背电极材料、结构以及厚度等影响钙钛矿太阳能电池性能的研究

王剑涛; 肖文波; 夏情感; 吴华明; 李璠; 黄乐

doi:10.7498/aps.70.20211037

摘要

背电极是影响钙钛矿太阳电池性能的一个重要因素. 本文采用COMSOL软件仿真研究了背电极材料、结构、厚度对电池性能的影响规律. 发现相对于背电极金属的功函数, 其阻值对电池性能影响小. 背电极结构除了阻值会影响电池性能, 还存在影响电池性能的其他因素. 蜂窝结构背电极中, 考虑制作难易程度的情况下, 圆形半径约等于边缘间距时性价比最高. 预测背电极中每增加10%的孔隙, 电池性能大约提升5%. 背电极阻值随着厚度的增加而减小, 考虑工艺、成本等因素的前提下, 最佳的厚度应在100—150 nm之间.

关键词:

Abstract

The back electrode is an important factor affecting the performance of perovskite solar cells. In this paper, the effects of back electrode material, structure and thickness on the performance of perovskite solar cells are studied by using COMSOL software. It is found that compared with the work function of the back electrode metal, its resistance has small effect on solar cell performance. Besides the back electrode structures affecting cell performance, there are other factors affecting cell performance. In terms of the back electrodes with honeycomb structure, considering the difficulty in fabricating, the best cost performance occurs when the radius of the circle is approximately equal to the edge spacing. It is predicted that the cell performance will be improved by about 5% in porosity with increasing 10% in the back electrode. The resistance of the back electrode decreases with its thickness increasing. Considering the process and cost, the optimal thickness should be between 100 nm and 150 nm.

Keywords:

作者及机构信息

1.
南昌航空大学, 无损检测技术教育部重点实验室, 南昌　330063

2.
江西省光电检测技术工程实验室, 南昌　330063

3.
南昌大学材料科学与工程学院, 南昌　330031

4.
广东工业大学材料与能源学院, 广州　450001

通信作者: 肖文波, xiaowenbo1570@163.com

基金项目: 国家自然科学基金(批准号: 12064027, 62065014, 62064007)、无损检测技术教育部重点实验室开放基金(批准号: EW201908442, EW201980090)和江西省主要学科学术和技术带头人培养计划-领军人才项目(批准号: 20204BCJ22002)资助的课题

Authors and contacts

1.
Key Laboratory of Nondestructive Testing, Ministry of Education, Nanchang Hangkong University, Nanchang 330063, China

2.
Jiangxi Engineering Laboratory for Optoelectronics Testing Technology, Nanchang Hangkong University, Nanchang 330063, China

3.
School of materials science and engineering, Nanchang University, Nanchang 330031, China

4.
School of materials and energy, Guangdong University of technology, Guangzhou 450001, China

Corresponding author: Xiao Wen-Bo, xiaowenbo1570@163.com

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 12064027, 62065014, 62064007), the Open Fund of the Key Laboratory of Nondestructive Testing of Ministry of Education, China (Grant Nos. EW201908442, EW201980090), and the Training Plan for Academic and Technical Leaders of Major Disciplines in Jiangxi Province - Leading Talent Project, China (Grant No. 20204BCJ22002)

文章全文 : translate this paragraph

参考文献

[1]	Jeong M, Choi I W, Go E M, Cho Y, Kim M, Lee B, Jeong S, Jo Y, Choi H W, Lee J, Bae J H, Kwak S K, Kim D S, Yang C 2020 Science 369 1615 Google Scholar
[2]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen X, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photonics 13 460 Google Scholar
[3]	姬超, 梁春军, 由芳田, 何志群 2021 物理学报 70 028402 Google Scholar Ji C, Liang C J, You T F, He Z Q 2021 Acta Phys. Sin. 70 028402 Google Scholar
[4]	Zhao Y, Wei J, Li, Y Yan, Zhou W, Yu D, Zhao Q 2016 Nat. Commun. 7 10228 Google Scholar
[5]	Walter D, Wu Y, Duong T, Peng J, Jiang L, Fong K C, Weber K 2018 Adv. Energy Mater. 8 1701522 Google Scholar
[6]	朱彧, 杜晨, 王硕, 马瑞新, 王成彦 2020 工程科学学报 42 16 Zhu Y, Du C, Wang S, Ma R X, Wang C Y 2020 Chin. J. Eng. 42 16
[7]	彭英才, 傅广生 2014 新概念太阳电池 (北京: 科学出版社) 第38−39页 Peng Y C, Fu G S 2014 New Concept Solar Cell (Beijing: Science Press) pp38−39 (in Chinese)
[8]	Wenham S R, Green M A, Watt M E, Corkish R 2007 Applied Photovoltaics (UK: Stylus Pub Llc) pp64−67
[9]	Lin C Y, Wan C C, Wei T C 2011 Electrochim. Acta 56 1941 Google Scholar
[10]	Fan Z J, Yi F S, Guo S, Bi Y G 2019 Opt. Eng. 58 017103
[11]	Zhang H, Song K, Zhu L, Meng Q 2020 Carbon 168 372 Google Scholar
[12]	Hu Y, Adhyaksa G W P, DeLuca G, Simonov A N, Duffy N W, Reichmanis E, Bach U, Docampo P, Bein T, Garnett E C, Chesman A S R, Jumabekov A N 2019 AIP Adv. 9 125037 Google Scholar
[13]	Jian W, Xu R P, Li Y Q, Chi L, Chen J D, Zhao X D, Xie Z Z, Lee C S, Zhang W J, Tang J X 2017 Adv. Energy Mater. 7 1700492 Google Scholar
[14]	Yang W, Yang Z, Shou C, Sheng J, Yan B, Ye J 2020 Sol. Energy 201 84 Google Scholar
[15]	Behrouznejad F, Tsai C M, Narra S, Diau E, Taghavinia N 2017 ACS Appl. Mater. Interfaces 9 25204 Google Scholar
[16]	Lin X, Chesman A S R, Raga S R, Scully A D, Jiang L, Tan B, Lu J, Cheng Y B, Bach U 2018 Adv. Funct. Mater. 28 1805098 Google Scholar
[17]	Jahantigh F, Ghorashi S M B 2019 Nano 14 1950127 Google Scholar
[18]	Saxena P, Gorji N E 2019 IEEE J. Photovoltaics 9 1693 Google Scholar
[19]	王媛, 崔艳, 吴以治 2019 人工晶体学报 48 2075 Google Scholar Wang Y, Cui Y, Wu Y Z 2019 J. Synth. Cryst. 48 2075 Google Scholar
[20]	车俐佳, 郭艳群, 邹谭圆, 盛鑫, 赖文志, 蔡传兵 2020 功能材料与器件学报 25 43 Che L J, Guo Y Q, Zou T Y, Sheng X, Lai W Z, Cai C B 2020 J. Funct. Mater. Devices 25 43
[21]	甘永进, 莫沛, 杨瑞兆, 饶俊慧, 李清流, 毕雪光 2021 固体电子学研究与进展 41 53 Gan Y J, Mo P, Yang R Z, Rao J H, Li Q L, Bi X G 2021 Prog. Solid State Electron. 41 53
[22]	Hou Q, Dorota B, Jumabekov A N, Wei L, Wang Z, Lin X, Hock N S, Tan B, Bao Q, Chesman A S R, Bing C, Bach U 2018 Nano Energy 50 710 Google Scholar
[23]	Zhou X, Bao C, Li F M, Gao H, Yu T, Yang J, Zhu W, Zou Z 2015 RSC Adv. 5 58543 Google Scholar
[24]	Mesquita I, Andrade L, Mendes A 2018 Renewable Sustainable Energy Rev. 82 2471 Google Scholar

施引文献

图 1 文献(a)及本文(b)构建的背电极结构在COMSOL中的网格剖分图; (c)文献与本文计算的背电极电阻-厚度变化趋势图

Fig. 1. The grid diagram of the back electrode structure constructed in literature (a) and this paper (b) in COMSOL; (c) back electrode resistance changing with its thickness.

下载: 全尺寸图片幻灯片

图 2 6种金属的背电极功函数、电池转换效率(a)及其电阻(b)

Fig. 2. Back electrode work function, cell conversion efficiency (a) and electrode resistance (b) of six metals.

下载: 全尺寸图片幻灯片

图 3 S-HQIDE (a、c)和L-HQIDE(b、d)的背电极结构以及仿真图

Fig. 3. Back electrode structure and simulation diagram of S-HQIDE ((a), (c)) and L-HQIDE ((b), (d)).

下载: 全尺寸图片幻灯片

图 4 蜂窝结构背电极电阻随圆形半径的变化

Fig. 4. The resistance of the back electrode with honeycomb structure varies with the radius of the circle.

下载: 全尺寸图片幻灯片

图 5 无孔隙及10%随机孔隙时背电极仿真图及其电阻(a), 以及占比变化对其电阻值影响(b)

Fig. 5. Simulation diagram of back electrode without and with 10% random pores and its resistance (a), and the influence of proportion change on its resistance (b).

下载: 全尺寸图片幻灯片

图 6 仿真蜂窝结构(a)及背电极电阻-厚度变化趋势图(b)

Fig. 6. Simulated honeycomb structure (a) and back electrode resistance changing with its thickness (b).

下载: 全尺寸图片幻灯片

[1]	Jeong M, Choi I W, Go E M, Cho Y, Kim M, Lee B, Jeong S, Jo Y, Choi H W, Lee J, Bae J H, Kwak S K, Kim D S, Yang C 2020 Science 369 1615 Google Scholar
[2]	Jiang Q, Zhao Y, Zhang X, Yang X, Chen X, Chu Z, Ye Q, Li X, Yin Z, You J 2019 Nat. Photonics 13 460 Google Scholar
[3]	姬超, 梁春军, 由芳田, 何志群 2021 物理学报 70 028402 Google Scholar Ji C, Liang C J, You T F, He Z Q 2021 Acta Phys. Sin. 70 028402 Google Scholar
[4]	Zhao Y, Wei J, Li, Y Yan, Zhou W, Yu D, Zhao Q 2016 Nat. Commun. 7 10228 Google Scholar
[5]	Walter D, Wu Y, Duong T, Peng J, Jiang L, Fong K C, Weber K 2018 Adv. Energy Mater. 8 1701522 Google Scholar
[6]	朱彧, 杜晨, 王硕, 马瑞新, 王成彦 2020 工程科学学报 42 16 Zhu Y, Du C, Wang S, Ma R X, Wang C Y 2020 Chin. J. Eng. 42 16
[7]	彭英才, 傅广生 2014 新概念太阳电池 (北京: 科学出版社) 第38−39页 Peng Y C, Fu G S 2014 New Concept Solar Cell (Beijing: Science Press) pp38−39 (in Chinese)
[8]	Wenham S R, Green M A, Watt M E, Corkish R 2007 Applied Photovoltaics (UK: Stylus Pub Llc) pp64−67
[9]	Lin C Y, Wan C C, Wei T C 2011 Electrochim. Acta 56 1941 Google Scholar
[10]	Fan Z J, Yi F S, Guo S, Bi Y G 2019 Opt. Eng. 58 017103
[11]	Zhang H, Song K, Zhu L, Meng Q 2020 Carbon 168 372 Google Scholar
[12]	Hu Y, Adhyaksa G W P, DeLuca G, Simonov A N, Duffy N W, Reichmanis E, Bach U, Docampo P, Bein T, Garnett E C, Chesman A S R, Jumabekov A N 2019 AIP Adv. 9 125037 Google Scholar
[13]	Jian W, Xu R P, Li Y Q, Chi L, Chen J D, Zhao X D, Xie Z Z, Lee C S, Zhang W J, Tang J X 2017 Adv. Energy Mater. 7 1700492 Google Scholar
[14]	Yang W, Yang Z, Shou C, Sheng J, Yan B, Ye J 2020 Sol. Energy 201 84 Google Scholar
[15]	Behrouznejad F, Tsai C M, Narra S, Diau E, Taghavinia N 2017 ACS Appl. Mater. Interfaces 9 25204 Google Scholar
[16]	Lin X, Chesman A S R, Raga S R, Scully A D, Jiang L, Tan B, Lu J, Cheng Y B, Bach U 2018 Adv. Funct. Mater. 28 1805098 Google Scholar
[17]	Jahantigh F, Ghorashi S M B 2019 Nano 14 1950127 Google Scholar
[18]	Saxena P, Gorji N E 2019 IEEE J. Photovoltaics 9 1693 Google Scholar
[19]	王媛, 崔艳, 吴以治 2019 人工晶体学报 48 2075 Google Scholar Wang Y, Cui Y, Wu Y Z 2019 J. Synth. Cryst. 48 2075 Google Scholar
[20]	车俐佳, 郭艳群, 邹谭圆, 盛鑫, 赖文志, 蔡传兵 2020 功能材料与器件学报 25 43 Che L J, Guo Y Q, Zou T Y, Sheng X, Lai W Z, Cai C B 2020 J. Funct. Mater. Devices 25 43
[21]	甘永进, 莫沛, 杨瑞兆, 饶俊慧, 李清流, 毕雪光 2021 固体电子学研究与进展 41 53 Gan Y J, Mo P, Yang R Z, Rao J H, Li Q L, Bi X G 2021 Prog. Solid State Electron. 41 53
[22]	Hou Q, Dorota B, Jumabekov A N, Wei L, Wang Z, Lin X, Hock N S, Tan B, Bao Q, Chesman A S R, Bing C, Bach U 2018 Nano Energy 50 710 Google Scholar
[23]	Zhou X, Bao C, Li F M, Gao H, Yu T, Yang J, Zhu W, Zou Z 2015 RSC Adv. 5 58543 Google Scholar
[24]	Mesquita I, Andrade L, Mendes A 2018 Renewable Sustainable Energy Rev. 82 2471 Google Scholar

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背电极材料、结构以及厚度等影响钙钛矿太阳能电池性能的研究