Physiochemical properties and crystallization behavior of GeS2-In2S3 chalcogenide glasses

Lin Chang-Gui; Zhai Su-Min; Li Zhuo-Bin; Qu Guo-Shun; Gu Shao-Xuan; Tao Hai-Zheng; Dai Shi-Xun

doi:10.7498/aps.64.054208

Abstract

Relationship among the composition, properties, and structure of glasses are one of the long standing topics in glass science. In this paper, (100-x) GeS2-xIn2S3 (x=10, 15, 20, 25 or 30 mol%) glasses and glass-ceramics are prepared by melt-quenching and subsequent heat treatments. Their composition dependence of optical bandgap, glass transition temperature, and crystallization behavior is measured by various techniques, and the effect of Ga or In element and the related structural units on their properties is discussed with the help of the previous researches on the GeS2-Ga2S3 glass system. Results show that In has a much bigger influence than Ga on the optical bandgap and glass transition temperature of chalcogenide glasses, while the crystallization behavior of the two kinds of glasses containing Ga and In is totally different, but has a close connection with the respective phase diagram. Their structural motifs can be realized by employing polarized Raman spectra. Consequently, combined with the recognition of their phase diagrams, the composition dependence of physiochemical properties and crystallization behavior, as well as the structural motifs, the correlation between chemical and structural topology is briefly discussed, which may provide a new insight into the glass topological structure.

Keywords:

Authors and contacts

1.
State Key Laboratory of Silicate Materials for Architecture (Wuhan University of Technology), Wuhan 430070, China;
2.
Laboratory of Infrared Materials and Devices, Advanced Technology Research Institute, Ningbo University, Ningbo 315211, China
Funds: Project supported by the National Natural Science Foundation of China (Grant No. 61108057), the Natural Science Foundation of Zhejiang Province, China (Grant No. LY14E020001), the State Key Laboratory of Silicate Materials for Architectures (Wuhan University of Technology), China (Grant No. SYSJJ2013-03), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the State Education Ministry. It was also sponsored by K.C. Wong Magna Fund in Ningbo University.

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Cited By

[1]	Zhou Y, Yu X, Xu X, Dai S 2012 Acta Phys. Sin. 61 157701 (in Chinese) [周亚训, 於杏燕, 徐星辰, 戴世勋 2012 物理学报 61 157701]
[2]	Dong G, Xiao X, Ren J, Ruan J, Liu X, Qiu J, Lin C, Tao H, Zhao X 2008 Chin. Phys. Lett. 25 1891
[3]	Wei K, Machewirth D P, Wenzel J, Snitzer E, Sigel G H 1994 Opt. Lett. 19 904
[4]	Wei K, Machewirth DP, Wenzel J, Snitzer E, Sigel Jr GH. 1995 J. Non-Cryst. Solids 182 257
[5]	Kim Y S, Cho W Y, Shin Y B, Heo J 1996 J. Non-Cryst. Solids 203 176
[6]	Heo J, Min Yoon J, Ryou S Y 1998 J. Non-Cryst. Solids 238 115
[7]	Lin C, Calvez L, Rozé M, Tao H, Zhang X, Zhao X 2009 Appl. Phys. A 97 713
[8]	Calvez L, Ma H L, Lucas J, Zhang X H 2007 Adv. Mater. 19 129
[9]	Lin C, Calvez L, Tao H, Allix M, Moréac A, Zhang X, Zhao X 2011 J. Solid State Chem. 184 584
[10]	Lin C, Qu G, Li Z, Dai S, Ma H, Xu T, Nie Q, Zhang X 2013 J. Am. Ceram. Soc. 96 1779
[11]	Li Z, Lin C, Nie Q, Xu T, Dai S 2012 Acta Phys. Sin. 61 104207 (in Chinese) [李卓斌, 林常规, 聂秋华, 徐铁峰, 戴世勋 2012 物理学报 61 104207]
[12]	Lin C, Li Z, Qian H, Ni W, Li Y, Dai S 2012 Acta Phys. Sin. 61 154212 (in Chinese) [林常规, 李卓斌, 覃海娇, 倪文豪, 李燕颖, 戴世勋 2012 物理学报 61 154212]
[13]	Lin C, Dai S, Liu C, Song Ba, Xu Y, Chen F, Heo J 2012 Appl. Phys. Lett. 100 231910
[14]	Lin C, Calvez L, Li Z, Dai S, Tao H, Ma H, Zhang X, Moine B, Zhao X 2013 J. Am. Ceram. Soc. 96 816
[15]	Dong G, Tao H, Chu S, Wang S, Zhao X, Gong Q, Xiao X, Lin C 2007 Opt. Commun. 270 373
[16]	Dong G, Tao H, Xiao X, Lin C, Zhao X, Mao S 2007 J. Phys. Chem. Solids 68 158
[17]	Xu Y, Chen D, Zhang Q, Wang W, Zeng H, Shen C, Chen G 2009 Chem. Phys. Lett. 472 104
[18]	Xu Y, Chen D, Zhang Q, Zeng H, Shen C, Adam J-l, Zhang X, Chen G 2009 J. Phys. Chem. C 113 9911
[19]	Tao H, Lin C, Chu S, Mao S, Gong Y, Zhao X, Wang S, Gong Q 2008 J. Non-Cryst. Solids 354 1303
[20]	Tao H, Lin C, Gong Y, Mao S, Zhao X 2008 Optoelectron. Adv. Mater. 2 29
[21]	Ying L, Lin C, Nie Q, Li Z, Xu Y, Chen F, Dai S 2012 J. Am. Ceram. Soc. 95 1320
[22]	Li Z, Lin C, Nie Q, Dai S 2013 J. Am. Ceram. Soc. 96 125
[23]	Li Z, Lin C, Nie Q, Dai S 2013 Appl. Phys. A 112 939
[24]	Loireau-Lozac'h A M, Guittard M 1975 Ann. Chim. 10 101
[25]	Sarkisov E S, Lidin R A 1969 Inorg. Mater. 5 839
[26]	Vogel W 1994 Glass Chemistry (Second Edition) (Berlin: Springer-Verlag) pp92-109
[27]	Tao H, Mao S, Dong G, Xiao H, Zhao X 2006 Solid State Commun. 137 408
[28]	Gasanly N M, Özkan H, Aydinli A, Yilmaz Ī 1999 Solid State Commun. 110 231

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Vol. 64, Issue 5 - 2015-03-05

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