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Research progress of waveguide integrated carbon based infrared detectors

LYU Xiaowei ZHANG Jiazhen CHEN Junyu LIU Zizhuo ZHAO Wenchao WU Qiushi XU Hao CHEN Xiaoshuang

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Research progress of waveguide integrated carbon based infrared detectors

LYU Xiaowei, ZHANG Jiazhen, CHEN Junyu, LIU Zizhuo, ZHAO Wenchao, WU Qiushi, XU Hao, CHEN Xiaoshuang
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  • Carbon-based materials, such as graphene and carbon nanotubes (CNTs), have garnered significant attention for next-generation infrared photodetection due to their unique and excellent physical properties, including ultra-high carrier mobility and exceptionally broad spectral absorption. These characteristics present vast application prospects in fields such as optical communications, military sensing, biomedical imaging, and energy. However, a critical bottleneck for their practical application is the inherently weak light-matter interaction stemming from their low-dimensional nature. For example, a single layer of graphene absorbs only 2.3% of incident light, which severely limits the sensitivity and overall performance of photodetectors.To overcome this fundamental limitation, integrating carbon-based materials with photonic waveguides has emerged as a highly effective and promising strategy. This approach confines light within the waveguide and utilizes the evanescent field to couple with the carbon material over a long interaction length, greatly enhancing the total light absorption. Furthermore, its intrinsic compatibility with CMOS fabrication processes paves the way for low-cost, high-density, and large-scale manufacturing, meeting the stringent demands of future optoelectronic systems.This paper comprehensively reviews the latest developments in waveguide-integrated carbon-based infrared photodetectors, systematically summarizing and analyzing the progress made in three major integration aspects: silicon-on-insulator (SOI), silicon nitride (SiNx), and advanced heterostructures such as plasmonic and slot waveguides). Various performance enhancement strategies are detailed by exploring different photodetection mechanisms, including the photovoltaic effect (PVE), photothermoelectric effect (PTE), photobolometric effect (PBE), and internal photoemission effect (IPE). Key breakthroughs are highlighted, such as achieving ultra-high bandwidths exceeding 150 GHz on SOI, realizing a superior balance of high responsivity (~2.36 A/W) and high speed (~33 GHz) on SiNx, and enhancing responsivity to over 600 mA/W while extending the detection range to the mid-infrared (5.2 μm) using advanced heterostructure waveguides.Finally, the current development bottlenecks are discussed, including challenges in material transfer, interface quality control, and thermal management. Future research directions are also suggested, such as the development of novel carbon-based heterostructures, deeper integration with on-chip photonic systems, and the exploration of new waveguide materials for long-wave infrared applications. This work provides a clear roadmap for the continously developing high-performance, waveguide-integrated carbon-based infrared detectors.
  • 图 1  碳原子的几种低维同素异形体, 出自文献[2], 已获得授权

    Figure 1.  Several low-dimensional allotropes of carbon atoms. Reproduced with permission from Ref.[2].

    图 2  正负PCE原理图, 出自文献[28], 已获得授权

    Figure 2.  Schematic diagram of positive and negative PCE. Reproduced with permission from Ref. [28].

    图 3  (a) PVE原理示意图; (b) 有无照明下PN结的两个典型IV曲线

    Figure 3.  (a) Schematic images of PVE; (b) two typical I-V curves of a P–N junction with and without illumination.

    图 4  (a) PBE物理机制的示意图; (b)测辐射热型探测器在有光照和无光照时的I-V曲线图

    Figure 4.  (a) Schematic diagram of the PBE physical mechanism; (b) plot of I-V curves for a bolometric detector under both illuminated and non-illuminated conditions.

    图 5  (a) PTE结构示意图; (b) PTE原理示意图

    Figure 5.  (a) Structure schematic diagram of PTE; (b) schematic diagram of PTE principle.

    图 6  (a) 石墨烯微腔光电探测器示意图, 出自文献[24], 已获得授权; (b) F-P微腔集成的单管二极管型光电探测器示意图, 出自文献[14], 已获得授权; (c) 带有等离子体光栅耦合器的金属-石墨烯-金属光电探测器, 出自文献[45], 已获得授权; (d) 基于分形超表面的增强型石墨烯光电探测器, 出自文献[46], 已获得授权

    Figure 6.  (a) Schematic drawing of a graphene microcavity photodetector, reproduced with permission from Ref.[24]; (b) schematic representation of a single-tube diode-type photodetector integrated with F–P microcavity, reproduced with permission from Ref.[14]; (c) metal-graphene-metal photodetector with plasmonic grating coupler, reproduced with permission from Ref.[45]; (d) enhanced graphene photodetector with fractal metasurface, reproduced with permission from Ref.[46].

    图 7  (a) 非对称接触配置下硅波导上集成的石墨烯光电探测器, 出自文献[49], 已获得授权; (b) 平面化波导上集成的双层石墨烯调制器/探测器的示意图, 出自文献[51], 已获得授权; (c) 波导集成碳纳米管光电二极管结构示意图, 出自文献[52], 已获得授权; (d) 低暗电流、48 GHz带宽的硅波导集成CNT光电探测器, 出自文献[53], 已获得授权; (e) 基于平面化硅波导的高速CNT光电探测器, 出自文献[54], 已获得授权; (f) 埋入硅波导上的hBN/SLG/hBN光电探测器, 出自文献[55], 已获得授权; (g) 高性能硅-石墨烯混合等离激元波导光电探测器的结构, 出自文献[57], 已获得授权; (h) PTE石墨烯光电探测器的3D示意图, 出自文献[58], 已获得授权; (i) 硅-石墨烯等离子体肖特基光电探测器, 出自文献[59], 已获得授权

    Figure 7.  (a) Graphene photodetector integrated on a silicon waveguide with asymmetric contact configuration, reproduced with permission from Ref.[49]; (b) schematic illustration of the dual layer graphene modulator/detector integrated on a planarized waveguide, reproduced with permission from Ref.[51]; (c) schematic diagram showing the structure of a waveguide-integrated carbon nanotube photodiode, reproduced with permission from Ref.[52]; (d) silicon waveguide-integrated carbon nanotube photodetector with low dark current and 48 GHz bandwidth, reproduced with permission from Ref.[53]; (e) high-speed carbon nanotube photodetector based on a planarized silicon waveguide, reproduced with permission from Ref.[54]; (f) the hBN/SLG/hBN photodetector on a buried silicon waveguide, reproduced with permission from Ref.[55]; (g) structures of the high-performance silicon–graphene hybrid plasmonic waveguide photodetectors, reproduced with permission from Ref.[57]; (h) 3D schematic of the PTE graphene photodetector, reproduced with permission from Ref.[58]; (i) silicon–Graphene plasmonic Schottky photodetector, reproduced with permission from Ref.[59]

    图 8  (a) 波导集成等离子体增强石墨烯光电探测器, 出自文献[66], 已获得授权; (b) 无源光子波导上具有聚合物栅极电介质的超快、零偏压石墨烯光电探测器, 出自文献[65], 已获得授权

    Figure 8.  (a) Waveguide-integrated, plasmonic enhanced graphene photodetectors, reproduced with permission from Ref.[66]; (b) ultrafast, zero-Bias, graphene photodetectors with polymeric gate dielectric on passive photonic waveguides, reproduced with permission from Ref.[65].

    图 9  (a) 基于缝隙波导的石墨烯光电探测器, 出自文献[69], 已获得授权; (b) 基于双槽结构的光电探测器, 出自文献[70], 已获得授权; (c) 石墨烯等离子体集成光电探测器, 出自文献[74], 已获得授权; (d) 在可扩展硫系玻璃平台上使用石墨烯进行波导集成, 出自文献[72], 已获得授权

    Figure 9.  (a) The graphene photodetector based on a slot-waveguide, reproduced with permission from Ref.[69]; (b) graphene photodetector employing double slot structure, reproduced with permission from Ref.[70]; (c) the graphene-plasmonic integrated photodetector, reproduced with permission from Ref.[74]; (d) waveguide-integrated mid-infrared photodetection using graphene on a scalable chalcogenide glass platform, reproduced with permission from Ref.[72].

    表 1  集成SOI波导的碳基红外探测器性能比对

    Table 1.  Performance comparison of carbon based infrared detectors with integrated SOI waveguides.

    工作
    机制
    文献 年份 碳基
    材料
    类型 波长/nm 响应率
    /(mA·W–1)
    带宽
    /GHz
    暗电流 创新点
    PVE [47] 2013 石墨烯 机械剥离 1450—1590 108 20 极低(零偏压) 非对称金属电极构建内建电场,
    实现零偏压高速探测
    [48] 2013 石墨烯 机械剥离 1310—1650 30—50 18 极低(零偏压) CMOS兼容工艺, 全波段覆盖
    [50] 2013 石墨烯 机械剥离 1550—2750 130 - 低(异质结抑制) 石墨烯/硅异质结结合悬浮波导,
    将探测范围拓展至2.75 μm
    [51] 2014 石墨烯 湿法转移 1550 57 3 零偏压无暗电流 调制-探测双功能集成
    [49] 2014 石墨烯 湿法转移 1550 7 41 零偏压无暗电流 晶圆级CVD材料+50 Gbit/s链路
    [52] 2020 CNT - 1530 12.5 - <1 nA(@ –0.5 V) 单片集成、零偏压工作、
    光电子系统兼容性作
    [53] 2023 CNT - 1550 73.62 48 0.157 μA(@ –2 V) 电极位置优化、实现高带宽与
    低暗电流的平衡
    [54] 2024 CNT - 1550 51.04 34 0.389 μA(@ –3 V) 波导平面化工艺、热稳定性提升
    PTE [55] 2015 石墨烯 湿法转移 1500—1800 360 42 零偏压无暗电流 hBN封装提升性能+自相关功能
    [56] 2016 石墨烯 湿法转移 1550 273 - 极低 槽波导光场局域化, 悬浮石墨烯
    抑制声子散射
    [57] 2020 石墨烯 湿法转移 1500—2000 400 >40 低偏压下暗电流可控 混合等离子体波导平衡吸收与损耗,
    支持中红外
    [58] 2021 石墨烯 湿法转移 1550 3500 >65 零暗电流 光热效应实现零偏压超高速,
    50 Ω阻抗匹配
    IPE [59] 2016 石墨烯 湿法转移 1550 370 - 等离子体波导增强光吸收, 雪崩增益
    PBE [60] 2025 石墨烯 湿法转移 1550—1640 68—200 155 等离激元谐振增强; 实现155 GHz带
    宽和创纪录的192 GBaud数据传输
    DownLoad: CSV

    表 2  集成SiNx波导的碳基红外探测器性能比对

    Table 2.  Performance comparison of carbon-based infrared detectors integrated with SiNx waveguides.

    工作机制文献年份碳基材料类型波长/nm响应率带宽/GHz暗电流创新点
    PTE(零偏压)+
    PBE(偏压)
    [64]2015石墨烯湿法转移1550126 mA/W--实现氮化硅波导集成石墨烯探测器,
    CMOS兼容性
    PVE(零偏压)+
    PBE(偏压)
    [67]2018石墨烯湿法转移15502.36 A/W3320 μA叉指电极减小载流子传输距离,
    实现高响应率与高带宽
    PTE[66]2019石墨烯湿法转移1500-160012.2 V/W42零暗电流等离子体波导增强光吸收,
    零偏压高响应率与高带宽
    [65]2020石墨烯湿法转移15506 V/W67零暗电流零偏置操作、聚合物介电优化、
    超高带宽
    DownLoad: CSV

    表 3  集成先进异质结构波导的碳基红外探测器性能比对

    Table 3.  Performance comparison of carbon based infrared detectors integrated with advanced heterostructure waveguides.

    工作
    机制
    文献年份碳基材料类型波长/nm响应率带宽/GHz暗电流创新点
    PTE[69]2016石墨烯机械剥离155035 mA/W65实现石墨烯PN结与硅波导集成,
    突破性提升带宽
    [72]2022石墨烯湿法转移52010 mA/W(零偏压),
    1.5 V/W(偏压)
    >1较高硫系玻璃波导扩展至中红外,
    分裂栅PN结
    PVE[71]2018石墨烯湿法转移400—160011 mA/W>50零偏压下
    可忽略
    石墨烯-P-I-N异质结结合光子晶体波导
    [74]2020石墨烯湿法转移1550360 mA/W>110-等离子体超强光限制,
    超短载流子路径
    [70]2022石墨烯湿法转移1550603.92 mA/W78-双槽结构平衡光吸收与金属损耗
    DownLoad: CSV
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Publishing process
  • Received Date:  25 June 2025
  • Accepted Date:  12 August 2025
  • Available Online:  02 September 2025
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