Thermoelectric properties and prospects of <i>MAX</i> phases and derived <i>MX</i>ene phases

Liu Chao; Yang Yue-Yang; Nan Ce-Wen; Lin Yuan-Hua

doi:10.7498/aps.70.20211050

Abstract

Thermoelectric materials, a kind of new energy material, can directly convert heat energy into electric energy, and vice versa, without needing any other energy conversion. However, the present development status of thermoelectric materials severely restricts their engineering applications in thermoelectric devices. Improving the thermoelectric performances of existing thermoelectric materials and exploring new thermoelectric materials with excellent performance are eternal research topics in thermoelectricity field. In recent years, the MAX phases and their derived MXene phases have gradually received the attention of researchers due to their unique microstructures and properties. The crystal structure of MAX phases is comprised of M_n+1X_n structural units and the single atomic plane of A stacked alternately. The two-dimensional MXene phase derived can be prepared after the atoms in the A-layer of MAX have been etched. The MAX phases and their derived MXene phases have both metal feature and ceramic feature, and also have good thermal conductivity and electric conductivity, and they are anticipated to be the promising thermoelectric materials. In this paper, the present development status of the preparation technology and the thermoelectric properties of MAX phases and MXene are reviewed. Finally, some feasible schemes to improve the thermoelectric properties of MAX and its derived MXene phase materials are proposed, and the development direction and prospect of MAX phases and MXene are prospected as well.

Keywords:

Authors and contacts

1.
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
2.
National Key Laboratory of Science and Technology for National on High-strength Structural Materials, Central South University, Changsha 410083, China

Corresponding author: Lin Yuan-Hua, linyh@tsinghua.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 51729201, 51788104, 51672155) and the State Key R&D Program of China (Grant No. 2016YFA0201003).

FullText HTML : translate this paragraph

References

[1]	Doman LE A V 2016 International Energy Outlook 2016
[2]	李宜 2019 博士学位论文 (济南: 山东大学) Yi L 2019 Ph. D. Dissertation (Jinan: Shandong University) (in Chinese)
[3]	Chu S, Majumdar A 2012 Nature 488 294 Google Scholar
[4]	Liu W, Hu J, Zhang S, Deng M, Han C G, Liu Y 2017 Mater. Today Phys. 1 50 Google Scholar
[5]	Enescu D, Virjoghe E O 2014 Renewable Sustainable Energy Rev. 38 903 Google Scholar
[6]	Zhang Y, Heo Y J, Park M, Park S J Polymers 2019 11 167
[7]	Bell L E 2008 Science 321 1457 Google Scholar
[8]	Zhao L D, Lo S H, Zhang Y S, Sun H, Tan G J, Uher C, Wolverton C, Dravid V P, Kanatzidis M G 2014 Nature 508 373 Google Scholar
[9]	Barsoum M W 2000 Prog. Solid State Chem. 28 201 Google Scholar
[10]	W B M 2013 MAX Phases: Properties of Machinable Ternary Carbides and Nitrides (Berlin: Wiley VCH) pp13–64
[11]	Ching W Y, Mo Y, Aryal S, Rulis P 2013 J. Am. Ceram. Soc. 96 2292 Google Scholar
[12]	Naguib M, Kurtoglu M, Presser V, Lu J, Niu J J, Heon M, Hultman L, Gogotsi Y, Barsoum M W 2011 Adv. Mater. 23 4248 Google Scholar
[13]	郑丽雅, 周延春, 冯志海 2013 宇航材料工艺 43 1 Zheng L Y, Zhou Y C, Feng Z H 2013 Aero. Mater. Tech. 2013 43 1
[14]	Ying G, He X, Li M, Du S, Han W, He F 2011 J. Alloys Compd. 509 8022 Google Scholar
[15]	Hong X, Mei B, Zhu J, Zhou W 2004 J. Mater. Sci. 39 1589 Google Scholar
[16]	Barsoum M W, Brodkin D, El-Raghy T 1997 Scr. Mater. 36 535 Google Scholar
[17]	Cetinkaya S, Eroglu S 2012 Ceram. Int. 38 6445 Google Scholar
[18]	Tian W, Wang P, Zhang G, Kan Y, Li Y, Yan D 2006 Scr. Mater. 54 841 Google Scholar
[19]	Barsoum M W, El-Raghy T, Ali M 2000 Metall. Mater. Trans. A 31 1857 Google Scholar
[20]	Liu A, Yang Q, Ren X, Meng F, Gao L, Gao M, Yang Y, Ma T, Wu G 2020 Ceram. Int. 46 6934 Google Scholar
[21]	Champagne A, Battaglia J L, Ouisse T, Ricci F, Kusiak A, Pradere C, Natu V, Dewandre A, Verstraete M J, Barsoum M W, Charlier J C 2020 J. Phys. Chem. C 124 24017 Google Scholar
[22]	Palmquist J P, Jansson U, Seppänen T, Persson P O Å, Birch J, Hultman L, Isberg P 2002 Appl. Phys. Lett. 81 835 Google Scholar
[23]	Palmquist J P, Li S, Persson P O Å, Emmerlich J, Wilhelmsson O, Högberg H, Katsnelson M I, Johansson B, Ahuja R, Eriksson O, Hultman L, Jansson U 2004 Phys. Rev. B 70 165401 Google Scholar
[24]	Racault C, Langlais F, Bernard C 1994 J. Mater. Sci. 29 5023 Google Scholar
[25]	Fakih H, Jacques S, Dezellus O, Berthet M P, Bosselet F, Sacerdote-Peronnet M, Viala J C 2008 J. Phase Equilib. Diffus. 29 239 Google Scholar
[26]	Medkour Y, Roumili A, Maouche D, Louail L, Haddadi K 2009 Eur. Phys. J. B 68 193 Google Scholar
[27]	Mauchamp V, Yu W, Gence L, Piraux L, Cabioc'h T, Gauthier V, Eklund P, Dubois S 2013 Phys. Rev. B 87 235105 Google Scholar
[28]	Ouisse T, Shi L, Piot B A, Hackens B, Mauchamp V, Chaussende D 2015 Phys. Rev. B 92 045133 Google Scholar
[29]	Flatten T, Matthes F, Petruhins A, Salikhov R, Wiedwald U, Farle M, Rosen J, Bürgler D E, Schneider C M 2019 Appl. Phys. Lett. 115 094101 Google Scholar
[30]	Schuster J C, Nowotny H, Vaccaro C 1980 J. Solid State Chem. 32 213 Google Scholar
[31]	Schneider J M, Sun Z, Mertens R, Uestel F, Ahuja R 2004 Solid State Commun. 130 445 Google Scholar
[32]	Drulis M K, Drulis H, Gupta S, Barsoum M W, El-Raghy T 2006 J. Appl. Phys. 99 093502 Google Scholar
[33]	Bai Y L, He X D, Zhu C C, Chen G Q 2012 J. Am. Ceram. Soc. 95 358 Google Scholar
[34]	Vovk R V, Khadzhai G Y, Prikhna T A, Gevorkyan E S, Kislitsa M V, Soloviev A L, Goulatis I L, Chroneos A 2018 J. Mater. Sci. -Mater. Electron. 29 11478 Google Scholar
[35]	Hu C, Sakka Y, Tanaka H, Nishimura T, Grasso S 2011 J. Am. Ceram. Soc. 94 410 Google Scholar
[36]	Cai P, He Q, Yang L, Huang Z, Liu X, Yin J, Huang Y 2019 Ceram. Int. 45 9799 Google Scholar
[37]	Yoo H I, Barsoum M W, El-Raghy T 2000 Nature 407 581
[38]	Finkel P, Seaman B, Harrell K, Palma J, Hettinger J D, Lofland S E, Ganguly A, Barsoum M W, Sun Z, Li S, Ahuja R 2004 Phys. Rev. B 70 085104 Google Scholar
[39]	Chen K, Chen Y, Zhang J, Song Y, Zhou X, Li M, Fan X, Zhou J, Huang Q 2021 Ceram. Int. 47 7582 Google Scholar
[40]	Sonntag J 2010 J. Phys. Condens. Matter 22 235501 Google Scholar
[41]	Xu C, Wang L, Liu Z, Chen L, Guo J, Kang N, Ma X L, Cheng H M, Ren W 2015 Nat. Mater. 14 1135 Google Scholar
[42]	Zhang F, Zhang Z, Wang H, Chan C H, Chan N Y, Chen X X, Dai J Y 2017 Phys. Rev. Mater. 1 034002 Google Scholar
[43]	Du Z G, Yang S B, Li S M, Lou J, Zhang S Q, Wang S, Li B, Gong Y J, Song L, Zou X L, Ajayan P M 2020 Nature 577 492 Google Scholar
[44]	Zhou J, Zha X H, Chen F Y, Ye Q, Eklund P, Du S Y, Huang Q 2016 Angew. Chem. Int. Ed. 55 5008 Google Scholar
[45]	Zhou J, Zha X, Zhou X, Chen F, Gao G, Wang S, Shen C, Chen T, Zhi C, Eklund P, Du S, Xue J, Shi W, Chai Z, Huang Q 2017 ACS Nano 11 3841 Google Scholar
[46]	Zhou J, Zha X H, Yildizhan M, Eklund P, Xue J M, Liao M Y, Persson P O A, Du S Y, Huang Q 2019 ACS Nano 13 1195 Google Scholar
[47]	Naguib M, Halim J, Lu J, Cook K M, Hultman L, Gogotsi Y, Barsoum M W 2013 J. Am. Chem. Soc. 135 15966 Google Scholar
[48]	Anasori B, Xie Y, Beidaghi M, Lu J, Hosler B C, Hultman L, Kent P R C, Gogotsi Y, Barsoum M W 2015 ACS Nano 9 9507 Google Scholar
[49]	Lipatov A, Alhabeb M, Lukatskaya M R, Boson A, Gogotsi Y, Sinitskii A 2016 Adv. Electron. Mater. 2 1600255 Google Scholar
[50]	Feng A H, Yu Y, Wang Y, Jiang F, Yu Y, Mi L, Song L X 2017 Mater. Des. 114 161 Google Scholar
[51]	Zhang B, Zhu J F, Shi P, Wu W L, Wang F 2019 Ceram. Int. 45 8395 Google Scholar
[52]	Sun Z, Yuan M, Lin L, Yang H, Nan C, Li H, Sun G, Yang X 2019 ACS Mater. Lett. 1 628 Google Scholar
[53]	Lukatskaya M R, Halim J, Dyatkin B, Naguib M, Buranova Y S, Barsoum M W, Gogotsi Y 2014 Angew. Chem. Int. Ed. 53 4877 Google Scholar
[54]	Yang S, Zhang P, Wang F, Ricciardulli A G, Lohe M R, Blom P W M, Feng X 2018 Angew. Chem. Int. Ed. 57 15491 Google Scholar
[55]	Pang S Y, Wong Y T, Yuan S G, Liu Y, Tsang M K, Yang Z B, Huang H T, Wong W T, Hao J H 2019 J. Am. Chem. Soc. 141 9610 Google Scholar
[56]	Sun W, Shah S A, Chen Y, Tan Z, Gao H, Habib T, Radovic M, Green M J 2017 J. Mater. Chem. A 5 21663 Google Scholar
[57]	Song M, Pang S Y, Guo F, Wong M C, Hao J 2020 Adv. Sci. 7 2001546 Google Scholar
[58]	Li X L, Li M, Yang Q, Liang G J, Huang Z D, Ma L T, Wang D H, Mo F N, Dong B B, Huang Q, Zhi C Y 2020 Adv. Energy Mater. 10 2001394 Google Scholar
[59]	Chertopalov S, Mochalin V N 2018 ACS Nano 12 6109 Google Scholar
[60]	Natu V, Pai R, Sokol M, Carey M, Kalra V, Barsoum M W 2020 Chem. 6 616 Google Scholar
[61]	Mei J, Ayoko G A, Hu C F, Sun Z Q 2020 Chem. Eng. J. 395 125111 Google Scholar
[62]	Li M, Lu J, Luo K, Li Y B, Chang K K, Chen K, Zhou J, Rosen J, Hultman L, Eklund P, Persson P O A, Du S Y, Chai Z F, Huang Z R, Huang Q 2019 J. Am. Chem. Soc. 141 4730 Google Scholar
[63]	Li Y, Shao H, Lin Z, Lu J, Liu L, Duployer B, Persson P O Å, Eklund P, Hultman L, Li M, Chen K, Zha X-H, Du S, Rozier P, Chai Z, Raymundo-Piñero E, Taberna P-L, Simon P, Huang Q 2020 Nat. Mater. 19 894 Google Scholar
[64]	Kamysbayev V, Filatov A S, Hu H C, Rui X, Lagunas F, Wang D, Klie R F, Talapin D V 2020 Science 369 979 Google Scholar
[65]	Shi H, Zhang P, Liu Z, Park S, Lohe M R, Wu Y, Shaygan Nia A, Yang S, Feng X 2021 Angew. Chem. Int. Ed. 60 8689 Google Scholar
[66]	Karmakar S, Saha-Dasgupta T 2020 Phys. Rev. Mater. 4 124007 Google Scholar
[67]	Jing Z A, Wang H Y, Feng X H, Xiao B, Ding Y C, Wu K, Cheng Y H 2019 J. Phys. Chem. Lett. 10 5721 Google Scholar
[68]	Liu P, Ding W J, Liu J, Shen L L, Jiang F X, Liu P P, Zhu Z Y, Zhang G, Liu C C, Xu J K 2020 J. Alloys Compd. 829 154634 Google Scholar
[69]	Ding W, Liu P, Bai Z, Wang Y, Liu G, Jiang Q, Jiang F, Liu P, Liu C, Xu J 2020 Adv. Mater. Interfaces 7 2001340 Google Scholar
[70]	Guan X, Feng W, Wang X Z, Venkatesh R, Ouyang J Y 2020 ACS Appl. Mater. Interfaces 12 13013 Google Scholar
[71]	Li X H, Zhang R Z, Cui H L 2020 ACS Omega 5 18403 Google Scholar
[72]	Bafekry A, Nguyen C V, Stampfl C, Akgenc B, Ghergherehchi M 2020 Phys. Status Solidi B 257 2000343 Google Scholar
[73]	Bafekry A, Akgenc B, Ghergherehchi M, Peeters F M 2020 J. Phys. Condens. Matter 32 355701 Google Scholar
[74]	Zhang H, Hu T, Wang X, Zhou Y 2020 J. Mater. Sci. Technol. 38 205 Google Scholar
[75]	Tao Q, Dahlqvist M, Lu J, Kota S, Meshkian R, Halim J, Palisaitis J, Hultman L, Barsoum M W, Persson P O Å, Rosen J 2017 Nat. Commun. 8 14949 Google Scholar
[76]	Meshkian R, Dahlqvist M, Lu J, Wickman B, Halim J, Thörnberg J, Tao Q Z, Li S X, Intikhab S, Snyder J, Barsoum M W, Yildizhan M, Palisaitis J, Hultman L, Persson P, Rosen J 2018 Adv. Mater. 30 1706409 Google Scholar
[77]	Meshkian R, Lind H, Halim J, El Ghazaly A, Thörnberg J, Tao Q, Dahlqvist M, Palisaitis J, Persson P O Å, Rosen J 2019 ACS Appl. Nano Mater. 2 6209 Google Scholar
[78]	Kim H, Anasori B, Gogotsi Y, Alshareef H N 2017 Chem. Mater. 29 6472 Google Scholar
[79]	Guo J, Legum B, Anasori B, Wang K, Lelyukh P, Gogotsi Y, Randall C A 2018 Adv. Mater. 30 1801846 Google Scholar
[80]	Khazaei M, Arai M, Sasaki T, Chung C Y, Venkataramanan N S, Estili M, Sakka Y, Kawazoe Y 2013 Adv. Funct. Mater. 23 2185 Google Scholar
[81]	Khazaei M, Arai M, Sasaki T, Estili M, Sakka Y 2014 Phys. Chem. Chem. Phys. 16 7841 Google Scholar
[82]	Zha X H, Luo K, Li Q, Huang Q, He J, Wen X, Du S 2015 EPL 111 26007 Google Scholar
[83]	Zha X H, Zhou J, Zhou Y H, Huang Q, He J, Francisco J S, Luo K, Du S Y 2016 Nanoscale 8 6110 Google Scholar
[84]	Luo K, Zha X H, Zhou Y H, Guo Z S, Lin C T, Huang Q, Zhou S H, Zhang R F, Du S Y 2018 RSC Adv. 8 22452 Google Scholar
[85]	Zhang X, Zhao X D, Wu D H, Jing Y, Zhou Z 2015 Nanoscale 7 16020 Google Scholar
[86]	Xie Y, Kent P R C 2013 Phys. Rev. B 87 235441 Google Scholar
[87]	Zha X H, Huang Q, He J, He H M, Zhai J Y, Francisco J S, Du S Y 2016 Sci. Rep. 6 1 Google Scholar
[88]	Xu X, Ge X, Liu X, Li L, Fu K, Dong Y, Meng F, Si R, Zhang M 2020 Ceram. Int. 46 13377 Google Scholar
[89]	Miranda A, Halim J, Barsoum M W, Lorke A 2016 Appl. Phys. Lett. 108 033102 Google Scholar
[90]	Jing H, Yeo H, Lyu B, Ryou J, Choi S, Park J H, Lee B H, Kim Y H, Lee S 2021 ACS Nano 15 1388 Google Scholar
[91]	Gao L G, Wang N, Cao J M, Li Y, Ma T L 2020 Surf. Interfaces 20 100604 Google Scholar
[92]	Mostafaei A, Faizabadi E, Semiromi E H 2019 Physica E 114 113559 Google Scholar
[93]	Zhang Y G, Sa B S, Zhou J, Sun Z M 2021 Comput. Mater. Sci. 186 110013 Google Scholar
[94]	Li L H 2016 Comput. Mater. Sci. 124 8 Google Scholar
[95]	Si C, Jin K H, Zhou J, Sun Z, Liu F 2016 Nano Lett. 16 6584 Google Scholar
[96]	Khazaei M, Ranjbar A, Arai M, Yunoki S 2016 Phys. Rev. B 94 125152 Google Scholar
[97]	Anasori B, Shi C, Moon E J, Xie Y, Voigt C A, Kent P R C, May S J, Billinge S J L, Barsoum M W, Gogotsi Y 2016 Nanoscale Horiz. 1 227 Google Scholar
[98]	Je M, Lee Y, Chung Y C 2016 Thin Solid Films 619 131 Google Scholar
[99]	Bai X, Zha X H, Qiao Y, Qiu N, Zhang Y, Luo K, He J, Li Q, Huang Q, Francisco J S, Lin C T, Du S 2020 Nanoscale 12 3795 Google Scholar

Cited By

图 1 热电材料的塞贝克效应和珀尔帖效应示意图^[6]

Figure 1. Schematic diagram of Seebeck effect and Peltier effect in thermoelectric materials^[6].

DownLoad: Full-Size Img PowerPoint

图 2 M_n+1AX_n相的晶体结构^[11]

DownLoad: Full-Size Img PowerPoint

图 3 Cr₂AlC的组织和性能　(a)晶体结构; (b)热导率; (c)测量电阻率; (d)预测面外电阻率^[21]

Figure 3. Microtructure and properties of Cr₂AlC: (a) Atomic structure; (b) thermal conductivity, compared to the values found in the literature; (c) measurements resistivity; (d) predicted out-of-plane resistivity. Plane reprinted with permission from Ref. [21]. Copyright © 2020 American Chemical Society.

DownLoad: Full-Size Img PowerPoint

图 4 Ti₂AlC的组织和性能　(a)蚀刻表面; (b)电导率和电阻率; (c)热导率、热容和热扩散率; (d)总热导率、电子热导率和声子热导率^[33]

Figure 4. Microtructure and properties of Cr₂AlC: (a) Etched surface; (b) electrical conductivity and resistivity; (c) thermal conductivity, heat capacity, and thermal diffusivity; (d) total, electronic and phonon thermal conductivity. Plane reprinted with permission from Ref. [33]. Copyright © 2011 John Wiley and Sons.

DownLoad: Full-Size Img PowerPoint

图 5 Ti₃AlC₂的热电性能　(a)电阻率; (b)热导率^[34]

DownLoad: Full-Size Img PowerPoint

图 6 MXene的制备方法　(a) HF刻蚀法^[12]; (b) LiF+HCl刻蚀法^[49]; (c) Li扩张法^[52]; (d)电化学刻蚀法^[57]; (e)路易斯酸刻蚀法^[62]; (f)碘刻蚀法^[65]

Figure 6. Preparation methods of MXene: (a) Etching method via HF^[12]; (b) etching method via LiF+HCl^[49]; (c) lithiation expansion^[52]; (d) electrochemical etching^[57]; (e) Lewis acid etching^[62]; (f) iodine‐assisted etching^[65]. Panel (a) reprinted from Ref. [12], Copyright 2011 John Wiley and Sons. Panel (b) reprinted from Ref. [49] with the permission of John Wiley and Sons. Panel (c) reprinted with permission from Ref. [52]. Copyright © 2019 American Chemical Society. Panel (e) reprinted with permission from Ref. [62], Copyright © 2019 American Chemical Society. Panel (f) reprinted from Ref. [65] with the permission of John Wiley and Sons

DownLoad: Full-Size Img PowerPoint

图 7 MXene的界面工程及热电性能　(a)−(c) Ti₃C₂T_x/SWCNTs (M/S), Ti₃C₂T_x-SWCNTs-Ti₃C₂T_x (MSM)和 SWCNTs-Ti₃C₂T_x-SWCNTs (SMS) 多层膜及能量过滤效应示意图^[69]; (d)−(f) 3种结构下对应的功率因子随SWCNTs百分比的变化图^[69]; (g) MXene和PEDOT复合后形成内建电场示意图; MXene/PEDOT:PSS中不同MXene质量分数下的(h)塞贝克系数和电导率以及(i)功率因子^[70]

Figure 7. Interface engineering and thermoelectric properties of MXene. The schematic energy diagrams of (a) Ti₃C₂T_x/SWCNTs (M/S), (b) Ti₃C₂T_x-SWCNTs-Ti₃C₂T_x (MSM), and (c) SWCNTs-Ti₃C₂T_x-SWCNTs (SMS) showing the different energy-filtering effects^[69]-. Power factor of (d) Ti₃C₂T_x/SWCNTs (M/S), (e) Ti₃C₂T_x-SWCNTs-Ti₃C₂T_x (MSM), and (f) SWCNTs-Ti₃C₂T_x-SWCNTs (SMS) films^[69]. (g) Schematic diagrams for the interfacial effect between MXene and PEDOT^[70]. (h) Seebeck coefficient and electrical conductivity and (i) power factor of MXene/PEDOT: PSS as a function of the MXene loading^[70]. Panels (a)−(f) are reprinted from Ref. [69] with the permission of John Wiley and Sons. Panels (g)−(i) are adapted with permission from Ref. [70], Copyright © 2020 American Chemical Society.

DownLoad: Full-Size Img PowerPoint

图 8 含有0.81% O空位的Ti₂CO₂在(a)单轴和(b)双轴应变下的电子能带结构; (c) Ti₂CO₂带隙随应力的变化^[72]

Figure 8. Electronic band structure of the O-vacacy Ti₂CO₂ structure (for 0.81% defect concentration) as a function of (a) uniaxial and (b) biaxial strain. (c) Variation of band gap with respect to strain. Reprinted from Ref. [72], Copyright © 2020 John Wiley and Sons

DownLoad: Full-Size Img PowerPoint

图 9 MXene的缺陷工程　(a) Mo_1.33C^[75]; (b) W_1.33C^[76]

Figure 9. Defect engineering of MXene: (a) Mo_1.33C; (b) W_1.33C. Panel (a) is reprinted with permission from Ref. [75], Springer Nature. Panel (b) is adapted from Ref. [76], Copyright © 2016 John Wiley and Sons.

DownLoad: Full-Size Img PowerPoint

图 10 MXene的合金化工程及热电性能 Mo基MXene的 (a)电导率、(b)塞贝克系数和(c)功率因子随温度变化图^[78]; (d) Cr基MXene的理论晶格和电子热导率^[67]; (e) Cr基MXene的理论ZT值^[67]; (f) TiMo基MXene的理论晶格和电子热导率^[66]; (g) TiMo基MXene的理论ZT值^[66]

Figure 10. Alloying engineering and thermoelectric properties of MXene. Temperature dependent thermoelectric properties of Mo-based MXene papers during the first thermal cycle: (a) Electrical conductivity; (b) Seebeck coefficient; (c) thermoelectric power factor^[78]. (d) Lattice and electron thermal conductivities of Cr-based MXene^[67]. (e) Thermoelectric figure of merit (ZT) of Cr-based MXene ^[67]. (f) Temperature-dependent electronic and lattice thermal conductivities of TiMo-based MXene ^[66]. (g) Thermoelectric figure of merit (ZT) effificiency for passivated TiMo-based MXene ^[66]. Panels (a) (c) are reprinted with permission from Ref. [78], Copyright © 2017 American Chemical Society. Panels (d), (e) are reprinted with permission from Ref. [67], Copyright © 2019 American Chemical Society. Panels (f), (g) are reprinted from Ref. [66] with permission from American Physical Society.

DownLoad: Full-Size Img PowerPoint

图 11 MXene体系热电性能研究现状, 图中表示的是M位元素组成, 紫色代表理论具有一定的热电性能, 蓝色代表实验上成功制备的MXene相, 红色代表实际已经测得热电性能, 下划线代表具有潜在热电性能的体系

Figure 11. Status of thermoelectric research of MXene system. Purple elements represent the constituent MXene have certain thermoelectric properties theoretically. Blue elements represent the constituent MXene synthesized experimentally. Red represents the thermoelectric properties of theses MXene being reported. The lanthanides on the underscore represent a class of MXene that may have thermoelectric properties.

DownLoad: Full-Size Img PowerPoint

表 1 常见单相MAX的热电性能^{[14,34,36,37]}

Table 1. Thermoelectric properties of single-phase MAX^{[14,34,36,37]}.

物相种类		测试温度 /K	热膨胀系数 /(10^-6 K^-1)	热导率 /(W·m^–1·K^–1)	电导率 /(10⁶ S·m^–1)	塞贝克系数/(μV·K^–1)
211相	Cr₂AlC	473	12.50	17.5	1.8	—
	Ti₂AlC	300	(8.10 ± 0.50)	46.0	2.8	—
	Nb₂AlC	300	8.10	20.0		—
	Ti₂SnC	300	10.00 ± 2.00	—	14.0	—
	Ti₂SC	300	8.40	60..0	1.8	–12.7
312相	Ti₃AlC₂	85	9.00 ± 0.20	26.5		0.22
312相	Ti₃SiC₂	300	9.20	46.0		—
413相	Nb₄AlC₃	300	5.75	13.5		—

DownLoad: CSV

表 2 MXene的带隙以及载流子迁移率^[80-99]

Table 2. Bandgap and carrier mobility of MXene^[80-99].

MXene	带隙/eV	迁移率/(cm²·V^–1·s^–1)	计算方法/实验值	参考文献
Sc₂CF₂	1.0	1000—5000 (e) 200—500 (h)	PBE	[80-83]
Sc₂CF₂	1.85		HSE06	[82]
Sc₂(OH)₂	0.45	2000 (e) 50—240 (h)	PBE	[80-83]
Sc₂(OH)₂	0.845		HSE06	[82]
Sc₂CO₂	1.8		PBE	[80, 82]
Sc₂CO₂	2.87		HSE06	[82]
Sc₃(CN)F₂	1.18	200—1300 (e) 80—1000 (h)	HSE06	[84]
Ti₂CO₂	0.17—0.26	250—610 (e) 20000—74000 (h)	PBE	[80-82, 85]
	0.9	70—150 (e) 10000—40000 (h)	HSE06	[82, 86, 87]
	1.03	2—900 (e) 4000—8000 (h)	HSE06	[88]
Ti₃C₂T_x(T = O, OH, F)		0.7±0.2 (e)	Experimental	[89]
		1.06 (e)	Experimental	[90]
	0.66		Experimental	[91]
Zr₂CO₂	0.88—0.97		PBE	[80, 82]
	0.66		PBE	[81]
	1.70	150 (e) 1400—17500 (h)	HSE06	[82, 87]
	1.58	14—376 (e) 770—1950 (h)	HSE06	[88]
	1.34		mBJ	[92]
Hf₂CO₂	0.8—1.0		PBE	[80-82]
	1.66	77—330 (e) 1000—34000 (h)	HSE06	[82, 87]
	1.78	24—700 (e) 620—1300 (h)	HSE06	[88]
(Zr_0.5Hf_0.5)₂CO₂	1.74	45—1460 (e) 1500—6200 (h)	PBE	[93]
Mo₂CF₂	0.25—0.30		PBE	[81, 82]
Mo₂CF₂	0.86		HSE06	[82]
Mo₂CCl₂	0.05		PBE	[81]
Mo₂C(OH)₂	0.1		PBE	[81]
W₂CO₂	0.0683		HSE06	[82]
Mo₂TiC₂O₂	0.04		PBE	[94, 95]
Mo₂TiC₂O₂	0.10—0.17		HSE06	[94-96]
Mo₂TiC₂(OH)₂	0.05		PBE	[97]
Cr₂CF(OH)	0.383		PBE	[98]
Cr₂CF₂	1.105		PBE	[98]
Cr₂C(OH)₂	0.396		PBE GGA	[98]
Mo₂ZrC₂O₂	0.066		PBE	[95]
Mo₂ZrC₂O₂	0.11—0.13		HSE06	[95, 96]
Mo₂HfC₂O₂	0.154		PBE	[95]
Mo₂HfC₂O₂	0.20—0.24		HSE06	[95, 96]
W₂TiC₂O₂	0.29		HSE06	[96]
W₂ZrC₂O₂	0.28		HSE06	[96]
W₂HfC₂O₂	0.41		HSE06	[96]
Lu₂CF₂	2.07	200—1000 (e) 14—6000 (h)	HSE06	[99]
Lu₂C(OH)₂	1.28	100000—200000 (e) 12—14000 (h)	HSE06	[99]

DownLoad: CSV

[1]	Doman LE A V 2016 International Energy Outlook 2016
[2]	李宜 2019 博士学位论文 (济南: 山东大学) Yi L 2019 Ph. D. Dissertation (Jinan: Shandong University) (in Chinese)
[3]	Chu S, Majumdar A 2012 Nature 488 294 Google Scholar
[4]	Liu W, Hu J, Zhang S, Deng M, Han C G, Liu Y 2017 Mater. Today Phys. 1 50 Google Scholar
[5]	Enescu D, Virjoghe E O 2014 Renewable Sustainable Energy Rev. 38 903 Google Scholar
[6]	Zhang Y, Heo Y J, Park M, Park S J Polymers 2019 11 167
[7]	Bell L E 2008 Science 321 1457 Google Scholar
[8]	Zhao L D, Lo S H, Zhang Y S, Sun H, Tan G J, Uher C, Wolverton C, Dravid V P, Kanatzidis M G 2014 Nature 508 373 Google Scholar
[9]	Barsoum M W 2000 Prog. Solid State Chem. 28 201 Google Scholar
[10]	W B M 2013 MAX Phases: Properties of Machinable Ternary Carbides and Nitrides (Berlin: Wiley VCH) pp13–64
[11]	Ching W Y, Mo Y, Aryal S, Rulis P 2013 J. Am. Ceram. Soc. 96 2292 Google Scholar
[12]	Naguib M, Kurtoglu M, Presser V, Lu J, Niu J J, Heon M, Hultman L, Gogotsi Y, Barsoum M W 2011 Adv. Mater. 23 4248 Google Scholar
[13]	郑丽雅, 周延春, 冯志海 2013 宇航材料工艺 43 1 Zheng L Y, Zhou Y C, Feng Z H 2013 Aero. Mater. Tech. 2013 43 1
[14]	Ying G, He X, Li M, Du S, Han W, He F 2011 J. Alloys Compd. 509 8022 Google Scholar
[15]	Hong X, Mei B, Zhu J, Zhou W 2004 J. Mater. Sci. 39 1589 Google Scholar
[16]	Barsoum M W, Brodkin D, El-Raghy T 1997 Scr. Mater. 36 535 Google Scholar
[17]	Cetinkaya S, Eroglu S 2012 Ceram. Int. 38 6445 Google Scholar
[18]	Tian W, Wang P, Zhang G, Kan Y, Li Y, Yan D 2006 Scr. Mater. 54 841 Google Scholar
[19]	Barsoum M W, El-Raghy T, Ali M 2000 Metall. Mater. Trans. A 31 1857 Google Scholar
[20]	Liu A, Yang Q, Ren X, Meng F, Gao L, Gao M, Yang Y, Ma T, Wu G 2020 Ceram. Int. 46 6934 Google Scholar
[21]	Champagne A, Battaglia J L, Ouisse T, Ricci F, Kusiak A, Pradere C, Natu V, Dewandre A, Verstraete M J, Barsoum M W, Charlier J C 2020 J. Phys. Chem. C 124 24017 Google Scholar
[22]	Palmquist J P, Jansson U, Seppänen T, Persson P O Å, Birch J, Hultman L, Isberg P 2002 Appl. Phys. Lett. 81 835 Google Scholar
[23]	Palmquist J P, Li S, Persson P O Å, Emmerlich J, Wilhelmsson O, Högberg H, Katsnelson M I, Johansson B, Ahuja R, Eriksson O, Hultman L, Jansson U 2004 Phys. Rev. B 70 165401 Google Scholar
[24]	Racault C, Langlais F, Bernard C 1994 J. Mater. Sci. 29 5023 Google Scholar
[25]	Fakih H, Jacques S, Dezellus O, Berthet M P, Bosselet F, Sacerdote-Peronnet M, Viala J C 2008 J. Phase Equilib. Diffus. 29 239 Google Scholar
[26]	Medkour Y, Roumili A, Maouche D, Louail L, Haddadi K 2009 Eur. Phys. J. B 68 193 Google Scholar
[27]	Mauchamp V, Yu W, Gence L, Piraux L, Cabioc'h T, Gauthier V, Eklund P, Dubois S 2013 Phys. Rev. B 87 235105 Google Scholar
[28]	Ouisse T, Shi L, Piot B A, Hackens B, Mauchamp V, Chaussende D 2015 Phys. Rev. B 92 045133 Google Scholar
[29]	Flatten T, Matthes F, Petruhins A, Salikhov R, Wiedwald U, Farle M, Rosen J, Bürgler D E, Schneider C M 2019 Appl. Phys. Lett. 115 094101 Google Scholar
[30]	Schuster J C, Nowotny H, Vaccaro C 1980 J. Solid State Chem. 32 213 Google Scholar
[31]	Schneider J M, Sun Z, Mertens R, Uestel F, Ahuja R 2004 Solid State Commun. 130 445 Google Scholar
[32]	Drulis M K, Drulis H, Gupta S, Barsoum M W, El-Raghy T 2006 J. Appl. Phys. 99 093502 Google Scholar
[33]	Bai Y L, He X D, Zhu C C, Chen G Q 2012 J. Am. Ceram. Soc. 95 358 Google Scholar
[34]	Vovk R V, Khadzhai G Y, Prikhna T A, Gevorkyan E S, Kislitsa M V, Soloviev A L, Goulatis I L, Chroneos A 2018 J. Mater. Sci. -Mater. Electron. 29 11478 Google Scholar
[35]	Hu C, Sakka Y, Tanaka H, Nishimura T, Grasso S 2011 J. Am. Ceram. Soc. 94 410 Google Scholar
[36]	Cai P, He Q, Yang L, Huang Z, Liu X, Yin J, Huang Y 2019 Ceram. Int. 45 9799 Google Scholar
[37]	Yoo H I, Barsoum M W, El-Raghy T 2000 Nature 407 581
[38]	Finkel P, Seaman B, Harrell K, Palma J, Hettinger J D, Lofland S E, Ganguly A, Barsoum M W, Sun Z, Li S, Ahuja R 2004 Phys. Rev. B 70 085104 Google Scholar
[39]	Chen K, Chen Y, Zhang J, Song Y, Zhou X, Li M, Fan X, Zhou J, Huang Q 2021 Ceram. Int. 47 7582 Google Scholar
[40]	Sonntag J 2010 J. Phys. Condens. Matter 22 235501 Google Scholar
[41]	Xu C, Wang L, Liu Z, Chen L, Guo J, Kang N, Ma X L, Cheng H M, Ren W 2015 Nat. Mater. 14 1135 Google Scholar
[42]	Zhang F, Zhang Z, Wang H, Chan C H, Chan N Y, Chen X X, Dai J Y 2017 Phys. Rev. Mater. 1 034002 Google Scholar
[43]	Du Z G, Yang S B, Li S M, Lou J, Zhang S Q, Wang S, Li B, Gong Y J, Song L, Zou X L, Ajayan P M 2020 Nature 577 492 Google Scholar
[44]	Zhou J, Zha X H, Chen F Y, Ye Q, Eklund P, Du S Y, Huang Q 2016 Angew. Chem. Int. Ed. 55 5008 Google Scholar
[45]	Zhou J, Zha X, Zhou X, Chen F, Gao G, Wang S, Shen C, Chen T, Zhi C, Eklund P, Du S, Xue J, Shi W, Chai Z, Huang Q 2017 ACS Nano 11 3841 Google Scholar
[46]	Zhou J, Zha X H, Yildizhan M, Eklund P, Xue J M, Liao M Y, Persson P O A, Du S Y, Huang Q 2019 ACS Nano 13 1195 Google Scholar
[47]	Naguib M, Halim J, Lu J, Cook K M, Hultman L, Gogotsi Y, Barsoum M W 2013 J. Am. Chem. Soc. 135 15966 Google Scholar
[48]	Anasori B, Xie Y, Beidaghi M, Lu J, Hosler B C, Hultman L, Kent P R C, Gogotsi Y, Barsoum M W 2015 ACS Nano 9 9507 Google Scholar
[49]	Lipatov A, Alhabeb M, Lukatskaya M R, Boson A, Gogotsi Y, Sinitskii A 2016 Adv. Electron. Mater. 2 1600255 Google Scholar
[50]	Feng A H, Yu Y, Wang Y, Jiang F, Yu Y, Mi L, Song L X 2017 Mater. Des. 114 161 Google Scholar
[51]	Zhang B, Zhu J F, Shi P, Wu W L, Wang F 2019 Ceram. Int. 45 8395 Google Scholar
[52]	Sun Z, Yuan M, Lin L, Yang H, Nan C, Li H, Sun G, Yang X 2019 ACS Mater. Lett. 1 628 Google Scholar
[53]	Lukatskaya M R, Halim J, Dyatkin B, Naguib M, Buranova Y S, Barsoum M W, Gogotsi Y 2014 Angew. Chem. Int. Ed. 53 4877 Google Scholar
[54]	Yang S, Zhang P, Wang F, Ricciardulli A G, Lohe M R, Blom P W M, Feng X 2018 Angew. Chem. Int. Ed. 57 15491 Google Scholar
[55]	Pang S Y, Wong Y T, Yuan S G, Liu Y, Tsang M K, Yang Z B, Huang H T, Wong W T, Hao J H 2019 J. Am. Chem. Soc. 141 9610 Google Scholar
[56]	Sun W, Shah S A, Chen Y, Tan Z, Gao H, Habib T, Radovic M, Green M J 2017 J. Mater. Chem. A 5 21663 Google Scholar
[57]	Song M, Pang S Y, Guo F, Wong M C, Hao J 2020 Adv. Sci. 7 2001546 Google Scholar
[58]	Li X L, Li M, Yang Q, Liang G J, Huang Z D, Ma L T, Wang D H, Mo F N, Dong B B, Huang Q, Zhi C Y 2020 Adv. Energy Mater. 10 2001394 Google Scholar
[59]	Chertopalov S, Mochalin V N 2018 ACS Nano 12 6109 Google Scholar
[60]	Natu V, Pai R, Sokol M, Carey M, Kalra V, Barsoum M W 2020 Chem. 6 616 Google Scholar
[61]	Mei J, Ayoko G A, Hu C F, Sun Z Q 2020 Chem. Eng. J. 395 125111 Google Scholar
[62]	Li M, Lu J, Luo K, Li Y B, Chang K K, Chen K, Zhou J, Rosen J, Hultman L, Eklund P, Persson P O A, Du S Y, Chai Z F, Huang Z R, Huang Q 2019 J. Am. Chem. Soc. 141 4730 Google Scholar
[63]	Li Y, Shao H, Lin Z, Lu J, Liu L, Duployer B, Persson P O Å, Eklund P, Hultman L, Li M, Chen K, Zha X-H, Du S, Rozier P, Chai Z, Raymundo-Piñero E, Taberna P-L, Simon P, Huang Q 2020 Nat. Mater. 19 894 Google Scholar
[64]	Kamysbayev V, Filatov A S, Hu H C, Rui X, Lagunas F, Wang D, Klie R F, Talapin D V 2020 Science 369 979 Google Scholar
[65]	Shi H, Zhang P, Liu Z, Park S, Lohe M R, Wu Y, Shaygan Nia A, Yang S, Feng X 2021 Angew. Chem. Int. Ed. 60 8689 Google Scholar
[66]	Karmakar S, Saha-Dasgupta T 2020 Phys. Rev. Mater. 4 124007 Google Scholar
[67]	Jing Z A, Wang H Y, Feng X H, Xiao B, Ding Y C, Wu K, Cheng Y H 2019 J. Phys. Chem. Lett. 10 5721 Google Scholar
[68]	Liu P, Ding W J, Liu J, Shen L L, Jiang F X, Liu P P, Zhu Z Y, Zhang G, Liu C C, Xu J K 2020 J. Alloys Compd. 829 154634 Google Scholar
[69]	Ding W, Liu P, Bai Z, Wang Y, Liu G, Jiang Q, Jiang F, Liu P, Liu C, Xu J 2020 Adv. Mater. Interfaces 7 2001340 Google Scholar
[70]	Guan X, Feng W, Wang X Z, Venkatesh R, Ouyang J Y 2020 ACS Appl. Mater. Interfaces 12 13013 Google Scholar
[71]	Li X H, Zhang R Z, Cui H L 2020 ACS Omega 5 18403 Google Scholar
[72]	Bafekry A, Nguyen C V, Stampfl C, Akgenc B, Ghergherehchi M 2020 Phys. Status Solidi B 257 2000343 Google Scholar
[73]	Bafekry A, Akgenc B, Ghergherehchi M, Peeters F M 2020 J. Phys. Condens. Matter 32 355701 Google Scholar
[74]	Zhang H, Hu T, Wang X, Zhou Y 2020 J. Mater. Sci. Technol. 38 205 Google Scholar
[75]	Tao Q, Dahlqvist M, Lu J, Kota S, Meshkian R, Halim J, Palisaitis J, Hultman L, Barsoum M W, Persson P O Å, Rosen J 2017 Nat. Commun. 8 14949 Google Scholar
[76]	Meshkian R, Dahlqvist M, Lu J, Wickman B, Halim J, Thörnberg J, Tao Q Z, Li S X, Intikhab S, Snyder J, Barsoum M W, Yildizhan M, Palisaitis J, Hultman L, Persson P, Rosen J 2018 Adv. Mater. 30 1706409 Google Scholar
[77]	Meshkian R, Lind H, Halim J, El Ghazaly A, Thörnberg J, Tao Q, Dahlqvist M, Palisaitis J, Persson P O Å, Rosen J 2019 ACS Appl. Nano Mater. 2 6209 Google Scholar
[78]	Kim H, Anasori B, Gogotsi Y, Alshareef H N 2017 Chem. Mater. 29 6472 Google Scholar
[79]	Guo J, Legum B, Anasori B, Wang K, Lelyukh P, Gogotsi Y, Randall C A 2018 Adv. Mater. 30 1801846 Google Scholar
[80]	Khazaei M, Arai M, Sasaki T, Chung C Y, Venkataramanan N S, Estili M, Sakka Y, Kawazoe Y 2013 Adv. Funct. Mater. 23 2185 Google Scholar
[81]	Khazaei M, Arai M, Sasaki T, Estili M, Sakka Y 2014 Phys. Chem. Chem. Phys. 16 7841 Google Scholar
[82]	Zha X H, Luo K, Li Q, Huang Q, He J, Wen X, Du S 2015 EPL 111 26007 Google Scholar
[83]	Zha X H, Zhou J, Zhou Y H, Huang Q, He J, Francisco J S, Luo K, Du S Y 2016 Nanoscale 8 6110 Google Scholar
[84]	Luo K, Zha X H, Zhou Y H, Guo Z S, Lin C T, Huang Q, Zhou S H, Zhang R F, Du S Y 2018 RSC Adv. 8 22452 Google Scholar
[85]	Zhang X, Zhao X D, Wu D H, Jing Y, Zhou Z 2015 Nanoscale 7 16020 Google Scholar
[86]	Xie Y, Kent P R C 2013 Phys. Rev. B 87 235441 Google Scholar
[87]	Zha X H, Huang Q, He J, He H M, Zhai J Y, Francisco J S, Du S Y 2016 Sci. Rep. 6 1 Google Scholar
[88]	Xu X, Ge X, Liu X, Li L, Fu K, Dong Y, Meng F, Si R, Zhang M 2020 Ceram. Int. 46 13377 Google Scholar
[89]	Miranda A, Halim J, Barsoum M W, Lorke A 2016 Appl. Phys. Lett. 108 033102 Google Scholar
[90]	Jing H, Yeo H, Lyu B, Ryou J, Choi S, Park J H, Lee B H, Kim Y H, Lee S 2021 ACS Nano 15 1388 Google Scholar
[91]	Gao L G, Wang N, Cao J M, Li Y, Ma T L 2020 Surf. Interfaces 20 100604 Google Scholar
[92]	Mostafaei A, Faizabadi E, Semiromi E H 2019 Physica E 114 113559 Google Scholar
[93]	Zhang Y G, Sa B S, Zhou J, Sun Z M 2021 Comput. Mater. Sci. 186 110013 Google Scholar
[94]	Li L H 2016 Comput. Mater. Sci. 124 8 Google Scholar
[95]	Si C, Jin K H, Zhou J, Sun Z, Liu F 2016 Nano Lett. 16 6584 Google Scholar
[96]	Khazaei M, Ranjbar A, Arai M, Yunoki S 2016 Phys. Rev. B 94 125152 Google Scholar
[97]	Anasori B, Shi C, Moon E J, Xie Y, Voigt C A, Kent P R C, May S J, Billinge S J L, Barsoum M W, Gogotsi Y 2016 Nanoscale Horiz. 1 227 Google Scholar
[98]	Je M, Lee Y, Chung Y C 2016 Thin Solid Films 619 131 Google Scholar
[99]	Bai X, Zha X H, Qiao Y, Qiu N, Zhang Y, Luo K, He J, Li Q, Huang Q, Francisco J S, Lin C T, Du S 2020 Nanoscale 12 3795 Google Scholar

[1]	He Jun-Song, Luo Feng, Wang Jian, Yang Shi-Guan, Zhai Li-Jun, Cheng Lin, Liu Hong-Xia, Zhang Yan, Li Yan-Li, Sun Zhi-Gang, Hu Ji-Fan. Thermoelectric properties of Co doped TiNiCo_xSn alloys fabricated by melt spinning. Acta Physica Sinica, 2024, 73(10): 107201. doi: 10.7498/aps.73.20240112
[2]	Han Dan, Liu Zhi-Hua, Liu Lu-Lu, Han Xiao-Mei, Liu Dong-Ming, Zhuo Kai, Sang Sheng-Bo. Preparation and gas sensing properties of a novel two-dimensional material Ti₃C₂T_xMXene. Acta Physica Sinica, 2022, 71(1): 010701. doi: 10.7498/aps.71.20211048
[3]	Huang Lu-Lu, Zhang Jian, Kong Yuan, Li Di, Xin Hong-Xing, Qin Xiao-Ying. Optimization of thermoelectric transport performance of nickel-doped CuGaTe₂. Acta Physica Sinica, 2021, 70(20): 207101. doi: 10.7498/aps.70.20211165
[4]	Yuan Min-Hui, Le Wen-Kai, Tan Xiao-Jian, Shuai Jing. Research progress of two-dimensional covalent bond substructure Zintl phase thermoelectric materials. Acta Physica Sinica, 2021, 70(20): 207304. doi: 10.7498/aps.70.20211010
[5]	Zhao Ying-Hao, Zhang Rui, Zhang Bo-Ping, Yin Yang, Wang Ming-Jun, Liang Dou-Dou. Phase structure and thermoelectric properties of Cu_1.8–x Sb_x S thermoelectric material. Acta Physica Sinica, 2021, 70(12): 128401. doi: 10.7498/aps.70.20201852
[6]	Huang Qing-Song, Duan Bo, Chen Gang, Ye Ze-Chang, Li Jiang, Li Guo-Dong, Zhai Peng-Cheng. Mn-In-Cu co-doping to optimize thermoelectric properties of SnTe-based materials. Acta Physica Sinica, 2021, 70(15): 157401. doi: 10.7498/aps.70.20202020
[7]	. Fabrication and Gas Sensing Properties of Two-Dimensional Ti3C2Tx Mxene. Acta Physica Sinica, 2021, (): . doi: 10.7498/aps.70.20211048
[8]	Wang Ya-Ning, Chen Shao-Ping, Fan Wen-Hao, Guo Jing-Yun, Wu Yu-Cheng, Wang Wen-Xian. Interface performance of PbTe-based thermoelectric joints. Acta Physica Sinica, 2020, 69(24): 246801. doi: 10.7498/aps.69.20201080
[9]	Guo Jing-Yun, Chen Shao-Ping, Fan Wen-Hao, Wang Ya-Ning, Wu Yu-Cheng. Improving interface properties of Te based thermoelectric materials and composite electrodes. Acta Physica Sinica, 2020, 69(14): 146801. doi: 10.7498/aps.69.20200436
[10]	Wang Tuo, Chen Hong-Yi, Qiu Peng-Fei, Shi Xun, Chen Li-Dong. Thermoelectric properties of Ag₂S superionic conductor with intrinsically low lattice thermal conductivity. Acta Physica Sinica, 2019, 68(9): 090201. doi: 10.7498/aps.68.20190073
[11]	Chen Yi-Hao, Xu Wei, Wang Yu-Qi, Wan Xiang, Li Yue-Feng, Liang Ding-Kang, Lu Li-Qun, Liu Xin-Wei, Lian Xiao-Juan, Hu Er-Tao, Guo Yu-Feng, Xu Jian-Guang, Tong Yi, Xiao Jian. Fabrication of synaptic memristor based on two-dimensional material MXene and realization of both long-term and short-term plasticity. Acta Physica Sinica, 2019, 68(9): 098501. doi: 10.7498/aps.68.20182306
[12]	Tao Ying, Qi Ning, Wang Bo, Chen Zhi-Quan, Tang Xin-Feng. Microstructure and thermoelectric properties of In2O3/poly(3, 4-ethylenedioxythiophene) composites. Acta Physica Sinica, 2018, 67(19): 197201. doi: 10.7498/aps.67.20180382
[13]	Zhang Yu, Wu Li-Hua, Zengli Jiao-Kai, Liu Ye-Feng, Zhang Ji-Ye, Xing Juan-Juan, Luo Jun. Microstructures and thermoelectric transports in PbSe-MnSe nano-composites. Acta Physica Sinica, 2016, 65(10): 107201. doi: 10.7498/aps.65.107201
[14]	Liu Hai-Yun, Liu Xiang-Lian, Tian Ding-Qi, Du Zheng-Liang, Cui Jiao-Lin. Acoustic charge transport behaviors of sulfur-doped wide gap Ga2Te3-based semiconductors. Acta Physica Sinica, 2015, 64(19): 197201. doi: 10.7498/aps.64.197201
[15]	Wu Zi-Hua, Xie Hua-Qing, Zeng Qing-Feng. Preparation and thermoelectric properties of Ag-ZnO nanocomposites synthesized by means of sol-gel. Acta Physica Sinica, 2013, 62(9): 097301. doi: 10.7498/aps.62.097301
[16]	Huo Feng-Ping, Wu Rong-Gui, Xu Gui-Ying, Niu Si-Tong. Thermoelectric properties of (AgSbTe2)100-x (GeTe)x fabricated by hot pressing method. Acta Physica Sinica, 2012, 61(8): 087202. doi: 10.7498/aps.61.087202
[17]	Ge Zhen-Hua, Zhang Bo-Ping, Yu Zhao-Xin, Liu Yong, Li Jing-Feng. Effects of mechanical alloying process on thermoelectric properties of Bi2S3 Bulk. Acta Physica Sinica, 2012, 61(4): 048401. doi: 10.7498/aps.61.048401
[18]	Fan Ping, Zheng Zhuang-Hao, Liang Guang-Xing, Zhang Dong-Ping, Cai Xing-Min. Preparation and characterization of Sb2Te3 thermoelectric thin films by ion beam sputtering. Acta Physica Sinica, 2010, 59(2): 1243-1247. doi: 10.7498/aps.59.1243
[19]	Yan Yong-Gao, Tang Xin-Feng, Liu Hai-Jun, Yin Ling-Ling, Zhang Qing-Jie. Thermoelectric properties of nonstoichiometric Ag1－xPb18SbTe20 materials. Acta Physica Sinica, 2007, 56(6): 3473-3478. doi: 10.7498/aps.56.3473
[20]	Lü Qiang, Rong Jian-Ying, Zhao Lei, Zhang Hong-Chen, Hu Jian-Min, Xin Jiang-Bo. Influence of process parameters on the electrical properties of n-type and p-type Bi2Te3-based pseudo-ternary thermoelectric materials by the hot-pressing method. Acta Physica Sinica, 2005, 54(7): 3321-3326. doi: 10.7498/aps.54.3321

Catalog

Vol. 70, Issue 20 - 2021-10-20

Metrics

Abstract views: 10560
PDF Downloads: 499
Cited By: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

Search

Article

留言板

Thermoelectric properties and prospects of MAX phases and derived MXene phases

Abstract

Authors and contacts

Corresponding author: Lin Yuan-Hua, linyh@tsinghua.edu.cn

FullText HTML : translate this paragraph

References

Cited By

Catalog

Metrics

Authors

Referees

About Journal

About

Search

Article

留言板

Thermoelectric properties and prospects of MAX phases and derived MXene phases

Abstract

Authors and contacts

Corresponding author: Lin Yuan-Hua, linyh@tsinghua.edu.cn

FullText HTML : translate this paragraph

References

Cited By

Catalog

Metrics

Publishing process

Authors

Referees

About Journal

About