fig. 5.  The relation of current with time under different voltage conditions (a) and different optical power conditions (b); the relationship between the responsivity and the detection rate of the photodetector with wavelength (c) and with optical power (d); the rise time (e) and the recovery time (f) of the photodetector.

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    [2]

    Li X F, Yang L M, Si M W, Li S C, Huang M Q, Ye P D, Wu Y Q 2015 Adv. Mater. 27 1547Google Scholar

    [3]

    Radisavljevic B, Radenovic A, Brivio J, Giacometti V, Kis A 2011 Nat. Nanotechnol. 6 147Google Scholar

    [4]

    Kaushik V, Ahmad M, Agarwal K, Varandani D, Belle B D, Das P, Mehta B R 2020 J. Phys. Chem. C 124 23368Google Scholar

    [5]

    Bagot P A J, Silk O B W, Douglas J O, Pedrazzini S, Crudden D J, Martin T L, Hardy M C, Moody M P, Reed R C 2017 Acta Mater. 125 156Google Scholar

    [6]

    Wang X D, Wang P, Wang J L, Hu W D, Zhou X H, Guo N, Huang H, Sun S, Shen H, Lin T, Tang M H, Liao L, Jiang A Q, Sun J L, Meng X J, Chen X S, Lu W, Chu J H 2015 Adv. Mater. 27 6575Google Scholar

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    Lee J, Pak S, Lee Y W, Cho Y, Hong J, Giraud P, Shin H S, Morris S M, Sohn J I, Cha S, Kim J M 2017 Nat. Commun. 8 14734Google Scholar

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  • 被引次数: 0
出版历程
  • 收稿日期:  2023-02-24
  • 修回日期:  2023-04-04
  • 上网日期:  2023-04-11
  • 刊出日期:  2023-06-05

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