新型空穴传输材料在钙钛矿太阳能电池中的研究进展

宋志浩; 王世荣; 肖殷; 李祥高

doi:10.7498/aps.64.033301

摘要

钙钛矿太阳能电池是一种全新的全固态薄膜电池. 报道的能量转换效率已提高到19.3%, 成为可再生能源领域的热点研究方向. 空穴传输材料是构成高效钙钛矿太阳能电池的重要组分之一. 本文介绍了钙钛矿太阳能电池的基本结构, 对空穴传输材料的分子结构、能级水平和迁移率等对电池性能的影响进行了详细的总结和评述.

关键词:

Perovskite solar cells with a solid-state thin film structure have attracted great attention in recent years due to their simple structure, low production cost and superb photovoltaic performance. Because of the boost in power conversion efficiency (PCE) in short intervals from 3.8% to 19.3% at present, this hybrid cells have been considered as the next generation photovoltaic devices. It is expected that the efficiencies of individual devices could ultimately achieve 25%, which is comparable to the single-crystal silicon solar cell.In this article, the perovskite absorber, its basic device structure, and operating principles are briefly introduced. Since most of the high efficiency perovskite solar cells employ hole transporting materials (HTM), they could benefit the hole transport and improve the metal-semiconductor interface in the cells. This perspective gives analyses of some effective hole transporting materials for perovskite solar cell application. The hole transporting materials used in perovskite solar cell are classified into six categories according to their structures, including triphenylamine-based small molecule HTM, small molecule HTM containing N atom, sulfur-based small molecule HTM, sulfur-based polymer HTM, polymer HTM containing N atom and inorganic HTM. Emphasis is placed on the interplay of molecular structures, energy levels, and charge carrier mobility as well as device parameters. A critial look at various approaches applied to achieve desired materials and device performance is provided to assist in the identification of new directions and further advances.

Keywords:

作者及机构信息

1.
天津大学化工学院, 天津 300072;

2.
天津化学化工协同创新中心, 天津 300072

基金项目: 国家高技术研究发展计划(批准号: 2012AA030307)和天津市科技支撑计划重点资助项目(批准号: 13ZCZDGX00900)资助的课题.

Authors and contacts

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;

2.
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China

Funds: Project supported by the National High Technology Research and Development Program of China (Grant No. 2012AA030307), and the Key Projects in the Science & Technology Pillar Program of Tianjin, China (Grant No. 13ZCZDGX00900).

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施引文献

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[3]	Zhou H P, Chen Q, Li G, Luo S, Song T B, Duan H S, Hong Z R, You J B, Liu Y S, Yang Y 2014 Science 345 542
[4]	Singh S P, Nagarjuna P 2014 Dalton Trans. 43 5247
[5]	Cai B, Xing Y D, Yang Z, Zhang W H, Qiu J S 2013 Energy Environ. Sci. 6 1480
[6]	Noh J H, Im S H, Heo J H, Mandal T N, Seok S I 2013 Nano Lett. 13 1764
[7]	Park N G 2013 J. Phys. Chem. Lett. 4 2423
[8]	Shen Q, Ogomi Y, Chang J, Tsukamoto S, Kukihara K, Oshima T, Osada N, Yoshino K, Katayama K, Toyoda T, Hayase S 2014 Phys. Chem. Chem. Phys. 16 19984
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[12]	Xing G C, Mathews N, Sun S Y, Lim S S, Lam Y M, Grätzel M, Mhaisalkar S, Sum T C 2013 Science 342 344
[13]	Stranks S D, Eperon G E, Grancini G, Menelaou C, Alcocer M J, Leijtens T, Herz L M, Petrozza A, Snaith H J 2013 Science 342 341
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[19]	Wang B H, Xiao X D, Chen T 2014 Nanoscale 6 12287
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[57]	Ryu S, Noh J H, Jeon N J, Kim Y C, Yang W S, Seo J W, Seok S I 2014 Energy Environ. Sci. 7 2614
[58]	Ito S, Tanaka S, Vahlman H, Nishino H, Manabe K, Lund P 2014 ChemPhysChem 15 1194
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[61]	Qin P, Tanaka S, Ito S, Tetreault N, Manabe K, Nishino H, Nazeeruddin M K, Grätzel M 2014 Nat. Commun. 5 3834
[62]	Subbiah A S, Halder A, Ghosh S, Mahuli N, Hodes G, Sarkar S K 2014 J. Phys. Chem. Lett. 5 1748
[63]	Jeng J Y, Chen K C, Chiang T Y, Lin P Y, Tsai T D, Chang Y C, Guo T F, Chen P, Wen T C, Hsu Y J 2014 Adv. Mater. 26 4107
[64]	Zhu Z L, Bai Y, Zhang T, Liu Z K, Long X, Wei Z H, Wang Z L, Zhang L X, Wang J N, Yan F, Yang S H 2014 Angew. Chem. Int. Ed. 53 12571
[65]	Wang K C, Jeng J Y, Shen P S, Chang Y C, Diau E W G, Tsai C H, Chao T Y, Hsu H C, Lin P Y, Chen P, Guo T F, Wen T C 2014 Sci. Rep. 4 4756
[66]	Wu Z W, Bai S, Xiang J, Yuan Z C, Yang Y G, Cui W, Gao X Y, Liu Z, Jin Y Z, Sun B Q 2014 Nanoscale 6 10505

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